Material Safety Data Sheet

Transcription

1 Page 1 of 24 Material Safety Data Sheet Rebound 25 MSDS No. 868 Date Of Preparation: April 5, 2012 Revision: 0003 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Rebound 25 Part A General Use: Silicone Elastomer Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Section 2- Hazards Identification Not hazardous according to United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) and Council directive 1999/45/EC and its subsequent amendments. HMIS H 1 F 1 R 0 No hazardous ingredients Section 3 - Composition / Information on Ingredients Section 4 - First Aid Measures Inhalation: Remove source(s) of contamination and move victim to fresh air. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing and launder before reuse. Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician immediately After first aid, get appropriate in-plant, paramedic, or community medical support. Section 5 - Fire-Fighting Measures Flash Point: >300 F Flash Point Method: PMCC NFPA LEL: Not Established UEL: Not Established 1 Flammability Classification: Non-Flammable 1 0 Extinguishing Media: Dry Chemical, Carbon Dioxide, and Foam Unusual Fire or Explosion Hazards: None 0 Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressuredemand or positive-pressure mode. Item Numbers: Page 1 of 24

2 Page 2 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Section 6 - Accidental Release Measures Spill /Leak Procedures: Dike and contain spill; absorb or scrape up excess into suitable container for disposal. Stop or reduce discharge if it can be done safely. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR ). Section 7 - Handling and Storage Handling Precautions: Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator. Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eyeand face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.. Section 9 - Physical and Chemical Properties Physical State: Viscous Liquid Appearance : Off White viscous liquid Odor : Sweet odor Vapor Pressure: None (Polymeric Resin) Vapor Density (Air=1): >1 Specific Gravity (H2O=1, at 4 C): 1.17 Water Solubility: Insoluble Boiling Point: None (Polymeric Resin) % Volatile: Nil Freezing/Melting Point: None (Polymeric Resin) Viscosity: 300 poise Evaporation Rate: Not Applicable Section 10 - Stability and Reactivity Stability: This product is stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization can not occur. Chemical Incompatibilities: Strong bases, and acids. Hazardous Decomposition Products: Silica, carbon monoxide and carbon dioxide Item Numbers: Page 2 Page 2 of 24

3 Page 3 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Eye Effects: Irritation Skin Effects: Irritation None Established Section 11- Toxicological Information Carcinogenicity: None Determined Mutagenicity: None Determined Teratogenicity: None Determined Section 12 - Ecological Information Section 13 - Disposal Considerations Disposal: Must be disposed of in accordance with applicable Federal, state and local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated Not Regulated Not Regulated United States Regulations EPA Regulations: Section 15 - Regulatory Information RCRA Hazardous Waste Number: Not listed (40 CFR ) SARA Toxic Chemical (40 CFR ): None These products do not contain chemicals that are subject to release reporting requirements under section 313 of SARA Title III. TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA Inventory. California Proposition 65: This product does not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm. CANADA Regulations WHMIS Identification: Not controlled CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): All are Listed Labeling according to EEC Directive No special packaging or labeling requirements. Item Numbers: Page 3 of Page 24 3

4 Page 4 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Section 16 - Other Information Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives. Item Numbers: Page 4 Page 4 of 24

5 Page 5 of 24 Material Safety Data Sheet Rebound 25 MSDS No. 868 Date Of Preparation: April 5, 2012 Revision: 0003 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Rebound 25 Part B General Use: Silicone Elastomer Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Section 2- Hazards Identification Not hazardous according to United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) and Council directive 1999/45/EC and its subsequent amendments. HMIS H 1 F 1 R 0 No hazardous ingredients Section 3 - Composition / Information on Ingredients Section 4 - First Aid Measures Inhalation: Remove source(s) of contamination and move victim to fresh air. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing and launder before reuse. Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician immediately After first aid, get appropriate in-plant, paramedic, or community medical support. Section 5 - Fire-Fighting Measures Flash Point: >300 F Flash Point Method: PMCC NFPA LEL: Not Established UEL: Not Established 1 Flammability Classification: Non-Flammable 1 0 Extinguishing Media: Dry Chemical, Carbon Dioxide, and Foam Unusual Fire or Explosion Hazards: None 0 Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressuredemand or positive-pressure mode. Item Numbers: Page 5 of 24

