SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830. Oxidase-Streifen Material number
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1 Page: 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: This safety data sheet pertains to the following products: Relevant identified uses of the substance or mixture and uses advised against General use: Use as laboratory reagent. Only for industrial users. 1.3 Details of the supplier of the safety data sheet Company name: Bio-Rad Medical Diagnostics GmbH Street/POB-No.: Industriestr. 1 Postal Code, city: Dreieich Germany WWW: contact.bmd@bio-rad.com Telephone: +49 (0) Telefax: +49 (0) Dept. responsible for information: Produktmanagement Infektion Telephone: Telefax: Emergency telephone number GIZ-Nord, Göttingen, Germany, Telephone: SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to EC regulation 1272/2008 (CLP) Skin Irrit. 2; H315 Causes skin irritation. Eye Irrit. 2; H319 Causes serious eye irritation. STOT SE 3; H335 May cause respiratory irritation. 2.2 Label elements Labelling (CLP) Signal word: Warning Hazard statements: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Bio-Rad V2, 14/3/2017
2 Page: 2 of 7 Precautionary statements: 2.3 Other hazards No risks worthy of mention. Results of PBT and vpvb assessment: 3.1 Substances: 3.2 Mixtures Hazardous ingredients: SECTION 3: Composition / information on ingredients Ingredient Designation Content Classification EC No CAS N,N,N',N'-Tetramethyl-pphenylenediamine dihydrochloride Full text of H- and EUH-statements: see section 16. Additional information: 100 % Skin Irrit. 2; H315. Eye Irrit. 2; H319. STOT SE 3; H335. paper strips Coating agent: N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride 4.1 Description of first aid measures In case of inhalation: Following skin contact: After eye contact: After swallowing: SECTION 4: First aid measures Provide fresh air. Seek medical treatment in case of troubles. Remove residues with water. Change contaminated clothing. In case of skin reactions, consult a physician. Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. In case of eye irritation consult an ophthalmologist. Rinse mouth and drink large quantities of water. Seek medical attention. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. When seeking medical attention bring along safety data sheet. 5.1 Extinguishing media SECTION 5: Firefighting measures Suitable extinguishing media: extinguishing powder, carbon dioxide. Co-ordinate fire-fighting measures to the fire surroundings. Extinguishing media which must not be used for safety reasons: Full water jet Bio-Rad V2, 14/3/2017
3 Page: 3 of Special hazards arising from the substance or mixture 5.3 Advice for firefighters Fires in the immediate vicinity may cause the development of dangerous vapours. In case of fire may be liberated: Hydrogen chloride, Nitrogen oxides (NOx), Carbon monoxide and carbon dioxide. Special protective equipment for firefighters: Wear self-contained breathing apparatus. Wear appropriate protective equipment. Additional information: Hazchem-Code: - Do not allow fire water to penetrate into surface or ground water. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions Avoid contact with skin and eyes. Provide adequate ventilation. Wear personal protection equipment. Do not allow to penetrate into soil, waterbodies or drains. 6.3 Methods and material for containment and cleaning up 6.4 Reference to other sections Take up mechanically and send to waste disposal. Final cleaning. Refer additionally to section 8 and Precautions for safe handling SECTION 7: Handling and storage Advices on safe handling: Avoid contact with skin and eyes. Wear appropriate protective equipment. Keep all containers, equipment and working place clean. Provide adequate ventilation, and local exhaust as needed. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storerooms and containers: Keep containers tightly closed and at a temperature between 2 C and 8 C. Keep only in the original container. Protect against heat /sun rays. Protect from moisture contamination. Hints on joint storage: 7.3 Specific end use(s) Do not store together with acids/alkalies and oxidation agents. No information available. 8.1 Control parameters Additional information: SECTION 8: Exposure controls/personal protection Contains no substances with occupational exposure limit values. Bio-Rad V2, 14/3/2017
