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1 This is a kit that contains the following components: EUCO 512 VOX EPOXY SEALER PART A EUCO 512 VOX EPOXY SEALER PART B 1/26

2 SAFETY DATA SHEET 1. Identification Product identifier: EUCO 512 VOX EPOXY SEALER PART A Product Code: Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information EUCLID CHEMICAL COMPANY REDWOOD ROAD CLEVELAND OH US Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Skin sensitizer Category 1 Unknown toxicity - Health Acute toxicity, oral % Acute toxicity, dermal % Acute toxicity, inhalation, vapor 99.3 % Acute toxicity, inhalation, dust 99.3 % or mist Unknown toxicity - Environment Acute hazards to the aquatic environment Chronic hazards to the aquatic environment 99.3 % 100 % Label Elements Hazard Symbol: 2/26

3 Signal Word: Hazard Statement: Warning May cause an allergic skin reaction. Precautionary Statements Prevention: Response: Disposal: Hazard(s) not otherwise classified (HNOC): Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see this label). Wash contaminated clothing before reuse. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Bisphenol A Polyglycidyl Ether Resin <10% 1-Methoxy-2-Propanol <5% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Rinse mouth thoroughly. Move to fresh air. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention. Rinse immediately with plenty of water. Most important symptoms/effects, acute and delayed 3/26

4 Symptoms: Hazards: Indication of immediate medical attention and special treatment needed Treatment: 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 4/26

5 7. Handling and storage Precautions for safe handling: Avoid contact with eyes, skin, and clothing. Wash hands thoroughly after handling. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities: Store away from incompatible materials. Store in original tightly closed container. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source 1-Methoxy-2-Propanol TWA 50 ppm US. ACGIH Threshold Limit Values ( ) STEL 100 ppm US. ACGIH Threshold Limit Values ( ) Chemical name type Exposure Limit Values Source 1-Methoxy-2-Propanol TWA 50 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (072007) STEL 75 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (072007) 1-Methoxy-2-Propanol TWA 50 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) STEL 100 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 1-Methoxy-2-Propanol TWA 100 ppm 369 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (122008) STEL 150 ppm 553 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (122008) Appropriate Engineering Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Use personal protective equipment as required. Wear goggles/face shield. Use suitable protective gloves if risk of skin contact. Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. 5/26

6 Respiratory Protection: Hygiene measures: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. Observe good industrial hygiene practices. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: White Odor: Mild Odor threshold: ph: 7.96 Melting point/freezing point: Initial boiling point and boiling range: > 100 C > 212 F Flash Point: > 93 C > 200 F(Pensky-Martens Closed Cup) Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.1 Solubility(ies) Solubility in water: Insoluble in water Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Material is stable under normal conditions. 6/26

7 Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Avoid heat or contamination. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Eye contact: Ingestion: May cause an allergic skin reaction. Eye contact is possible and should be avoided. May be ingested by accident. Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: Skin Contact: Eye contact: Ingestion: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal Inhalation Specified substance(s): 1-Methoxy-2-Propanol ATEmix: 46, mg/kg ATEmix: 7, mg/kg Not classified for acute toxicity based on available data. LC 50 (Rat): 54.6 mg/l Repeated dose toxicity Skin Corrosion/Irritation 7/26

8 Specified substance(s): Bisphenol A Polyglycidyl Ether Resin in vivo (Rabbit): Slightly irritating Experimental result, Key study 1-Methoxy-2-Propanol in vivo (Rabbit): Not irritant Experimental result, Key study Serious Eye Damage/Eye Irritation Specified substance(s): Bisphenol A Polyglycidyl Ether Resin Rabbit, 24 hrs: Slightly irritating 1-Methoxy-2-Propanol Rabbit, hrs: Not irritating Respiratory or Skin Sensitization Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure 8/26

9 Aspiration Hazard Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) 9/26

10 Mobility in soil: Other adverse effects: 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. OSHA Specifically Regulated Substances (29 CFR ) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity 1-Methoxy-2-Propanol Reportable quantity 100 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate (Acute) Health Hazards 10/26

11 SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity 1-Methoxy-2-Propanol 100 lbs. SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Bisphenol A Polyglycidyl lbs Ether Resin 1-Methoxy-2-Propanol lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. US State Regulations US. California Proposition 65 No ingredient regulated by CA Prop 65 present. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity 1-Methoxy-2-Propanol US. Massachusetts RTK - Substance List Chemical Identity 1-Methoxy-2-Propanol US. Pennsylvania RTK - Hazardous Substances Chemical Identity 1-Methoxy-2-Propanol US. Rhode Island RTK Chemical Identity 1-Methoxy-2-Propanol International regulations Montreal protocol not applicable Stockholm convention not applicable Rotterdam convention not applicable 11/26

12 Kyoto protocol not applicable VOC: When appropriately mixed with the other part, product has a VOC less water and exempt solvent of: 68 g/l Regulatory VOC (less water and exempt solvent) : 175 g/l VOC Method 310 : 2.33 % 12/26

13 Inventory Status: Australia AICS: Canada DSL Inventory List: EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: All components in this product are listed on or exempt from the Inventory. All components in this product are listed on or exempt from the Inventory. 16.Other information, including date of preparation or last revision Version #: 2.0 Further Information: 13/26

14 Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 14/26

15 SAFETY DATA SHEET 1. Identification Product identifier: EUCO 512 VOX EPOXY SEALER PART B Product Code: Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information EUCLID CHEMICAL COMPANY REDWOOD ROAD CLEVELAND OH US Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Skin sensitizer Category 1 Unknown toxicity - Health Acute toxicity, oral % Acute toxicity, dermal % Acute toxicity, inhalation, vapor 100 % Acute toxicity, inhalation, dust 99 % or mist Acute hazards to the aquatic environment Chronic hazards to the aquatic environment % 100 % Label Elements Hazard Symbol: 15/26

16 Signal Word: Hazard Statement: Warning May cause an allergic skin reaction. Precautionary Statements Prevention: Response: Disposal: Hazard(s) not otherwise classified (HNOC): Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see this label). Wash contaminated clothing before reuse. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Isophoronediamine <1% m-xylenediamine <1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Call a POISON CENTER/doctor/.../if you feel unwell. Rinse mouth. Move to fresh air. If skin irritation occurs: Get medical advice/attention. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention. Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. 16/26

17 Most important symptoms/effects, acute and delayed Symptoms: Hazards: Indication of immediate medical attention and special treatment needed Treatment: 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 17/26

18 7. Handling and storage Precautions for safe handling: Avoid contact with eyes, skin, and clothing. Wash hands thoroughly after handling. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities: Store away from incompatible materials. Store in original tightly closed container. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source m-xylenediamine Ceiling 0.1 mg/m3 US. ACGIH Threshold Limit Values (2011) None of the components have assigned exposure limits. Appropriate Engineering Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Use personal protective equipment as required. Wear goggles/face shield. Use suitable protective gloves if risk of skin contact. Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Observe good industrial hygiene practices. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: White Odor: Mild Odor threshold: ph: /26

19 Melting point/freezing point: Initial boiling point and boiling range: > 100 C > 212 F Flash Point: > 93 C > 200 F(Pensky-Martens Closed Cup) Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.1 Solubility(ies) Solubility in water: Insoluble in water Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Material is stable under normal conditions. Avoid heat or contamination. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Eye contact: Ingestion: Causes mild skin irritation. May cause an allergic skin reaction. Eye contact is possible and should be avoided. May be ingested by accident. Ingestion may cause irritation and malaise. 19/26

20 Symptoms related to the physical, chemical and toxicological characteristics Inhalation: Skin Contact: Eye contact: Ingestion: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Specified substance(s): Isophoronediamine Not classified for acute toxicity based on available data. LD 50 (Rat): 1,030 mg/kg m-xylenediamine LD 50 (Rat): 930 mg/kg Dermal Specified substance(s): Isophoronediamine Not classified for acute toxicity based on available data. LD 50 (Rat): > 2,000 mg/kg m-xylenediamine LD 50 (Rabbit): 2,000 mg/kg Inhalation Specified substance(s): Isophoronediamine Not classified for acute toxicity based on available data. LC 50 (Rat): > 5.01 mg/l m-xylenediamine LC 50 (Rat): 1.16 mg/l Repeated dose toxicity Skin Corrosion/Irritation 20/26

21 Specified substance(s): m-xylenediamine in vivo (Rat): Corrosive Experimental result, Weight of Evidence study Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard Other effects: 21/26

22 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates Specified substance(s): Isophoronediamine EC 50 (Water flea (Daphnia magna), 24 h): mg/l Intoxication Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Mobility in soil: Other adverse effects: 22/26

23 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. OSHA Specifically Regulated Substances (29 CFR ) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Ethylene glycol Reportable quantity 5000 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate (Acute) Health Hazards SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Ethylene glycol 5000 lbs. 23/26

24 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Isophoronediamine lbs m-xylenediamine lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Ethylene glycol Developmental toxin US. New Jersey Worker and Community Right-to-Know Act No ingredient regulated by NJ Right-to-Know Law present. US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances No ingredient regulated by PA Right-to-Know Law present. US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. International regulations Montreal protocol not applicable Stockholm convention not applicable Rotterdam convention not applicable Kyoto protocol not applicable VOC: When appropriately mixed with the other part, product has a VOC less water and exempt solvent of: 68 g/l 24/26

25 Regulatory VOC (less water and exempt solvent) : 2 g/l VOC Method 310 : 0.02 % Inventory Status: Australia AICS: Canada DSL Inventory List: EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: All components in this product are listed on or exempt from the Inventory. All components in this product are listed on or exempt from the Inventory. 16.Other information, including date of preparation or last revision Version #: /26

26 Further Information: Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 26/26

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