SAFETY DATA SHEET according to Regulation (EC) No. 1907/ BOND+SEAL BLACK 300ML

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name : BOND+SEAL BLACK 300ML Product code : MSDS-Identcode : Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Adhesives, Sealant 1.3 Details of the supplier of the safety data sheet Company : Würth Handelsges.m.b.H. Würth Strasse Böheimkirchen Austria address: thomas.meindorfer@wuerth.at Telephone : +43 (0) Telefax : +43 (0) Responsible/issuing person : address: prodsafe.wurth@sap.com 1.4 Emergency telephone number Vergiftungs-Informations-Zentrale +43 (0) Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Sensitising R42: May cause sensitization by inhalation. 2.2 Label elements Labelling according to EC Directives: 1999/45/EC Hazard symbols : Harmful R-phrase(s) : R42 May cause sensitization by inhalation. S-phrase(s) : S23 Do not breathe vapour. S45 In case of accident or if you feel unwell, seek 1 / 15

2 S51 S60 medical advice immediately (show the label where possible). Use only in well-ventilated areas. This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: Special labelling of certain mixtures : Contains isocyanates. See information supplied by the manufacturer. 2.3 Other hazards 3. Composition/information on ingredients 3.1 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Classification (67/548/EEC) Registration number xylene R Xn; R20/21 Xi; R38 Classification (1272/2008/EC) Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 Concentration [%] >= 2 - < 3 low boiling point hydrogen treated naphtha R N; R51/53 Xn; R65 R66-R67 Flam. Liq. 3; H226 STOT SE 3; H336 Asp. Tox. 1; H304 Aquatic Chronic 2; H411 >= 2 - < 2,5 4,4'-methylenediphenyl diisocyanate Carc.Cat.3; R Xn; R20-R48/20 Xi; R36/37/38 R42/43 Acute Tox. 4; H332 Skin Irrit. 2; H315 Resp. Sens. 1; H334 Skin Sens. 1; H317 Carc. 2; H351 STOT SE 3; H335 STOT RE 2; H373 >= 0,75 - < 1 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section / 15

3 4. First aid measures 4.1 Description of first aid measures General advice If inhaled In case of skin contact In case of eye contact If swallowed : Symptoms of poisoning may appear several hours later. Call a doctor immediately if allergic signs, particularly in the respiratory tract, are observed. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. : If breathed in, move person into fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. : In case of contact, immediately flush skin with soap and plenty of water. Do NOT use solvents or thinners. If skin irritation persists, call a physician. : Protect unharmed eye. If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, seek medical advice immediately and show this container or label. If swallowed, DO NOT induce vomiting. If a person vomits when lying on his back, place him in the recovery position. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. : High volume water jet 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under fire condi- 3 / 15

4 tions (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Avoid inhalation of vapour or mist. Immediately evacuate personnel to safe areas. 6.2 Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Do not flush with water. Clean contaminated surface thoroughly. 6.4 Reference to other sections see chapter: 7, 8, 11, 12 and Handling and storage 7.1 Precautions for safe handling Advice on safe handling : For personal protection see section 8. Use with local exhaust ventilation. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Handle with care. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. 4 / 15

5 Advice on protection against fire and explosion : Normal measures for preventive fire protection. Dust explosion class : not applicable 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in a well-ventilated place. Do not keep the container sealed. Advice on common storage Other data : Keep away from food, drink and animal feedingstuffs. Never allow product to get in contact with water during storage. : No decomposition if stored and applied as directed. 7.3 Specific end use(s) 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Control parameters Basis Update xylene TMW: 221 mg/m3, 50 ppm H, KZW: 442 mg/m3, 100 ppm H, KZW: 0,1 mg/m3, 0,01 ppm Sah, TMW: 0,05 mg/m3, 0,005 ppm Sah, AT OEL AT OEL Components CAS-No. Control parameters Basis Update xylene TWA: 221 mg/m3, 50 ppm skin, STEL: 442 mg/m3, 100 ppm skin, 2000/39/EC Other information on limit values: see chapter Exposure controls Engineering measures 5 / 15

6 Provide sufficient air exchange and/or exhaust in work rooms. Highly effective exhaust ventilation Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Hand protection Material Material : butyl-rubber : Nitrile rubber Remarks Eye protection : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. : In case of splash hazard, please wear protective goggles. Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Avoid breathing vapors, mist or gas. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6 / 15

7 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : paste Colour : black Odour : characteristic Odour Threshold Flash point : > 70 C Method: closed cup Ignition temperature Thermal decomposition Lower explosion limit Upper explosion limit Explosive properties Flammability (solid, gas) Oxidizing properties Auto-ignition temperature Burning number Molecular Weight ph Vapour pressure Density : ca. 1,26 g/cm3 at 20 C Bulk density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Flow time Impact Sensitivity Relative vapor density Surface tension Evaporation rate Minimum ignition energy Acid number Refraction index Miscibility in water Solvent separation test 9.2 Other information None known. : insoluble : not applicable 7 / 15

