SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product number Product name Effective date Company information telephone US Emergency telephone outside US Version# Emergency overview C-139 De Aqua Lube 08/01/17 Baton Rouge Industries, Inc Groom Road Baker, LA Hazards Identification Aerosol. CONTENTS UNDER PRESSURE. Cancer hazard. Irritating to skin. Irratating to eyes. Irratating to respiratory system. Prolonged exposure may cause chronic effects. Potential heath effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Skin contact. Eye contact. Inhalation. Irritating to eyes. May be harmful if absorbed through skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Irratating to skin. Intentional muse by concentrating and inhaling the product can be harmful or fatal. Irritating to respiratory system. Prolonged inhalation may be harmful. Exposure by ingestion of an aerosol is unlikely. Components of the product may be absorbed into the body by ingestion. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged and may cause blood damage. These effects have not been observed in humans. Liver. Kidneys. Central nervous system. Lungs. Chronic effects Signs and symptoms Unconsciousness. Conjunctiva. May be harmful if absorbed through skin. Liver injury may occur. Kidney injury may occur. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision} and/or damage. May cause delayed lung injury. Discomfort in the chest. Narcosis. Coughing. Liver enlargement. Jaundbe. Conjunctivitis. Defatting of the skin. Skin irrtation. 3. Composition / Information on Ingredients Components CAS # Percent Trichloroethybne Carbon Dioxide 2-Butoxyethanol 1,2-Butybne Oxide _ 0.5 Non-hazardous and other components below reportable levels _ First Aid Measures First au procedures Eye contact Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Immediately flush skin with plenty of water. Remove and isolate contaminated clothing and shoes. Call a physician or Poison Control Center immediately. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. M SOS US Revision date: 08/01/17 Print date: 08/01/17 1/ 6

2 Inhalation Ingestion Notes to physician Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-tomouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician or Poison Control Center immediately. Never give anything by mouth to a victim who is unconscious or is having convulsions. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not induce vomiting without advice from poison control center. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical deve. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. In case of shortness of breath, give oxygen. Keep vbtirn under observation. Symptoms may be delayed. 5.Fire Fighting Measures Flammable properties Protection of firefighters Protective equipment and precautions for firefighters Not flammable by OSHA criteria. Not combustible by OSHA criteria. Containers should be cooled with water to prevent vapor pressure bulb up. Move containers from fire area if you can do so without risk. 6.Accidental Release Measures Methods for containment Methods for cleaning up ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Move the cylinder to a safe and open area if the leak is irreparable. Stop the flow of material, if the is without risk. Small Spills: WO up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. 7. Handling and Storage Handling Storage Pressurized container: Do not pierce or burn, even after use. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not smoke while using or until sprayed surface is thoroughly cy. Do not use if spray button is musing or defective. Do not re-use empty containers. Avoid breathing dust/fume/gas/mist/vapors/spray. Contents under pressure. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Do not expose to heat or store at temperatures above 120 `F/49 C as can may burst. Keep away from heat, sparks and open flame. Avoid exposure to long periods of sunlight. Level 1 Aerosol (NFPA 308) 8. Exposure Controls / Personal Protection Exposure limits ACGIH Components CAS# TWA STEL Ceiling Trichloroethylene ppm 25 ppm Not established Carbon Dioxide ppm ppm Not established 2-Butoxyethanol ppm Not established Not established OSHA Components CAS# TWA STEL Ceiling Trchloripethyene ppm Not established 200 ppm Carbon Dioxide ppm Not established Not established 2-Butoxyethanol ppm Not established Not established Personal protective equipment Eye face protection Skin protection Chemical goggles are recommended. Wear tight-fitting goggles or face shield. Wear appropriate chemical resistant clothing. Chemical resistant gloves. kisosus Revision date: 08/01/17 Print date: 08/01/17 2 / 6

