Material Safety Data Sheet acc. to ISO 11014

Transcription

1 Page 1/6 1 Identification of substance Product details Product number: NET UC Application of the substance / the preparation Laboratory chemicals Manufacturer/Supplier: PerkinElmer Life and Analytical Sciences 710 Bridgeport Avenue Shelton, CT Information department: Technical Support Emergency information: If inside, call CHEMTREC at If outside, call CHEMTREC at Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: ethanol % 3 Hazards identification Hazard description: Highly flammable Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of international guidelines. Highly flammable. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. NFPA ratings (scale 0-4) Health = 0 Fire = 3 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 3 Reactivity = 0 (Contd. on page 2)

2 Page 2/6 (Contd. of page 1) 4 First aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately rinse with water. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Seek medical treatment. 5 Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: Wear self-contained respiratory protective device. 6 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. 7 Handling and storage Handling: Information for safe handling: Store in cool, dry place in tightly closed receptacles. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: ethanol PEL REL TLV 1900 mg/m³, 1000 ppm 1900 mg/m³, 1000 ppm Short-term value: 1880 mg/m³, 1000 ppm Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) Breathing equipment: Suitable respiratory protective device recommended. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties General Information Form: Color: Odor: Fluid According to product specification Characteristic Change in condition Melting point/melting range: C (-174 F) Boiling point/boiling range: 78 C (172 F) Flash point: 21 C ( 70 F) Ignition temperature: 425 C (797 F) Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: 3.5 Vol % Upper: 15 Vol % Vapor pressure at 20 C (68 F): 59 hpa (44 mm Hg) Density at 20 C (68 F): 0.79 g/cm³ Solubility in / Miscibility with Water at 20 C (68 F): 1 g/l ph-value: N/A Solvent content: Organic solvents: % VOC content: % (Contd. on page 4)

4 Page 4/6 (Contd. of page 3) 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided: Dangerous reactions No dangerous reactions known. Dangerous products of decomposition: No dangerous decomposition products known. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: May cause skin irritation. on the eye: May cause eye irritation. Sensitization: No sensitizing effects known. 12 Ecological information Other information: N/A 13 Disposal considerations Product: Recommendation: Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information DOT regulations: Hazard class: 3 Identification number: UN1170 Packing group: II Proper shipping name (technical name): ETHANOL SOLUTION Label 3 Land transport ADR/RID (cross-border): ADR/RID class: 3 Flammable liquids Danger code (Kemler): 33 UN-Number: 1170 (Contd. on page 5)

5 Page 5/6 Packaging group: II Label: 3 Description of goods: 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Maritime transport IMDG: (Contd. of page 4) IMDG Class: 3 UN Number: 1170 Label 3 Packaging group: II EMS Number: F-E,S-D Marine pollutant: No Propper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: 1170 Label 3 Packaging group: II Proper shipping name: ETHANOL SOLUTION 15 Regulations Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: All ingredients are listed. (Contd. on page 6)

6 Page 6/6 Cancerogenity categories EPA (Environmental Protection Agency) (Contd. of page 5) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) ethanol A3 NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Highly flammable Risk phrases: Highly flammable. Safety phrases: Keep container tightly closed and in a well-ventilated place. Keep away from sources of ignition - No smoking. This material and its container must be disposed of as hazardous waste. 16 Other information The information provided in this is based on our present knowledge, and believed to be correct at the date of publication. However, no representation is made concerning its accuracy and completeness. It is intended as guidance only, and is not to be considered a warranty or quality specification. All materials may present unknown hazards, and should be used with caution. Although certain hazards are described, we cannot guarantee that these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held liable for any damage resulting from handling or from contact with the product. Department issuing MSDS: EHS Contact: Technical Support