6 Page 6 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Section 6 - Accidental Release Measures Spill /Leak Procedures: Dike and contain spill; absorb or scrape up excess into suitable container for disposal. Stop or reduce discharge if it can be done safely. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR ). Section 7 - Handling and Storage Handling Precautions: Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator. Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eyeand face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State: Viscous Liquid Appearance : Orange viscous liquid Odor : Sweet odor Vapor Pressure: None (Polymeric Resin) Vapor Density (Air=1): >1 Specific Gravity (H2O=1, at 4 C): 1.17 Water Solubility: Insoluble Boiling Point: None (Polymeric Resin) % Volatile: Nil Freezing/Melting Point: None (Polymeric Resin) Viscosity: 300 poise Evaporation Rate: Not Applicable Section 10 - Stability and Reactivity Stability: This product are stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization can not occur. Chemical Incompatibilities: Strong bases, and acids. Hazardous Decomposition Products: Silica, carbon monoxide and carbon dioxide Item Numbers: Page 6 Page 6 of 24

7 Page 7 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Eye Effects: Irritation Skin Effects: Irritation None Established Section 11- Toxicological Information Carcinogenicity: None Determined Mutagenicity: None Determined Teratogenicity: None Determined Section 12 - Ecological Information Section 13 - Disposal Considerations Disposal: Must be disposed of in accordance with applicable Federal, state and local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated Not Regulated Not Regulated United States Regulations EPA Regulations: Section 15 - Regulatory Information RCRA Hazardous Waste Number: Not listed (40 CFR ) SARA Toxic Chemical (40 CFR ): None These products do not contain chemicals that are subject to release reporting requirements under section 313 of SARA Title III. TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA Inventory. California Proposition 65: This product does not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm. CANADA Regulations WHMIS Identification: Not controlled CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): All are Listed Labeling according to EEC Directive No special packaging or labeling requirements. Item Numbers: Page 7 of Page 24 7

8 Page 8 of 24 MSDS No. 868 Rebound 25 Revision: 0003 Section 16 - Other Information Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives. Item Numbers: Page 8 Page 8 of 24

9 Page 9 of 24 Material Safety Data Sheet Smooth-Cast 300 Series MSDS No. 476 Date of Preparation: April 5, 2012 Revision: 0010 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Smooth-Cast 300, 300Q, 305 and 310 Part A General Use: Polyurethane Elastomer Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Hazard Designation: Section 2 - Hazards Identification Europe Xn = Harmful Canada Information pertaining to particular dangers R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin R40: Limited evidence of a carcinogenic effect R 1 R48/20: Harmful; danger of serious damage to health by prolonged exposure through inhalation Classified according to Articles 6 & 7of Directive 1999/45/EC Section 3 - Composition / Information on Ingredients Component ACGIH TWA OSHA PEL Hazard Designation Weight Percent (%) 4,4 Methylene ppm 0.02 ppm bis(phenylisocyanate) (MDI) CAS Number: EINECS Number: Xn Section 4 - First Aid Measures HMIS H 2 F 1 Inhalation: Remove source(s) of contamination and move victim to fresh air. If breathing has stopped, give artificial respiration, then oxygen if needed. Contact physician immediately. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing and launder before reuse; seek medical attention if rash develops. Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician immediately After first aid, get appropriate in-plant, paramedic, or community medical support. Item Numbers: Page 9 of 24

