GHS SAFETY DATA SHEET (SDS)

Transcription

1 GHS SAFETY DATA SHEET (SDS) SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT: Part #1786 Nylon Bagging Film, Above 300 F FIBRE GLAST DEVELOPMENTS CORP. 385 CARR DRIVE BROOKVILLE, OH TELEPHONE: (937) FAX: (937) FOR CHEMICAL EMERGENCY CALL (800) HRS. RECOMMENDED USE: Soft co-extruded Nylon with Ultra High Elongation for use with Standard Composite Manufacturing SECTION 2 HAZARDS IDENTIFICATION Emergency Overview Form Color Odor Hazard Summary : film : clear or coloured : odourless : No hazards resulting from the material as supplied. Can release irritating and/or toxic vapors at elevated processing temperatures or if involved in a fire. POTENTIAL HEALTH HAZARDS Skin Contact: Eye Contact: Ingestion: Chronic Exposure: No hazards resulting from the material supplied. No hazards resulting from the material supplied. May cause mechanical irritation. Unlikely route of exposure. Elevated processing temperatures may generate fumes and vapors which may cause irritation None known. Carcinogenicity

2 No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. % of Ingredient Nylon 6 Homopolymer CAS % Nylon 6, 6/6 Copolymer CAS % Thermoplastic Elastomer CAS Trade Secret 10-40% Colorants and Stabilizers CAS Trade Secret 0-3% SECTION 4 FIRST AID MEASURES Inhalation: No hazards which require special first aid measures. If exposed to vapors at elevated processing temperatures, remove to fresh air. Skin Contact: No hazards which require special first aid measures. Eye Contact: Ingestion: No hazards which require special first aid measures. If material comes into contact with the eye, flush eyes with water while holding eyelids apart to ensure complete irrigation. Unlikely route of exposure. No hazards which require special first aid measures. Consult a physician if necessary. SECTION 5 FIRE FIGHTING MEASURES Suitable extinguishing media Specific hazards during Firefighting Special protective equipment for Firefighters : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : The solid polymer can only be burned with difficulty. Forms or accumulates static electricity, may cause fire or explosion. May combust when in contact with naked flames, high temperature. In case of fire hazardous decomposition products may be produced such as: Caprolactam Ammonia Hydrogen cyanide (hydrocyanic acid) Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit SECTION 6 ACCIDENTAL RELEASE MEASURES

3 Personal precautions: Environmental precautions: Methods for cleaning up: Wear personal protective equipment. Do not allow run-off from fire fighting to enter drains or water courses. Place spilled material in an appropriate container for disposal. SECTION 7 HANDLING AND STORAGE Handling Handling: Advice on protection against fire and explosion: Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Keep away from heat and sources of ignition. Storage Requirements for storage Areas and containers: Keep in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Keep away from direct sunlight. Store away from incompatible substances. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures: General room ventilation is adequate for storage and handling. Use adequate ventilation and/or engineering controls in high temperature processing to prevent exposure to vapors. Wear as appropriate: Safety glasses with side-shields. When handling hot material, use heat resistant gloves. Wear heat protective clothing for handling hot material. No personal respiratory protective equipment normally required. In the case of vapor formation use a respirator with an approved filter. Handle in accordance with good industrial hygiene and safety practice. Exposure Guideline ε-caprolactam TWA : time weighted average 5 mg/m ACGIH:US. ACGIH Threshold Limit Values Form of exposure: Inhalable fraction and vapor ε-caprolactam REL : 1 mg/m3 Recommended (0.22 ppm) 2005 NIOSH/GUIDE:US.

4 (REL): ε-caprolactam STEL : Short 3 mg/m3 (0.66 ppm) exposure limit 2005 NIOSH/GUIDE:US. ε-caprolactam REL : Recommended (REL): 1 mg/m NIOSH/GUIDE:US. ε-caprolactam STEL : Short exposure limit 3 mg/m NIOSH/GUIDE:US. ε-caprolactam TWA : time weighted average 1 mg/m Z1A:US. OSHA ε-caprolactam TWA : time 20 mg/m3 weighted (5 ppm) average 1989 Z1A:US. OSHA ε-caprolactam STEL : Short 3 mg/m Z1A:US. OSHA ε-caprolactam STEL : Short 40 mg/m3 (10 ppm) 1989 Z1A:US. OSHA

5 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Physical Status: Color: Odor: ph: Vapor Pressure: Vapor Density: Boiling Point: Freezing/Melting Point: Water Solubility: Spec. Grav./Density: Ignition temperature: Film clear or coloured No odor N/A Note: Negligible at ambient temperature. Note: no data available, (Air=1.0) N/A Not deined Negligible g/cm3 > 410 O C Decomposition temperature: > 275 O C SECTION 10 STABILITY AND REACTIVITY Stability: Possibility of hazardous reactions: Conditions to avoid: Materials to avoid (Incompatibility): Hazardous Decomposition Products: Stable under normal conditions. Hazardous polymerization does not occur. Heat, flames and sparks. Keep away from direct sunlight. Avoid exposure to temperatures exceeding recommended processing conditions. Honeywell should be contacted if questions arise concerning specific processing conditions. Strong oxidizers. In case of fire hazardous decomposition products may be produced such as: Caprolactam Ammonia Hydrogen cyanide (hydrocyanic acid) Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). SECTION 11 TOXICOLOGICAL INFORMATION Immediate (Acute) Effects: Delayed (Sub-chronic and chronic) Effects: Other Data: Not deined None Known None

6 SECTION 12 ECOLOGICAL INFORMATION Material is considered inert and not expected to be biodegradable or toxic. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in compliance with Federal, State and Local government regulations. Usually is considered an inert packaging material that can be recycled or landfilled. SECTION 14 TRANSPORT INFORMATION US DOT Hazard Class: US DOT ID Number: Not regulated Not applicable SECTION 15 REGULATORY INFORMATION Inventories US Toxic Substances Control Act Australia. Industrial Chemical (Notification and Assessment Act) Canada, Canadian Environmental Protection Act (CEPA) Domestic Substances List (DSL) (Can. Gaz. Part II. Vol. 133) Japan. Kashin-Hou Law List: Korea. Toxic Chemical Control Law (TCCL) List Philippines. The Toxic Substances And Hazardous and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances EU. EINECS National Regulatory Information SARA 311/312 HAZARDS California Prop. 65 No SARA This product does not contain any chemicals known to State of California to cause cancer, birth or any other reproductive defects.

7 WHMIS Classification Not Rated SECTION 16 OTHER INFORMATION HMIS III NFPA Health Hazard O O Flammability 1 1 Physical Hazard O O Instability O O The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with Fibre Glast Developments or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances.