WARNING! Harmful if inhaled, absorbed through skin, or swallowed. Causes skin, eye and respiratory irritation.

Transcription

1 Finished Goods Catalog / Chemical Name: Emerald JR-PJ Manufacturer Name: Anchor Lithkemko, a subsidiary of Fuji Hunt 1 PRODUCT AND COMPANY IDENTIFICATION Product Number: Anchor Lithkemko, a subsidiary of Fuji Hunt 50 Industrial Loop North Orange Park FL Intended Use: Fountain Solution for Commercial Printers Emergency Telephone: Medical Emergency (24HR): Prosar Transport ER Ph. (outside NA): (Accepts collect calls) Transport ER Ph. (inside NA): Non-emergency Telephone: EHS Hotline: (M-F 8:30am - 5pm) General Information: (M-F 8:30am - 5pm) EST 2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Green Odor: Mild WARNING! Harmful if inhaled, absorbed through skin, or swallowed. Causes skin, eye and respiratory irritation. Potential Health Effects Inhalation: Harmful by inhalation. Irritating to respiratory system. Eye Contact: Irritating to eyes. Exposed may experience eye tearing, redness, and discomfort. Skin Contact: Harmful if absorbed through skin. Irritating to skin. Ingestion: Harmful if swallowed. Chronic Health Effects: Chronic overexposure to butyl cellosolve in high concentrations has caused anemia, liver and blood abnormalities, and kidney and lung damage in laboratory animals; may cause maternal toxicity. May cause central nervous system effects. Gum arabic as dust: May cause inhalation hypersensitivity (occupational asthma) in sensitive individuals. Target Organ(s): Respiratory system Eye Kidney Lung Liver Blood. Skin Central nervous system. Page: 1 of 7

2 Potential Physical / Chemical Effects: This product is not flammable. OSHA Regulatory Status: When used for its intended purpose, this material is classified as hazardous in accordance with OSHA 29CFR Environment: Not regarded as an environmental hazard under current legislation. 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Concentration* Water % Propylene glycol % % Gum arabic % % Ammonium nitrate % Malic acid % * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. This chemical is hazardous according to OSHA/WHMIS criteria. 4 FIRST AID MEASURES Inhalation: Move into fresh air and keep at rest. If breathing stops, provide artificial respiration. Get medical attention immediately. Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention immediately. Skin Contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Ingestion: Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Get immediate medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable Extinguishing Media: None. Special Fire Fighting Procedures: Use standard firefighting procedures and consider the hazards of other involved materials. Unusual Fire & Explosion Hazards: None known. Hazardous Combustion Products: Carbon Oxides, Nitrogen Oxides Protective Measures: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. Self contained breathing apparatus and full protective clothing Page: 2 of 7

3 must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid inhalation of vapors and contact with skin and eyes. Wear suitable protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Spill Cleanup Methods: Absorb in vermiculite, dry sand or earth and place into containers. Environmental Precautions: Avoid discharge into drains, water courses or onto the ground. Notification Procedures: Inform Authorities if large amounts are involved. 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing mists or vapors. Work practice should minimize contact. Use only in well-ventilated areas. Observe good industrial hygiene practices. Storage: Store between 10 C and 37.7 C. Keep container in a well-ventilated place. Keep from freezing. Keep container tightly closed and dry. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: Chemical Name Source Type Exposure Limits Notes ACGIH STEL 15 ppm ACGIH TWA 10 ppm NIOSH Guide Concentration 50 ppm US. OSHA Table TWA 10 ppm 25 mg/m³ Z-1 ACGIH TWA 20 ppm NIOSH Guide Concentration 700 ppm US. OSHA Table TWA 50 ppm 240 mg/m³ Skin Z-1 Engineering Controls: Adequate ventilation should be provided so that exposure limits are not exceeded. Observe good industrial hygiene practices. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Eye Protection: Wear approved safety goggles. Hand Protection: Wear chemical-resistant gloves. Contact glove manufacturer for specific information. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Page: 3 of 7