10 Page 10 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: 0010 Section 5 - Fire-Fighting Measures Flash Point: 262 F (128 C) NFPA Flash Point Method: COC LEL: Not Established 1 UEL: Not Established 2 1 Flammability Classification: Non-Flammable Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam 0 Unusual Fire or Explosion Hazards: Hazardous decomposition products may be formed. Avoid water contamination in closed containers or confined areas as exothermic heat and carbon dioxide can evolve. Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressuredemand or positive-pressure mode. Section 6 - Accidental Release Measures Spill /Leak Procedures: Only properly protected personnel should remain in the spill area; dike and contain spill; absorb or scrape up excess into suitable container for disposal; wash area with dilute ammonia solution. Stop or reduce discharge if it can be done safely. Section 7 - Handling and Storage Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper respiratory equipment. Avoid moisture contamination. Reseal partial containers. Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator. Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eyeand face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics Item Numbers: Page 2 Page 10 of 24

11 Page 11 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: 0010 Physical State: Liquid Appearance : Pale amber liquid Odor : Characteristic odor Vapor Pressure: 25 C Vapor Density (Air=1): 8.6 Specific Gravity (H2O=1, at 4 C): 1.10 Section 9 - Physical and Chemical Properties Water Solubility: Reacts with water Boiling Point: None determined % Volatile: Nil Freezing/Melting Point: None Determined Viscosity: 1 poise Evaporation Rate: Not Applicable Section 10 - Stability and Reactivity Stability: These products are stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization can occur. Chemical Incompatibilities: Strong bases, water, amines, alcohols. Conditions to Avoid: Avoid contamination with water and other materials that react with Isocyanates. Hazardous Decomposition Products: MDI vapors, hydrogen cyanide gas, oxides of nitrogen, carbon monoxide and carbon dioxide Section 11- Toxicological Information Hazardous Component LD50 Oral LC50 Inhalation 4,4 Methylene Mouse: 2200 mg/kg Rat: 178 mg/m 3 bis(phenylisocyanate) (MDI) Rat: 9200 mg/kg Section 12 - Ecological Information For MDI: Aquatic: Rapidly hydrolyzes to form an insoluble crust. Terrestrial: Will bind with moist soil no leaching will occur. Atmospheric: Remains in the vapor phase and half life is 32 hours. Will not biodegrade. Section 13 - Disposal Considerations Disposal: These materials must be disposed of in accordance with local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated Not Regulated Not Regulated United States EPA Regulations: Section 15 - Regulatory Information Clean Air Act SOCMI Chemical: 4, 4 Methylene bis(phenylisocyanate) Hap Code: XOV These products contain the following chemicals that are subject to release reporting requirements under section 313 of SARA Title III. Chemical Name CAS # % by Weight 4, 4 Methylene bis(phenylisocyanate) Max Item Numbers: Page 11 of Page 24 3

12 Page 12 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: 0010 Section 15 - Regulatory Information (Continued) TSCA Inventory Status (40 CFR710): All components of these formulations are listed in the TSCA Inventory. California Proposition 65: These products do not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm. Canadian Regulations; WHMIS Identification: D2A, D2B CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): Listed on CDSL Labeling according to EEC Directive Risk Phrases Symbol(s) Required for EU Label Safety Phrases R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin R40: Limited evidence of a carcinogenic effect R48/20: Harmful; danger of serious damage to health by prolonged exposure through inhalation (Xn = Harmful) S1/2: Keep locked up and out of reach of children S23: Do not breath vapors S36/37: Wear suitable protective equipment. S45: In case of an accident or if you feel sick, seek medical attention 16 - Other Information Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives Item Numbers: Page 4 Page 12 of 24

13 Page 13 of 24 Material Safety Data Sheet Smooth-Cast 300 Series MSDS No. 476 Date of Preparation: April 5, 2012 Revision: 0010 Section 1 - Chemical Product and Company Identification Product/Chemical Name Smooth-Cast 300, 300Q, 305 and 310 Part B General Use: Polyurethane Elastomer Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Section 2- Hazards Identification Not hazardous according to United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR ) and Council directive 1999/45/EC and its subsequent amendments HMIS H 1 F 1 R 0 No hazardous ingredients Section 3 - Composition / Information on Ingredients Section 4 - First Aid Measures Inhalation: Remove source(s) of contamination and move victim to fresh air. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing and launder before reuse. Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician immediately After first aid, get appropriate in-plant, paramedic, or community medical support. Section 5 - Fire-Fighting Measures Flash Point: 262 F (128 C) NFPA Flash Point Method: PMCC Flammability Classification: Non-Flammable 1 Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam Unusual Fire or Explosion Hazards: None 1 0 Fire-Fighting Instructions: Fire fighters should wear self-contained breathing 0 apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode. Item Numbers: Page 13 of 24