8 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability The product is chemically stable Possibility of hazardous reactions Stability : No decomposition if stored and applied as directed. Mixture reacts slowly with water resulting in evolution of CO2. Evolution of CO2 in closed containers causes overpressure and produces a risk of bursting Conditions to avoid 10.5 Incompatible materials Materials to avoid : Water, Oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products : Halogenated compounds, Carbon oxides, Metal oxides 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity: low boiling point hydrogen treated naphtha : LD50 rat: > mg/kg : LD50 rat: > mg/kg Acute inhalation toxicity: xylene : LC50 : > mg/l Test atmosphere: vapour Exposure time: 4 h : LC50 rat: > 2,24 mg/l Test atmosphere: dust/mist 8 / 15

9 Acute dermal toxicity: Exposure time: 1 h LC50 rat: 0,49 mg/l Test atmosphere: dust/mist Exposure time: 4 h Note: Harmful by inhalation. xylene : LD50 : > mg/kg : LD50 rabbit: > mg/kg Acute toxicity (other routes of administration): Skin corrosion/irritation xylene low boiling point hydrogen treated naphtha : Severe skin irritation : Repeated exposure may cause skin dryness or cracking. : Species: rabbit irritating Serious eye damage/eye irritation Respiratory or skin sensitization Sensitisation Germ cell mutagenicity Genotoxicity in vitro: Genotoxicity in vivo: : Species: rabbit Eye irritation : May cause sensitization by inhalation. Carcinogenicity Remarks : Carcinogenicity: Limited evidence of carcinogenicity in animal studies Mutagenicity: 9 / 15

10 Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Reproductive toxicity : Note: No evidence of adverse effects on sexual function and fertility, and on development, based on animal experiments /when indicated) Teratogenicity STOT - single exposure low boiling point hydrogen treated naphtha STOT - repeated exposure : May cause drowsiness or dizziness. : May cause respiratory irritation. : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Aspiration toxicity low boiling point hydrogen treated naphtha : May be fatal if swallowed and enters airways. Neurological effects Toxicology Assessment Toxicology, Metabolism, Distribution Acute effects Further information : Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with isocyanates. 10 / 15

11 12. Ecological information 12.1 Toxicity Toxicity to fish : LC0 (Oryzias latipes (Orange-red killifish)): > mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > mg/l Exposure time: 24 h Method: OECD Test Guideline 202 Toxicity to algae : EC50 : > mg/l Exposure time: 72 h NOEC : mg/l Exposure time: 72 h Toxicity to bacteria : EC50 : > 100 mg/l Exposure time: 3 h Test Method: Respiration inhibition of activated sludge Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: >= 10 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Ecotoxicology Assessment Chronic aquatic toxicity low boiling point hydrogen treated naphtha : Toxic to aquatic life with long lasting effects Persistence and degradability 12.3 Bioaccumulative potential 11 / 15

12 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Additional ecological information : The product should not be allowed to enter drains, water courses or the soil. 13. Disposal considerations 13.1 Waste treatment methods Advice on disposal and packaging : Disposal: In accordance with local and national regulations. Do not dispose of waste into sewer. This material and its container must be disposed of as hazardous waste. Do not dispose of together with household waste. Waste codes should be assigned by the user based on the application for which the product was used. The following Waste Codes are only suggestions: Waste Code (EWC) : Waste Key (unused product): , waste isocyanates Waste key (used product): , waste isocyanates Disposal of uncleaned packaging : Waste key (uncleaned packaging): , packaging containing residues of or contaminated by dangerous substances Note: Empty containers should be taken to an approved waste handling site for recycling or disposal. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Dispose of as unused product. 14. Transport information ADR Not dangerous goods RID Not dangerous goods 12 / 15

13 IATA Not dangerous goods IMDG Not dangerous goods Special precautions for user see chapter: 6, 7 and Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture VOC : Directive 1999/13/EC 3,46 % Directive (96/82/EC) : Update: 2003 Quantity 1 Quantity 2 Petroleum products: (a) gasolines and naphthas, (b) kerosenes (including jet fuels), (c) gas oils (including diesel fuels, home heating oils and gas oil blending streams) t t National legislation Fire Hazard Class : A III Other regulations Further information : Take note of Dir 94/33/EC on the protection of young people at work. : Ensure a continuous supply of fresh air during and after operation. Persons who suffer from allergies or who have a chronic disposition to respiratory illness must not be required to work with this material. Reserved for industrial and professional use Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 13 / 15

14 R10 Flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R42 May cause sensitization by inhalation. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Full text of H-Statements referred to under sections 2 and 3. H226 H304 H312 H315 H317 H332 H334 H335 H336 H351 H373 H411 Other information Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. H Sah skin Risk of skin absorption Danger of sensitization of the respiratory system and the skin Identifies the possibility of significant uptake through the skin The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by : SAP Business Compliance Services GmbH Birlenbacher Str. 19 D Siegen Germany Telephone: +49-(0) Ref.: WIAG / 15

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