4 Page: 4 of Exposure controls Personal protection equipment Occupational exposure controls Provide good ventilation and/or an exhaust system in the work area. Respiratory protection: With the formation of dust, use a dust mask. Particulates filter P2 according to EN 143. The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. Hand protection: Protective gloves according to EN 374. Glove material: Nitrile rubber - Layer thickness: 0.11 mm Breakthrough time: > 480 min Observe glove manufacturer's instructions concerning penetrability and breakthrough time. Eye protection: Tightly sealed goggles according to EN 166. Body protection: Wear suitable protective clothing. General protection and hygiene measures: Avoid contact with skin and eyes. Provide adequate ventilation. Change contaminated clothing. After work, wash hands and face. When using do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Odour: Odour threshold: ph value: Physical state at 20 C and kpa: solid Form: solid Colour: beige Melting point/freezing point: Initial boiling point and boiling range: (N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride) approx. 223 C Flash point/flash point range: Not applicable Evaporation rate: Flammability: Explosion limits: Vapour pressure: Vapour density: Density: Solubility: Partition coefficient: n-octanol/water: Auto-ignition temperature: Decomposition temperature: Viscosity, kinematic: Explosive properties: Oxidizing characteristics: 9.2 Other information Additional information: Bio-Rad V2, 14/3/2017
5 Page: 5 of Reactivity refer to 10.3 SECTION 10: Stability and reactivity 10.2 Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions None known Conditions to avoid Protect against heat /sun rays. Protect from moisture contamination Incompatible materials Strong oxidizing agents, strong acids and alkalis Hazardous decomposition products Thermal decomposition: In case of fire may be liberated: Hydrogen chloride, Nitrogen oxides (NOx), Carbon monoxide and carbon dioxide. SECTION 11: Toxicological information 11.1 Information on toxicological effects Toxicological effects: Acute toxicity (oral): Lack of data. Acute toxicity (dermal): Lack of data. Acute toxicity (inhalative): Lack of data. Skin corrosion/irritation: Skin Irrit. 2; H315 = Causes skin irritation. Serious eye damage/irritation: Eye Irrit. 2; H319 = Causes serious eye irritation. Sensitisation to the respiratory tract: Lack of data. Skin sensitisation: Lack of data. Germ cell mutagenicity/genotoxicity: Lack of data. Carcinogenicity: Lack of data. Reproductive toxicity: Lack of data. Effects on or via lactation: Lack of data. Specific target organ toxicity (single exposure): STOT SE 3; H335 = May cause respiratory irritation. Specific target organ toxicity (repeated exposure): Lack of data. Aspiration hazard: Lack of data Toxicity Further details: SECTION 12: Ecological information Bio-Rad V2, 14/3/2017
6 Page: 6 of Persistence and degradability Further details: 12.3 Bioaccumulative potential Partition coefficient: n-octanol/water: 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects General information: Do not allow to penetrate into soil, waterbodies or drains Waste treatment methods Product Waste key number: Recommendation: Contaminated packaging Recommendation: SECTION 13: Disposal considerations * = discarded organic chemicals consisting of or containing hazardous substances * = Evidence for disposal must be provided. Special waste. Dispose of waste according to applicable legislation. Dispose of waste according to applicable legislation. Handle contaminated packages in the same way as the substance itself. Non-contaminated packages may be recycled UN number 14.2 UN proper shipping name Not restricted 14.3 Transport hazard class(es) 14.4 Packing group SECTION 14: Transport information Bio-Rad V2, 14/3/2017
7 Page: 7 of Environmental hazards Marine pollutant: no 14.6 Special precautions for user No dangerous good in sense of these transport regulations Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations - Great Britain Hazchem-Code: - National regulations - EC member states Labelling of packaging with <= 125mL content Signal word: Hazard statements: Warning Precautionary statements: 15.2 Chemical Safety Assessment For this mixture a chemical safety assessment is not required. Further information SECTION 16: Other information Wording of the H-phrases under paragraph 2 and 3: H315 = Causes skin irritation. H319 = Causes serious eye irritation. H335 = May cause respiratory irritation. Reason of change: Date of first version: 8/6/2015 Department issuing data sheet Contact person: Changes in section 1: Identification of the substance or preparation see section 1: Dept. responsible for information For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety assessment, chapter R.20 (Table of terms and abbreviations). The information in this data sheet has been established to our best knowledge and was up-to-date at time of revision. It does not represent a guarantee for the properties of the product described in terms of the legal warranty regulations. Bio-Rad V2, 14/3/2017
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