14 Page 14 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: 0010 Section 6 - Accidental Release Measures Spill /Leak Procedures: Dike and contain spill; absorb or scrape up excess into suitable container for disposal. Stop or reduce discharge if it can be done safely. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR ). Section 7 - Handling and Storage Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper respiratory equipment. Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator. Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eyeand face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: Clear colorless liquid Odor: Mild odor Vapor Pressure: None (Polymeric Resin) Vapor Density (Air=1): >1 Specific Gravity (H2O=1, at 4 C): 1.00 Water Solubility: Negligible: Boiling Point: None (Polymeric Resin) % Volatile: Nil Freezing/Melting Point: None Determined Viscosity: 1.2 poise Evaporation Rate: None (Polymeric Resin) Section 10 - Stability and Reactivity Stability: These products are stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization can not occur. Chemical Incompatibilities: Strong acids and oxidizers. Conditions to Avoid: Avoid contamination with water and other materials that react with amines. Thermal Decomposition Products: Oxides of nitrogen, carbon monoxide and carbon dioxide Item Numbers: Page 6 Page 14 of 24

15 Page 15 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: 0010 Acute Inhalation Effects: None established Acute Oral Effects: None Established Section 11- Toxicological Information Toxicity Data: Reproductive Toxicity: None Established Mutagenicity: None Established Teratogenicity: None Established Sensitization: None Established None Established Section 12 - Ecological Information Section 13 - Disposal Considerations Disposal: These materials must be disposed of in accordance with applicable local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated Not Regulated Not Regulated Section 15 - Regulatory Information US TSCA Inventory Status (40 CFR 710): All components of these product sare listed on the TSCA inventory. California Proposition 65: These products do not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm WHMIS Identification: Not controlled CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): All are Listed Labeling according to EEC Directive No special packaging or labeling requirements Item Numbers: Page 15 of Page 24 7

16 Page 16 of 24 MSDS No. 476 Smooth-Cast 300 Series Revision: Other Information Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives Item Numbers: Page 8 Page 16 of 24

17 Page 17 of 24 Material Safety Data Sheet Sonite Wax MSDS No. 915 Date of Preparation: February 22, 2012 Revision: 0011 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Sonite Wax General Use: Release Agent Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Hazard Designation: Europe Xn: Harmful Section 2 - Hazards Identification Canada HMIS H 1 F 2 R 0 Risk phrases pertaining to particular dangers: R53: May cause long term adverse effects in the aquatic environment R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking Classified according to Articles 6 & 7of Directive 1999/45/EC Section 3 - Composition / Information on Ingredients Component ACGIH TWA OSHA PEL Hazard Designation Alkanes, C9-12-iso- None None Established Established CAS Number: Xn EINECS Number: Section 4 - First Aid Measures Weight Percent (%) 70-75% Inhalation: Remove source(s) of contamination and move victim to fresh air. If breathing has stopped, give artificial respiration, then oxygen if needed. Contact physician immediately. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water. Ingestion: Ingestion is unlikely route of exposure. Do not induce vomiting unless instructed by a physician. After first aid, get appropriate in-plant, paramedic, or community medical support. Item Numbers: Page 17 of 24

