Section 1 - Product Information. Section 2 - Hazards Identification

Transcription

1 SAFETY DATA SHEET Section 1 - Product Information Product Name: RUST REMOVER 371 Product Code: Manufactured By: T&L Specialty Company Inc. 3 Airpark Road Tupelo, MS Hour Emergency Telephone: CHEMTREC: (8) Telephone: (662) Product Use: Rust Remover Section 2 - Hazards Identification GHS Ratings: Skin corrosive 1A Destruction of dermal tissue: Exposure < 3 min. Observation < 1 hour, visible necrosis in at least one animal Eye corrosive 1 Serious eye damage: Irreversible damage 21 days after exposure, Draize score: Corneal opacity >= 3, Iritis > 1.5 Carcinogen 1B Presumed Human Carcinogen, Based on demonstrated animal carcinogenicity GHS Hazards H314 H318 H35 Causes severe skin burns and eye damage Causes serious eye damage May cause cancer GHS Precautions P21 P22 P26 P264 P28 P281 P31 P321 P363 P31+P33+P331 P33+P361+P353 P34+P34 Obtain special instructions before use Do not handle until all safety precautions have been read and understood Do not breathe dust/fume/gas/mist/vapours/spray Wash thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Use personal protective equipment as required Immediately call a POISON CENTER or doctor/physician Specific treatment (see on this label) Wash contaminated clothing before reuse IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing SDS for: Page 1 of 5 Printed: 7/22/216 at 7:1:22AM

2 P35+P351+P338 P38+P313 P45 P51 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do continue rinsing IF exposed or concerned: Get medical advice/attention Store locked up Dispose of contents/container to comply with all local, state and federal regulations Signal Word: Danger Section 3 - Composition / Information on Ingredients Chemical Name CAS number Weight Concentration % Phosphoric Acid % Sulfuric Acid % Inhalation: Eye Contact: SECTION 4 - FIRST AID MEASURES If inhaled, remove to fresh air. Get medical attention if symptoms occur. Flush eyes with water for 15 minutes. Get medical attention if symptoms persist. Skin Contact: In case of contact with substance, immediately flush skin with running water. Remove and isolate contaminated clothing and shoes. If skin irritatin continues get medical attention. Ingestion: Do NOT induce vomiting without medical advice. Drink water as a precaution. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Notes to Physician - Treatment: Treat symptomatically. Flash Point: Not Applicable LEL: Flammable Limits: Section 5 - Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use water jet at and extinguisher, as this may spread the fire. Unusual Fire Hazards: No unusual fire or explosion hazards noted. Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Do not use direct water stream which may spread fire. Fire Fighting Equipment: Self-Contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. UEL: SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Keep unnecessary personnel away fro spill/leak. Wear appropriate personal protective equipment (PPE) and clothing during clean up. Do not breathe mist or vapror. Ensure adequate ventilation. Environmental Precations: Do not contaminate water sources or sewer. Prevent further leakage ro spillage. Inform environmental manager of all major spills. SDS for: Page 2 of 5

3 Small Spills: Wipe up with absorbent material such as pet litter, sand, vermiculite. Clean surface thoroughly to remove residual contamination. Large Spills: Stop the flow of material. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb with vermiculite, dry sand, earth, or appropriate absorbant and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water and clean thoroughly. SECTION 7 - HANDLING AND STORAGE Handling Precautions: Wear appropriate personal protective equipment. Do not swallow. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. Storage Conditions: Keep containers tightly closed in a dry, cool and well ventilated place. Protect from excessive heat. Keep from freezing. Store only in approved containers. SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits Phosphoric Acid Sulfuric Acid mg/m3 TWA 3 mg/m3 STEL NIOSH: 1 mg/m3 TWA 1 mg/m3 TWA 3 mg/m3 STEL 1 mg/m3 TWA.2 mg/m3 TWA (thoracic NIOSH: 1 mg/m3 TWA fraction) Engineering Controls Use local exhaust ventilation or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. Hygene Measures: Emergency equipment nearby and immediately accessible, with instructions for use. Ensure that eyewash stations and safetyshowers are close and accessible to the workstation location. Use clean, well maintained personal protection equipment. Personal Protective Equipment: Respiratory Protection: Wear appropriate respirator when ventilation is inadequate. Hand Protection: Use gloves chemically resistant to this material (Neoprene, NItrile, PVC) Eye Protection: Chemical safety glasses. Chemical face shield should be worn in case of contact through splashing. Skin and Body Protection: Wear appropriate clothing to avoid direct skin contact. Remove and wash contaminated clothing before wearing agian. Contaminated Gear: Contaminated work clothing or personal protection equipment (PPE) should not be allowed out of the workplace. Before reuse, thoroughly clean clothing and PPE. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear Light Brown Liquid Vapor Pressure:.71 mmhg Odor: Acrid Odor threshold: Not Determined Vapor Density: N/A ph: 1.5 Specific Gravity: 1.3 Freezing point: Not Determined Boiling range: Not Determined Melting point: Not Determined Solubility: Complete Flash point: Not Applicable SDS for: Page 3 of 5

