Issue Date: 31-Oct-2012 Revision Date: 02-Nov-2012 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION. Physical State Liquid
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1 Safety Data Sheet Issue Date: 31-Oct-2012 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # UN/ID No Chlora Brite OWENS-14 UN1791 Recommended use of the chemical and restrictions on use Recommended Use Cleaning agent. Details of the supplier of the safety data sheet Supplier Address Owens Distributors 2850 W. Airport Blvd Sanford, FL Info@OwensDistributors.com Website: Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) INFOTRAC (International) (North America) Classification 2. HAZARDS IDENTIFICATION Physical State Liquid Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Harmful if swallowed Causes severe skin burns and eye damage Page 1 / 8
2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do not induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Very toxic to aquatic life with long lasting effects Very toxic to aquatic life First Aid Measures 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician immediately. Wash off immediately with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician immediately. Rinse mouth. Do not induce vomiting. Call a poison center or doctor/physician if you feel unwell. Most important symptoms and effects Symptoms Causes eye irritation. Causes skin irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Page 2 / 8
3 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Precautions for safe handling Advice on Safe Handling Prevent further leakage or spillage if safe to do so. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Wash face, hands, and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Use personal protection recommended in Section 8. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up. Acids. Amines. Ammonium salts. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines No exposure limits noted for ingredient(s) Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Wear approved safety goggles. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Do not breathe gas/fumes/vapor/spray. General Hygiene Considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Do not eat, drink or smoke when using this product. Page 3 / 8
4 Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Odor Color Odor Threshold Property Values Remarks Method ph Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Soluble in water Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials Acids. Amines. Ammonium salts. Hazardous Decomposition Products None known based on information supplied. 10. STABILITY AND REACTIVITY Page 4 / 8
5 Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes severe eye damage. Causes severe skin burns. Avoid breathing vapors or mists. Harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 8200 mg/kg ( Rat ) > mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Contact will cause irritation and redness to exposed areas. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Carcinogenic potential is unknown. Chemical Name ACGIH IARC NTP OSHA Group 3 Legend IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" Numerical measures of toxicity Page 5 / 8
6 Ecotoxicity Very toxic to aquatic life with long lasting effects. 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms 0.095: 24 h Skeletonema : 96 h Pimephales costatum mg/l EC50 promelas mg/l LC50 flowthrough : 96 h Pimephales promelas mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 flow-through : 96 h Oncorhynchus mykiss mg/l LC50 flowthrough : 96 h Oncorhynchus mykiss mg/l LC50 semi-static : 96 h Oncorhynchus mykiss mg/l LC50 static Crustacea 2.1: 96 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static Persistence/Degradability. Bioaccumulation. Mobility Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. Page 6 / 8
7 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1791 Proper Shipping Name Hypochlorite solutions Hazard Class 8 Packing Group II Reportable Quantity (RQ) 100 lbs IATA UN/ID No UN1791 Proper Shipping Name Hypochlorite solutions Hazard Class 8 Packing Group II IMDG UN/ID No UN1791 Proper Shipping Name Hypochlorite solutions Hazard Class 8 Packing Group II International Inventories US Federal Regulations CERCLA 15. REGULATORY INFORMATION Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ SARA 313 CWA (Clean Water Act) Component ( 100 ) CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 100 lb X US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X Page 7 / 8
8 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards Flammability Flammability Instability Physical Hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 31-Oct Nov-2012 New product Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8
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