18 Page 18 of 24 MSDS No. 915 Sonite Wax Revision: 0011 Section 5 - Fire-Fighting Measures Flash Point: >104 F (>40 C) NFPA Flammable Limits: LEL: 1.2 Note: Approximate UEL: 9.6 Note: Approximate 2 Flash Point Method: TCC Autoignition Temperature: 559 F (293 C) Note: Approximate 1 0 Flammability Classification: Flammable Liquid 0 Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam Unusual Fire or Explosion Hazards: None Fire and Explosion Hazards: Vapors confined in a poorly ventilated area may be ignited by a spark or flame. Vapors may travel considerable distances to source of ignition. Vapors are heavier than air and may accumulate in low areas. Containers may rupture or explode under fire conditions. Hazardous decomposition products may be formed. Material can accumulate static charges, which can cause an incendiary electrical discharge. Empty containers retain product residue and can be dangerous. Fire-Fighting Instructions: Use dry chemical, foam or CO 2; water may be ineffective but should be used to keep containers cool. Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressuredemand or positive-pressure mode. Section 6 - Accidental Release Measures Spill /Leak Procedures: Only properly protected personnel should remain in the spill area; dike and contain spill; absorb or scrape up excess into suitable container for disposal; wash area with dilute ammonia solution. Stop or reduce discharge if it can be done safely. Section 7 - Handling and Storage Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper respiratory equipment. Avoid moisture contamination. Reseal partial containers. Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standards EN 141, 143 and 371; wear an MSHA/NIOSH or European Standards EN 141, 143 and 371 approved respirators. Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas. Protective Clothing/Equipment: Wear chemically protective gloves and aprons to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Item Numbers: Page 2 Page 18 of 24

19 Page 19 of 24 MSDS No. 915 Sonite Wax Revision: 0011 Section 8 - Exposure Controls / Personal Protection (continued) Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9 Physical and Chemical Properties Product Form: Soft Paste Appearance and Odor: Yellow, slight ethereal odor Specific Gravity: 0.78 Section 10 - Stability and Reactivity Water Solubility: Insoluble Boiling Point: >311 F (155 C) Evaporation Rate (BuAc=1): 0.16 Stability: This product is stable at room temperature. Polymerization: Hazardous polymerization cannot occur. Hazardous Decomposition Products: Thermal oxidative decomposition can produce; carbon monoxide, carbon dioxide and hydrocarbons. Section 11- Toxicological Information Hazardous Component LD50 Oral LC50 Skin Alkanes, C9-12-iso mg/kg 3160 mg/kg Section 12 - Ecological Information Ecotoxicity: May cause long term adverse effects in the aquatic environment. Mobility; Material is highly volatile, will partition to air. Not expected to partition to sediment and wastewater solids. Vapors are expected to degrade rapidly in air. Section 13 - Disposal Considerations Disposal: This material must be disposed of in accordance with local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated In Containers of 119 Gallons Capacity or Less Shipping Name: Hydrocarbons, Liquid, N.O.S. Hazard Label: Flammable (Isodecane & isoundecane) UN #: 3295 Hazard Class: 3 Packing Group: III Shipping Name: Hydrocarbons, Liquid, N.O.S. Hazard Label: Flammable (Isodecane & isoundecane) UN #: 3295 Hazard Class: 3 Packing Group: III Item Numbers: Page 19 of Page 24 3

20 Page 20 of 24 MSDS No. 915 Sonite Wax Revision: 0011 Section 15 - Regulatory Information United States EPA Regulations: SARA Toxic Chemical (40 CFR ): None SARA EHS (Extremely Hazardous Substance) (40 CFR 355): None TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA Inventory. States Right To Know, Substance List: California Proposition 65: This product does not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm. Canadian Regulations: WHMIS Identification: CLASS D-2B: Material causing other toxic effects (TOXIC). Labeling according to EEC Directive Risk Phrases Symbol(s) Required for EU Label Safety Phrases R53: May cause long term adverse effects in the aquatic environment R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking Xn: Harmful 16 - Other Information S23: Do not breathe vapor. S24: Avoid contact with skin. S33: Take precautionary measures against static discharge. S43: In case of fire use chemical, foam or CO 2; water may be ineffective but should be used to keep containers cool. S62: If swallowed do not induce vomiting. Seek medical advice immediately and show this label. Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Mann Release Technologies Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives. Item Numbers: Page 4 Page 20 of 24