4 Evaporation rate: Not Determined Explosive Limits: Not Determined Autoignition temperature: Not Determined Viscosity: Not Determined Flammability: Not Applicable Partition coefficient (noctanol/water): Not Determined Decomposition temperature: Not Determined Grams VOC less water: Not Determined Materials to Avoid: SECTION 1 - STABILITY AND REACTIVITY Hazardous Decomposition: Hazardous polymerization will not occur. Mixture Toxicity Oral Toxicity LD5: 3,17mg/kg Inhalation Toxicity LC5: 41mg/L SECTION 11 - TOXICOLOGICAL INFORMATION Component Toxicity Phosphoric Acid Oral LD5: 1,53 mg/kg (Rat) Dermal LD5: 2,74 mg/kg (Rabbit) Oral LD5: 2,14 mg/kg (Rat) Inhalation LC5: 51 mg/m3 (Rat) Routes of Entry: Target Organs: Eyes Skin Respiratory System Effects of Overexposure Carcinogenicity: The following chemicals comprise.1% or more of this mixture and are listed and/or classified as carcinogens or potential carcinogens by NTP, IARC, OSHA (mandatory listing), or ACGIH (optional listing). CAS Number Description % Weight Carcinogen Rating 1 Sulfuric Acid: IARC: Human carcinogen IARC: Human carcinogen OSHA: listed Acute Toxicity: SECTION 12 - ECOLOGICAL INFORMATION Component Ecotoxicity Sulfuric Acid 96 Hr LC5 Brachydanio rerio: >5 mg/l [static] SECTION 13 - DISPOSAL CONSIDERATIONS Disposal Instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers or water supplies. Dispose or contents and container in acordance with all local, regional, national, and international regulations. For used, contaminated and residual materials, additional evaluations may be required. Local Disposal Regulations: SDS for: Page 4 of 5

5 Dispose in accordance with all applicable regulations. Waste From Residues/Unused Products: Dispose of in accordance with local regulations. Empty containers may retain some product residues. This material and its container must be disposed or in a safe manner. Contaminated Packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Empty containers may retain product residue, follow label warnings even after container is emptied. SECTION 14 - TRANSPORT INFORMATION Agency Proper Shipping Name UN Number Packing Group Hazard Class DOT CORROSIVE LIQUID, NOS (PHOSPHORIC ACID) 176 II 8 SECTION 15 - REGULATORY INFORMATION The following chemicales are reportable under the New Jersey Right to Know Act: Phosphoric Acid The following chemicals are reportable under SARA 313: Country Regulation All Components Listed - None SECTION 16 - OTHER INFORMATION Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) 3 X Flammability HMIS & NFPA Hazard Rating Legend * = Chronic Health Hazard Health = INSIGNIFICANT 3 1 = SLIGHT 2 = MODERATE 3 = HIGH Special Instability T&L Specialty Company, Inc. urges each reciepient of this SDS to study and consult with the appropriate expertise to become aware of and understand the data contained within and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate. No warranty, express or implied, is given. It is the buyer's/user's responsibility to ensure that all activities comply with all federal, state and local laws. It is the buyer's/user's responsibility to determine the conditions necessary for the safe use of this product. Date revised: Date Prepared: 7/22/216 Reviewer Revision 1 SDS for: Page 5 of 5