Safety Data Sheet. Ammonium Iodide ACS. In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week)

Transcription

1 Safety Data Sheet Ammonium Iodide ACS 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Iodide ACS Synonyms/Generic Names: None Product Number: 0503 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information: (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION OSHA Hazards: Irritant Target Organs: None Signal Words: Warning Pictograms: GHS Classification: irritation Category 2 Eye irritation Category 2A Specific target organ toxicity- single exposure Category 3 GHS Label Elements, including precautionary statements: Hazard Statements: H315 H319 H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Precautionary Statements: P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. Revised on 10/18/2018 Page 1 of 6

2 P302+P352 P304+P340 P305+P351+P338 P312 P332+P313 P337+P313 P362+P364 P403+P233 P405 P501 IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER/doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local regulations. Potential Health Effects Causes eye irritation. Inhalation May be harmful if inhaled. Causes respiratory tract irritation. May be harmful if absorbed through skin. Causes skin irritation. Ingestion May be harmful if swallowed. NFPA Ratings Health 2 Flammability 0 Reactivity 0 Specific hazard HMIS Ratings Health 2 Fire 0 Reactivity 0 Personal 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % CAS # EINECS# / ELINCS# Formula Molecular Weight Ammonium Iodide > NH4I g/mol 4. FIRST-AID MEASURES Inhalation Ingestion Rinse with plenty of water for at least 15 minutes and seek medical attention if necessary. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. Flush with plenty of water and wash using soap. Get medical attention if necessary. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary. 5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Specific hazards arising from the chemical Product is not flammable. Use appropriate media for adjacent fire. Cool containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Emits toxic fumes (nitrogen oxides, hydrogen iodide, and ammonia) under fire conditions. (See also Stability and Reactivity section) Revised on 10/18/2018 Page 2 of 6

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up See section 8 for recommendations on the use of personal protective equipment. Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements. Pick up and arrange disposal without creating dust. Sweep up and place in suitable, closed containers for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts. Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Contains no substances with occupational exposure limit values. Personal Protection Wear chemical safety glasses or goggles. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear nitrile or rubber gloves, apron or lab coat. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limit Vapor pressure White solid at 50 g/l at 25 C (77 F) 551 C (1,024 F) Not Flammable Not Flammable Not Explosive 1 hpa (1 mmhg) at C (411.6 F) Revised on 10/18/2018 Page 3 of 6

4 Vapor density Relative density 2.51 g/cm 3 Solubility (ies) Soluble in water. Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable Will not occur. Air. Strong bases, strong acids. Nitrogen oxides, hydrogen iodide, Ammonia. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA as probable, possible or confirmed human carcinogen by IARC. as a carcinogen or potential carcinogen by ACGIH. as a known or anticipated carcinogen by NTP. as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Rash, irritation, pain. Redness, irritation, pain, watering eyes. Respiratory Runny nose, headache, irritation of mucous membrane. Ingestion Nausea, vomiting. Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization 12. ECOLOGICAL INFORMATION Ecotoxicity Aquatic Vertebrate Aquatic Invertebrate Terrestrial Revised on 10/18/2018 Page 4 of 6

5 Persistence and Degradability Bioaccumulative Potential Mobility in Soil PBT and vpvb Assessment Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Product or Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION US DOT TDG IMDG Marine Pollutant IATA/ICAO No 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 All ingredients are listed on the TSCA inventory. All ingredients are listed on the DSCL inventory. Acute Health Hazard Acute Health Hazard Revised on 10/18/2018 Page 5 of 6

6 16. OTHER INFORMATION Revision Date Revision 1 03/20/2013 Revision 2 07/31/2013 Revision 3 10/18/2018 Disclaimer: The information provided in this Safety Data Sheet ( SDS ) is correct to the best of our knowledge, information and belief at the date of publication. The information in this SDS relates only to the specific Product identified under Section 1, and does not relate to its use in combination with other materials or products, or its use as to any particular process. Those handling, storing or using the Product should satisfy themselves that they have current information regarding the particular way the Product is handled, stored or used and that the same is done in accordance with federal, state and local law. WE DO NOT MAKE ANY WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. WE DO NOT ASSUME RESPOSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT. Revised on 10/18/2018 Page 6 of 6