SAFETY DATA SHEET. Polywater Europe BV Zuidhaven 9-11 Unit B CR Zevenbergen Netherlands Tel: +31 (0) polywater.

Transcription

1 Revision Date: January 2, 2015 Revision Number: 4, supersedes 3 SAFETY DATA SHEET 1. Identification of the substance/mixture and of the company 1.1 Product identifier Product Name: Type HP Cleaner/Degreaser Saturated Towel/Wipe Package Product ID numbers: HP-1, HP-1C, HP-1M, HP-P158ID, HP-P158IDB, HP-P158IDC, HP-P158IDM, HP-3P158IDS,HP-6P158ID, HP-P1K, HP-P63, HP-P63C HP-D72, HP-D72C, HP-D72E, HP-P31212, HP-P369, HP-T369, HP-T369/S, HP-T369/SC, HP-T369/SH, HP-T369/S-D, HP-T369/S-DC 1.2 Relevant identified uses of the mixture and uses advised against Identified uses: Electrical cleaning List of advices against: Not applicable. 1.3 Details of the supplier of the safety data sheet Supplier/Manufacturer: American Polywater Corporation th Street North Stillwater, MN USA Tel: sds@polywater.com 1.4 Emergency telephone numbers INFOTRAC (USA) Polywater Europe BV Zuidhaven 9-11 Unit B CR Zevenbergen Netherlands Tel: +31 (0) sds@ polywater.com 2. Hazards Identification 2.1 Classification of the substance or mixture Classification according to OSHA 29 CFR and Regulation (EC) No 1272/2008. Skin Sens 1 H317 Flam Liq 4 H Label elements Contains: Petroleum distallates, hydrotreated light; d-limonene Pictograms: Signal word: Warning Hazard Statements: H227 Combustible liquid H317 May cause an allergic skin reaction. Precautionary Statements: Page 1 of 7

2 P210 Keep away from flames and hot surfaces. No smoking. P280 Wear protective gloves. P302 + P352 IF ON SKIN: Wash with plenty of water. P333 + P313 If skin irritation or rash occurs: Get medical advice. P403 + P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with local and national regulations. Notes: Aspiration classification not applied due to the physical form of the product. 2.3 Other hazards: No information available. 3. Composition/Information on Ingredients Component CAS # EC # Wt. % GHS/CLP Classification Petroleum distillates, hydrotreated light < 100 Asp. Tox. 1 H304; EUH066 Skin Irrit. 3 H316; Flam Liq 4 H227 d-limonene < 10 Flam Liq 3, H226 Skin Irrit 2, H315 Skin Sens 1, H317 Aquatic Chronic 1, H410 Aquatic Acute 1, H First Aid Measures 4.1 Description of first aid measures Eye Contact: If eye irritation from exposure to vapors develops, move to fresh air. Flush eyes with clean water. If irritation persists, seek medical attention. For direct eye contact, flush with large quantity of water for 15 minutes. Seek medical attention. Skin Contact: Remove contaminated clothing; flush skin thoroughly with water. If irritation occurs, seek medical attention. Inhalation (Breathing): If irritation of nose or throat develops, move to fresh air. If irritation persists, seek medical attention. If breathing is difficult, provide oxygen. If not breathing, give artificial respiration. Seek immediate medical attention. Ingestion (Swallowing): Do not induce vomiting or give anything by mouth. If victim is drowsy or unconscious, place on the left side with head down. Do not leave victim unattended. Seek medical attention. 4.2 Most important symptoms and effects, both acute and delayed Refer to Section 11 for more information. 4.3 Indication of immediate medical attention and special treatment needed. No information available. 5. Firefighting Measures 5.1 Extinguishing media: Carbon dioxide, water fog, dry chemical or foam. 5.2 Special hazards arising from the substance or mixture Hazardous decomposition and by-products: Burning generates CO, CO 2 and smoke. Smoke may be acrid and fumes irritating. 5.3 Advice for firefighters Wear full protective clothing, including self-contained, positive pressure or pressure-demand breathing apparatus. Sealed container can build up pressure when exposed to high heat. Use water spray to cool fire exposed containers. Page 2 of 7

