Safety data sheet 203 LIMCO PREPAINT CLEANER Revision date : 2015/01/19 Page: 1/11

Transcription

1 Revision date : 2015/01/19 Page: 1/11 1. Substance/preparation and company identification Company BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA 24 Hour Emergency Response Information CHEMTREC: BASF HOTLINE: HELP (4357) 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Germ cell mutagenicity 1 Carcinogenicity 1 Flammable liquids 2 Hazardous to the aquatic environment - acute 2 Hazardous to the aquatic environment - chronic 2 Label elements Pictogram: Flame Environment Health hazard Signal Word: Danger Hazard Statement: H411 H225 H350 H340 Toxic to aquatic life with long lasting effects. Highly flammable liquid and vapour. May cause cancer. May cause genetic defects. Precautionary Statements (Prevention): P273 Avoid release to the environment. P202 Do not handle until all safety precautions have been read and understood. P240 Ground/bond container and receiving equipment. P233 Keep container tightly closed.

2 Revision date : 2015/01/19 Page: 2/11 P243 P241 P242 P201 P210 P280 P281 Take precautionary measures against static discharge. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Precautionary Statements (Response): P391 Collect spillage. P308 + P313 IF exposed or concerned: Get medical advice/attention. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378 In case of fire: Use water spray for extinction. Precautionary Statements (Storage): P405 Store locked up. P403 + P235 Store in a well-ventilated place. Keep cool. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part Emergency overview FLAMMABLE LIQUID HARMFUL IF INHALED CAN CAUSE CENTRAL NERVOUS SYSTEM DAMAGE CAN CAUSE LIVER DAMAGE CAN CAUSE KIDNEY DAMAGE MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION MAY CAUSE PULMONARY EDEMA INGESTION MAY CAUSE GASTRIC DISTURBANCES 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part

3 Revision date : 2015/01/19 Page: 3/11 CAS Number Weight % Chemical name % stoddard solvent % vm&p naphtha According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Weight % Chemical name % vm&p naphtha % stoddard solvent % isopropyl alcohol 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. If breathing difficulties develop, aid in breathing and seek immediate medical attention. If on skin: Immediately wash thoroughly with soap and water. Seek medical attention. If in eyes: Flush with copious amounts of water for at least 15 minutes. Hold eyelids open to facilitate rinsing. If irritation develops, seek medical attention. Seek medical attention. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting due to aspiration hazard. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention is required. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Indication of any immediate medical attention and special treatment needed Note to physician

4 Revision date : 2015/01/19 Page: 4/11 Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: Dry extinguishing media Carbon dioxide Foam Water spray Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: Vapors and/or decomposition products are irritants and/or toxic. If product is heated above decomposition temperatures, acrid smoke and fumes will be released. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Vapors are heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition. Flash fire may occur. Remove product from areas of fire or otherwise cool sealed containers with water in order to avoid pressure build-up due to heat. Do not flood burning material with water due to potential spreading of fire. Contain contaminated water/firefighting water. Run-off water from fire may cause pollution. Notify proper authorities. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Extinguish sources of ignition nearby and downwind. Wear suitable personal protective clothing and equipment. Ensure adequate ventilation. Avoid prolonged inhalation. Avoid contact with skin and eyes.

5 Revision date : 2015/01/19 Page: 5/11 Use antistatic tools. Environmental precautions Do not discharge into drains/surface waters/groundwater. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. Methods and material for containment and cleaning up Dike spillage. Place into appropriately labeled waste containers. Spills should be contained, solidified, and placed in suitable containers for disposal. 7. Handling and Storage Precautions for safe handling Ensure adequate ventilation. Do not puncture, drop or slide containers. Use static lines when mixing and transferring material. Handle and open container with care. Avoid contact with the skin, eyes and clothing. WARNING: Empty containers may still contain hazardous residue. Do not apply to hot surfaces. Proper ventilation and respiratory protection is required when sanding, flame cutting, welding or brazing coated surfaces. Protection against fire and explosion: Use antistatic tools. Exhaust fans should be explosion proof. Provide adequate ventilation to remove solvent vapors from lower levels or work areas and to prevent solvent contact with ignition sources. Sealed containers should be protected against heat as this results in pressure build-up. Risk of explosion if heated under confinement. Avoid all sources of ignition: heat, sparks, or open flame. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from oxidizing agents. Segregate from strong bases. Segregate from strong acids. Further information on storage conditions: Keep container tightly closed. Protect from direct sunlight. Protect from temperatures above 49C/ 120F. Consult local fire marshal for storage requirements. Storage stability: 8. Exposure Controls and Personal Protection