3 Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-suppled respirator. 9. Physical & Chemical Properties Appearance Boiling point Color Density Flammability (HOC) Flash back Flash point Form Freezing point Odor Physical state Pressure Solubility Specifc gravi ty Cloudy. 284 F (140 '0) estimated Brown g/cm3 estimated kjig estimated No None (Propellant) Aerosol. Not available Solvent. Liquid. 90 Partially estimated Chemical stability Conditions to avoid 10. Chemical Stability & Reactivity Information Material is stable under normal conditions. Heat, flames and sparks. Hazardous decomposition products Irrtants. Toxc gas. Component analysis - LD50 Toxicology Data Selected LD50s and LC5Os 11. Toxicological Information 1,2-Butylene Oxide Inhalation LC50 Rat 6.3 mgil 4 h ; Oral LD50 Rat 500 mg/kg; Dermal LD50 Rabbit 1757 mg,kg 2-Butoxyethanol Inhalation LC50 Rat 221 mg/l 4 h; Inhalation LC50 Rat 450 ppm 4 h; Oral LD50 Rat 470 mgkg; Dermal LD50 Rat 2270 mg/kg; Dermal LD50 Rabbit 220 mg/kg Trichloroethylene Inhalation LC50 Rat 8000 ppm 4 h; Inhalation LC50 Rat ppm 1 h; Oral LD50 Rat 4290 mg/kg; Dermal LD50 Rabbit 20 gikg Carcinogenicity [ARC -Group 2A (Probably Carcinogenic to Humans) Hazardous by OSHA criteria. Risk of cancer cannot be excluded with prolonged exposure. Trichloroethylene Monograph 63 [1995]; Supplement 7 [1987] IA RC - Group 2B (Possibly Carcinogenic to Humans) 1,2-Butylene Oxide Monograph 71 [1999]; Monograph 47 [1989] (overall evaluation upgraded from 3 to 2B with supporting evidence from other relevant data) 12. Ecological Information Ecotoxicity Components of this product are hazardous to aquatic life. 13. Disposal Considerations Waste codes Disposal instructions D040: Waste Trichbroethyene Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material and its container to hazardous or special waste collection point. msosus Revision date: 08/01/17 Print date: 08/01/17 3 / 6

4 Department of Transportation (COT) Requirements Basic shipping requirements: 14. Transport Information Proper shipping name Hazard class UN number Additional information: Special provisions Packaging exceptions Packaging non bulk Packaging bulk Further information IMOG Basic shipping requirements: Proper shipping name Aerosols 22 UNI None None This product meets the exception requirements of section as a limied quantity and may be shipped as a lirnted quantity. Unti112/31/2013, the "Consumer Commodity- ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the kilted quantity diamond mark on cartons after 12/31/13 and may be used now in place of the "Consumer Commodity ORM-D" marking but not concurrently. AEROSOLS IATA Hazard class 2.2 Subsidiary hazard class 6.1 UN number 1950 Additional information: Packaging exceptions Item NOTa LTD QTY 5T Labels required Transport Category Basic shipping requirements: Proper shipping name Hazard class 2_2 Subsidiary hazard class 6.1 UN number 1950 Additional information: Packaging exceptions Labels required US federal regulations If <1 L: Consumer Commodity Aerosols, non-flammable, containing substances in Division 6.1, Packing Group Ill NOT a LTD QTY U.S.- CERCLA/SAHA- Section 313- Emission Reporting 15. Regulatory Information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR ,2-Butylene Oxide % de minimis concentration 2-Butoxyethanol % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less, orr = phenyl or akyl substtuted phenyl, R' = H or al kyl C7 or less, or OR consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) Trichloroethylene /0 de rriniat concentration Occupational Safety and Health Administration 29 CFR hazardous Yes chemical CERCLA (Superfund) reportable quantity Trichloroethylene: ,2-Butybne Oxide: (OSHA) kisosus Revision date: 08/01/17 Print date: 08/01/17 4 / 6

5 Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 extremely No hazardous substance Yes Section 311 hazardous chemical Hazard categories (311/312) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Inventory status Revision date: 08/01/17 Print date: 08/01/17 5 of 6

6 Country(s) or region inventory (yes/no)* China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of New and Existing Chemicals (EI NEC S) Europe Japan Korea European List of Notified Chemical Substances (ELINCS) Inventory of Ex sting and New Chemical Substances (ENCS) Existing Chemicals List (ECL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations State of California to cause WARNING: This product contains a chemical known to the cancer. U.S.- Pennsylvania- RTK (Right to Know) List 1,2-Butylene Oxide Environmental hazard 2-Butoxyethanol Present Carbon Dioxide Present Trichbroethylene Environmental hazard Further information HMIS ratings Health: 2* Flammability: 2 Physical hazard: 0 Disclaimer the best of our Prepared by 16. Other Information HMIS is a registered trade and service mark of the NPCA. The information provided in this Safety Data Sheet is correct to knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handing, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication, The information given is designed only as a guidance for safe handing, use, processing, storage. transportation, disposal and release and is not to be considered a warranty or quality specification, The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Regulatory Compliance OS US Revision date: 08/01/17 Print date: 08/01/17 6 of 6