4 Skin Protection: Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Green Odor: Mild Odor Threshold: No data available. Physical State: Liquid ph: 4 Melting Point: No data available. Freezing Point: No data available. Boiling Point: 100 C (212 F) Flash Point: >93 C (200 F) Evaporation Rate: <1 Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor Pressure: 17.4 mmhg Vapor Density (Air=1): > 1 Specific Gravity: Solubility in Water: Completely soluble in water Solubility (Other): No data available. Partition Coefficient (n-octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): 2.07 lbs/gal Percent Volatile: 87 %w 10 STABILITY AND REACTIVITY Stability: Stable under normal temperature conditions Conditions to Avoid: Excessive heat. Avoid frost. This product contains an ammonia compound. Mixing of this product with household or industrial bleaches (Sodium Hypochlorite) can result in the release of hazardous or toxic gases. Inhalation of these gases may cause severe respiratory irritation. Incompatible Materials: Strong oxidizing agents. Sodium hypochlorite. Strong acids. Strong Bases Hazardous Decomposition Products: At Elevated Temperatures: Ammonia, Maleic Acid, Maleic Anhydride Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Specified Substance(s) Acute Toxicity: Page: 4 of 7

5 Component Chemical Name Test Results Dermal LD50 (Rabbit): 220 mg/kg Inhalation LC50 (4 hour(s), Rat): 450 ppm (v) Oral LD50 (Rat): 470 mg/kg Dermal LD50 (Rabbit): 1060 mg/kg Inhalation LC50 (Mouse): 5620 ppm (v) Oral LD50 (Rat): 3310 mg/kg Ammonium nitrate Oral LD50 (Rat): 2217 mg/kg Gum arabic Oral LD50 (Rat): >16 g/kg Malic acid Oral LD50 (Rat): 3200 mg/kg Propylene glycol Dermal LD50 (Rabbit): mg/kg Propylene glycol Oral LD50 (Rat): mg/kg Chronic Toxicity: Gum arabic as dust: May cause respiratory allergy. Listed Carcinogens: Chemical Name IARC NTP OSHA ACGIH Not Listed Not Listed Not Listed A3 ACGIH: A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen. Product Information Other Acute: Harmful if inhaled, absorbed through skin, or swallowed. Causes skin, eye and respiratory irritation. Chronic Toxicity: Chronic overexposure to butyl cellosolve in high concentrations has caused anemia, liver and blood abnormalities, and kidney and lung damage in laboratory animals; may cause maternal toxicity. May cause central nervous system depression. 12 ECOLOGICAL INFORMATION Ecotoxicity: No data available. Mobility: The product is miscible with water. May spread in water systems. Persistence and Degradability: No data available. Bioaccumulation Potential: No data available 13 DISPOSAL CONSIDERATIONS General Information: Dispose of waste and residues in accordance with local authority requirements. Disposal Instructions: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. 14 TRANSPORT INFORMATION DOT Not Regulated TDG Not Regulated Page: 5 of 7

6 IATA Not Regulated IMDG Not Regulated 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D1B, D2B Mexican Dangerous Statement: This is a Mexican "dangerous" product. Inventory Status This product or all components are listed on the following inventory: TSCA US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Name RQ 5000 lbs SARA Title III Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): None Section 311/312 (40 CFR 370): X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): Chemical Name CAS-No. Concentration % Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): None Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Drug Enforcement Act: None TSCA: No component is listed on TSCA Sections 4(a), 5(a)(2), 5(e) or 12(b). State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None Massachusetts Right-To-Know List: ; Ammonium nitrate; Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): None Page: 6 of 7

7 Minnesota Hazardous Substances List: ; ; Propylene glycol New Jersey Right-To-Know List: ; Ammonium nitrate; ; Gum arabic Pennsylvania Right-To-Know List: ; Ammonium nitrate; ; Propylene glycol Rhode Island Right-To-Know List: ; Ammonium nitrate; ; Propylene glycol 16 OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Reactivity Hazard Special Hazard NFPA Health Hazard Fire Hazard Reactivity Hazard Personal Protection HMIS 2* 1 0 B 0 - Minimal; 1- Slight; 2 - Moderate; 3 - Serious; 4 - Severe *- Chronic Health Effect B - Safety Glasses & Gloves Issued by: Issue Date: 21-Jun-2006 Supercedes Date: Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. Page: 7 of 7