3 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Limited spill hazard with saturated towel package. 6.2 Environmental precautions: Avoid release to the environment. 6.3 Methods materials for containment and cleaning up: Collect towel and absorb any excess material with sand or absorbents. 6.4 Reference to other sections: Refer to Sections 4, 5, 8, and 13 for more information. 7. Handling and Storage 7.1 Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. No smoking. Avoid breathing vapors or spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Wash contaminated clothing before reuse. For industrial or professional use only. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2 Conditions for safe storage, including incompatibilities Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store away from acids and oxidizing agents. 7.3 Specific end uses See technical data sheet on this product for further information. 8. Exposure Controls / Personal Protection 8.1 Control parameters Exposure limits and recommendations: Component Name Limit Standard Source/Note Petroleum distillates, hydrotreated light 100 ppm ACGIH TWA United States Petroleum distillates, hydrotreated light 500 ppm OSHA TWA United States Petroleum distillates, hydrotreated light 1200 mg/m 3 RCP* TWA ACGIH, Manufacturer d-limonene 110 mg/m 3 DFG** OEL Germany *reciprocal calculation procedure for total hydrocarbons **deutsche forschungsgemeinschaft, German Research Foundation 8.2 Exposure controls Respiratory protection: Normal ventilation is adequate. Towelette limits solvent vapor exposure. If exposure exceeds recommended limits, respirator protection is recommended. Use a respirator or gas mask with cartridges for organic vapors (NIOSH or CE approved) with particulate pre-filter, P100 or AP2. Protective gloves: For repeated or prolonged skin contact, the use of impermeable gloves is recommended to prevent drying and possible irritation. Suggested Material: Suggested Thickness: Nitrile Rubber For short term contact (<15 minutes), splashes use 0.2 mm. For full contact use 0.4 mm Exact break-through time has not been determined. Guidance is based on similar chemistry/material. Maximum wearing time should be determined based on 50 % of the penetration time determined by EN 374 part III. Eye protection: Page 3 of 7

4 None necessary. Wipe package eliminates splash hazard. Do not allow wipe/towel to directly contact eyes. Other protective equipment: It is suggested that a source of clean water be available in work area for flushing eyes and skin. Impervious clothing should be worn as needed. 9. Physical and Chemical 9.1 Information of basic physical and chemical properties (bulk liquid) Appearance: Clear, colorless liquid with a very light citrus scent. Odor threshold: Not available ph: Does not apply Freezing point: <-58 F (<-50 C) Boiling point: 365 F (185 C) Initial Flash point: >140 F (>60.5 C), Closed Cup (PMCC) Evaporation rate: <0.1 (n-butyl acetate = 1) Flammability (solid, gas): Not applicable to liquids Upper/lower flammability or explosive limits: LEL = 0.7% UEL = 6.1%-7.0% Vapor pressure: <1 mm Hg < C Vapor density (Air = 1): > 1.0 Specific gravity (H 2 O = 1): 0.79 Solubility in water: Nil Partition coefficient: n- octanol/water: Not available Auto-ignition temperature: Not available Decomposition temperature: Not available Viscosity: Not available 9.2 Other Information Volatiles (Weight %): 100% VOC Content: 790 g/l 10. Stability and Reactivity 10.1 Reactivity: See remaining headings in Section Chemical stability: Stable 10.3 Possibility of hazardous reactions: None known Conditions to avoid: Avoid heat, flame, and sparks Incompatible materials : Strong oxidizing agents Hazardous decomposition products: Carbon dioxide, carbon monoxide. 11. Toxicological Information 11.1 Information on toxicological effects: Acute toxicity Page 4 of 7