6 Revision date : 2015/01/19 Page: 6/11 Components with occupational exposure limits isopropyl alcohol ACGIH STEL 400 ppm; TWA 200 ppm OSHA PEL 400 ppm 980 mg/m3 stoddard solvent ACGIH TWA 100 ppm OSHA PEL 500 ppm 2900 mg/m3 Advice on system design: Provide local exhaust ventilation to maintain recommended P.E.L. General mechanical ventilation should comply with OSHA Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear NIOSH-certified (or equivalent) organic vapor respirator. Particulate filters should be added during spray operations. Do not exceed the maximum use concentration for the respirator facepiece/cartridge combination. Observe OSHA regulations for respirator use (29 CFR ). Hand protection: Use appropriate chemically resistant gloves as determined by an evaluation of glove performance characteristics and the hazards and potential hazards identified, including but not limited to butyl, natural and synthetic rubber, nitrile, or neoprene. Eye protection: Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen based on activity level and exposure. General safety and hygiene measures: Work place should be equipped with a shower and eye wash. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift. 9. Physical and Chemical Properties Form: liquid Odour: aromatic Odour threshold: Colour: clear ph value: Melting temperature: Boiling range: F / C

7 Revision date : 2015/01/19 Page: 7/11 Sublimation temperature: Flash point: 45 F (7.2 C) +/- 3 F Setaflash Closed Cup (measured) Flammability: Lower explosion limit: not available Upper explosion limit: not available Autoignition: Vapour pressure: not available Density: 6.33 Lb/USg CALC Relative density: 0.76 Vapour density: heavier than air Partitioning coefficient n-octanol/water (log Pow): Thermal decomposition: Viscosity, dynamic: Viscosity, kinematic: > mm2/s Solubility in water: % volatiles: approx % / %(V) Solubility (quantitative): Solubility (qualitative): Evaporation rate: 10. Stability and Reactivity Reactivity Reactivity: Chemical stability Chemical stability: The product is chemically stable. Possibility of hazardous reactions Hazardous reactions: Conditions to avoid Conditions to avoid: Avoid all sources of ignition: heat, sparks or open flames. Avoid electrostatic discharge. Incompatible materials Substances to avoid: strong bases strong oxidizing agents strong acids Hazardous decomposition products

8 Revision date : 2015/01/19 Page: 8/11 Decomposition products: carbon monoxide carbon dioxide Thermal decomposition: 11. Toxicological Information Primary routes of exposure Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: stoddard solvent Assessment of acute toxicity: Aspiration may result in chemical pneumonitis, which may be fatal. Oral Acute oral toxicity: Inhalation Acute inhalation toxicity: Dermal Acute dermal toxicity: Assessment other acute effects Assessment of STOT single: Irritation / corrosion Assessment of irritating effects: Sensitization Assessment of sensitization:

9 Revision date : 2015/01/19 Page: 9/11 Aspiration hazard Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Genetic toxicity Assessment of mutagenicity: Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: vm&p naphtha Assessment of carcinogenicity: The substance caused cancer in animal studies. Reproductive toxicity Assessment of reproduction toxicity: Development Assessment of teratogenicity: Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Ecological Information 13. Disposal Considerations Waste disposal of substance Dispose of in accordance with national, state and local regulations. The use and processing of this product, or addition of other constituents, may cause it to be considered a hazardous waste. It is the waste generators responsibility to determine if a particular waste is hazardous under RCRA.

10 Revision date : 2015/01/19 Page: 10/11 Do not discharge into drains/surface waters/groundwater. Incinerate or dispose of in a RCRA licensed facility. Do not incinerate closed containers. Container disposal WARNING: Empty containers may still contain hazardous residue. Dispose of in accordance with national, state and local regulations. 14. Transport Information Reference Bill of Lading Land transport USDOT Sea transport IMDG Air transport IATA/ICAO 15. Regulatory Information Federal Regulations Registration status TSCA, US released / listed EPCRA 313 CAS number Weight % Chemical name isopropyl alcohol State regulations State RTK CAS Number Chemical name vm&p naphtha stoddard solvent isopropyl alcohol ,2,4-trimethylbenzene xylene benzene CA Prop. 65 WARNING: This product contains a chemical(s) known to the State of California to cause cancer and birth defects or other reproductive harm. HMIS III rating

11 Revision date : 2015/01/19 Page: 11/11 Health: 2 Flammability: 3 Physical hazard: Other information SDS prepared by: BASF NA Product Regulations SDS prepared on 2015/01/19 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.