21 Page 21 of 24 Material Safety Data Sheet THI-VEX MSDS No. 839 Date Of Preparation: November 5, 2014 Revision: 0005 Section 1 - Chemical Product and Company Identification Product/Chemical Name: THI-VEX General Use: Silicone Elastomer Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA Phone (610) , FAX (610) Emergency Contact: Chem-Tel Domestic International Section 2- Hazards Identification Not hazardous according to United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) and Council directive 1999/45/EC and its subsequent amendments. No hazardous ingredients Section 3 - Composition / Information on Ingredients Section 4 - First Aid Measures Inhalation: Remove source(s) of contamination and move victim to fresh air. Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing and launder before reuse. Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician immediately After first aid, get appropriate in-plant, paramedic, or community medical support. Section 5 - Fire-Fighting Measures HMIS H 1 F 1 R 0 Flash Point: >356 F (180 C) Flash Point Method: PMCC NFPA LEL: Not Established UEL: Not Established 1 Flammability Classification: Non-Flammable 1 0 Extinguishing Media: Dry Chemical, Carbon Dioxide, and Foam Unusual Fire or Explosion Hazards: None 0 Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressuredemand or positive-pressure mode. Item Numbers: Page 21 of 24

22 Page 22 of 24 MSDS No. 839 THI-VEX Revision: 0005 Section 6 - Accidental Release Measures Spill /Leak Procedures: Dike and contain spill; absorb or scrape up excess into suitable container for disposal. Stop or reduce discharge if it can be done safely. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR ). Section 7 - Handling and Storage Handling Precautions: Use good general housekeeping procedures. Storage Requirements: Store in cool dry, well-ventilated area. Section 8 - Exposure Controls / Personal Protection Respiratory Protection: Follow OSHA respirator regulations 29 CFR and European Standards EN 141, 143 and 371; wear an MSHA/NIOSH or European Standards EN 141, 143 and 371 approved respirators. Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eyeand face-protection regulations 29 CFR and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State: Viscous Liquid Appearance : Pale-Yellow viscous liquid Odor : Mild odor Vapor Pressure: None (Polymeric Resin) Vapor Density (Air=1): >1 Specific Gravity (H2O=1, at 4 C): 0.96 Water Solubility: Soluble Boiling Point: None (Polymeric Resin) % Volatile: Nil Freezing/Melting Point: 19 F (-7 C) Viscosity: 18 poise Evaporation Rate: Not Applicable Section 10 - Stability and Reactivity Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization can not occur. Chemical Incompatibilities: Strong bases, and acids. Hazardous Decomposition Products: Silica, carbon monoxide and carbon dioxide Item Numbers: Page 2 Page 22 of 24

23 Page 23 of 24 MSDS No. 839 THI-VEX Revision: 0005 Eye Effects: Irritation Skin Effects: Irritation None Established Section 11- Toxicological Information Carcinogenicity: None Determined Mutagenicity: None Determined Teratogenicity: None Determined Section 12 - Ecological Information Section 13 - Disposal Considerations Disposal: Must be disposed of in accordance with applicable Federal, state and local regulations. Section 14 - Transport Information DOT IATA IMDG Not Regulated Not Regulated Not Regulated United States Regulations EPA Regulations: Section 15 - Regulatory Information RCRA Hazardous Waste Number: Not listed (40 CFR ) SARA Toxic Chemical (40 CFR ): None These products do not contain chemicals that are subject to release reporting requirements under section 313 of SARA Title III. TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA Inventory. California Proposition 65: This product does not intentionally contain any chemicals which have been identified by the state of California to cause cancer, birth defects or other reproductive harm. CANADA Regulations WHMIS Identification: Not controlled CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): All are Listed Labeling according to EEC Directive No special packaging or labeling requirements. Item Numbers: Page 23 of Page 24 3

24 Page 24 of 24 MSDS No. 839 THI-VEX Revision: 0005 Section 16 - Other Information Disclaimer: The information contained in this MSDS is considered accurate as of the version date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability of the product for its intended application and assumes all risk and liability for its safe use. This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS), and European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication Standard (29 CFR ), the Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union (EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union Directives. Item Numbers: Page 4 Page 24 of 24