5 Eye contact: Direct eye contact may cause eye irritation. This irritation is minimal and expected to be transient. Skin contact: Prolonged or repeated skin exposure can remove oils, causing redness, drying and cracking. Persons with pre-existing skin disorders may be more susceptible to skin irritation from this material. Irritation and Sensitization Potential: Product may be irritating to skin and eyes. It may cause an allergic skin reaction. Inhalation (Breathing): Concentrated petroleum solvent vapors may cause irritation of the nose and throat. Prolonged exposure to excessively high vapor concentrations can result in central nervous system depression (e.g., drowsiness, dizziness, loss of coordination, and fatigue). Persons with impaired lung function may experience additional breathing difficulties due to the irritant properties of this material. Ingestion: Ingestion of large quantities may cause irritation of the digestive tract, nervous system depression (e.g., drowsiness, dizziness, loss of coordination, and fatigue). Toxicity to Animals: Petroleum distillates, hydrotreated light: Aspiration hazard d-limonene: LD 50 (oral rat) >5000 mg/kg LD 50 (dermal rabbit) >2000 mg/kg LC 50 (inhl rat) >4.3mg/L, 4 hours LD 50 (oral rat) >5000 mg/kg LD 50 (dermal rabbit) 5000 mg/kg RD ppm Liquid solvent has an aspiration hazard. This route of exposure is not expected for towelette form. Chronic Exposure: Reproductive Toxicity: Not available. Mutagenicity: Not available. Teratogenicity: Not available. Specific Target Organ Toxicity (STOT) No end point data. Toxicologically Synergistic Products: Not available. Carcinogenic Status: This substance has not been identified as a carcinogen or probable carcinogen by NTP, IARC, or OSHA, nor have any of its components. 12. Ecological Information 12.1 Toxicity: Ecotoxicity: No information available. Aquatic Toxicity: No information available Persistence and degradability: Expected to be biodegradable Bioaccumulation potential: No information available 12.4 Mobility in soil: No information available Results of PBT and vpvb Assessment: 12.6 Other adverse effects: None known. 13. Disposal Considerations Dispose of product in accordance with National and Local Regulations. This product is not, nor does it contain a substance that is a PBT or vpvb. Page 5 of 7

6 14. Transport Information UN Number: UN Proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions: TDG: ICAO/IATA-DGR: IMDG: ADR/RID: Not Listed None known None known 15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture USA Federal and State All components are listed on the TSCA inventory. Hazard Categories for SARA Section 311/312 Reporting Acute Chronic Fire Pressure Reactive No No Yes No No CERCLA/SARA Sec 302 SARA Sec. 313 Components Hazardous Substance RQ EHS TPQ Toxic Release Components are not affected by these Superfund regulations. NFPA Ratings: Health: 1 Fire: 2 Reactivity: 0 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel during spill, fire or similar emergencies. Hazard ratings are based on physical and toxic properties of combustion or decomposition. European Union All components are listed on the European Inventory of Existing Chemical Substances (EINECS). Product complies with the communication requirements of REACH Regulation (EC) No. 1907/2006. It does not contain Substances of Very High Concern (SVHC). Canada All components are listed on the DSL inventory. This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS Classification: B3 Australia All components are listed on the AICS. Hazardous according to criteria of NOHSC Australia. Product classified as harmful (Xn) Chemical Safety Assessment No chemical safety assessment has been carried out for the mixture by the supplier. 16. Other Information Page 6 of 7

7 Abbreviations and acronyms: OSHA = Occupational Safety and Health Administration CLP = Classification, Labeling and Packaging Regulation STOT = Specific Target Organ Toxicity LD 50 = Median Lethal Dose DNEL = Derived No Effect Level ACGIH = American Conference of Governmental Industrial Hygienists TSCA = Toxic Substances Control Act (USA) DSL = Domestic Substances List (Canada) AICS = Australian Inventory of Chemical Substances Hazard Statements: H227 H317 Combustible liquid May cause an allergic skin reaction. Revision Date: January 2, 2015 Revision Number: 5 Supersedes: September 23, 2014 Other: Indication of Changes: Section 1, 2, 3, 8, 15, 16 updated. Hazard and precautionary codes adjusted, additional information on exposure limits. Addition of acronyms and other formatting changes. Updated in accordance with the provisions of OSHA App D and REACH Annex II (EU No 453/2010). (GHS format) The information and recommendations contained herein are believed to be reliable. However, the supplier makes no warranties, express or implied, concerning the use of this product. The buyer must determine conditions of safe usage and assumes all risk and liability in handling this product. Page 7 of 7