SAFETY DATA SHEET ZIP GRIP 4404

Transcription

1 Revision Date 13/11/2012 Revision 2 Supersedes date 07/06/2005 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Adhesive Details of the supplier of the safety data sheet Supplier ITW DEVCON Unit 3 Shipton Way Express Business Park Northampton NORTHANTS NN10 6GL T: 0044(0) F: 0044(0) info@itwppe.eu 1.4. Emergency telephone number +44(0) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Xi;R36/37/38. Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of reach of children Label elements Contains Labelling ETHYL 2-CYANOACRYLATE Irritant Risk Phrases Safety Phrases 2.3. Other hazards R36/37/38 Irritating to eyes, respiratory system and skin. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S51 Use only in well-ventilated areas. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 6

2 ETHYL 2-CYANOACRYLATE % CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT SE 3 - H335 Classification (67/548/EEC) Xi;R36/37/38 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Avoid inhalation of vapours and contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Do not induce vomiting. Rinse mouth thoroughly. Get medical attention immediately! Skin contact Wash the skin immediately with soap and water. If adhesive bonds skin, flush with water and seek medical assistance. Do not attempt to force skin apart if bonded. Eye contact If adhesive bonds eyelids, flush with water and seek medical assistance. Do not attempt to force bonded skin apart Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Fire can be extinguished using: Water. Carbon dioxide (CO2). Dry chemicals. Foam Special hazards arising from the substance or mixture Specific hazards When heated and in case of fire, irritating vapours/gases may be formed Advice for firefighters Special Fire Fighting Procedures Avoid breathing fire vapours. Keep up-wind to avoid fumes. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Avoid inhalation of vapours and contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. In case of inadequate ventilation, use respiratory protection. Do not smoke, use open fire or other sources of ignition Environmental precautions Do not discharge into drains, water courses or onto the ground. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. 2 / 6

3 6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Liquid adhesive; bonds skin and eyes in seconds. Avoid contact with skin and eyes. Keep away from heat, sparks and open flame. Do not use in confined spaces without adequate ventilation and/or respirator. Do not eat, drink or smoke when using the product. Observe good chemical hygiene practices Conditions for safe storage, including any incompatibilities Keep out of the reach of children. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight Specific end use(s) Not noted. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes ETHYL 2-CYANOACRYLATE WEL 0.3 ppm 1.5 mg/m3 WEL = Workplace Exposure Limit Exposure controls Protective equipment Process conditions Provide eyewash, quick drench. Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment If ventilation is insufficient, suitable respiratory protection must be provided. Hand protection Polyethylene gloves are recommended. Eye protection Wear approved safety goggles. Hygiene measures Keep away from food, drink and animal feeding stuffs. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes wet or contaminated. When using do not eat, drink or smoke. Skin protection Protection suit must be worn. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Viscous liquid. Colour Colourless. Odour Slightly pungent odour. Solubility Slightly soluble in water. Initial boiling point and boiling range > Melting point ( C) N/D Relative density 1.05 Vapour density (air=1) >1 Vapour pressure 0.17mmHg 20 3 / 6

4 Evaporation rate N/D Flash point >76.66 Flammability Limit - Lower(%) N/D Flammability Limit - Upper(%) N/D 9.2. Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Hazardous Polymerisation May polymerise. Polymerisation Description Avoid alkalis and/or heat Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight Incompatible materials Materials To Avoid Avoid contact with water. Bases, alkalis (inorganic). Bases, alkalis (organic). Organic peroxides/hydroperoxides. Inorganic peroxides Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Hydrogen cyanide (HCN). SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation May cause irritation to the respiratory system. Vapour may irritate respiratory system or lungs. Ingestion May cause severe internal injury. Skin contact Liquid adhesive; bonds skin and eyes in seconds. Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Eye contact Liquid adhesive; bonds eyes in seconds. Irritating to eyes. Risk of serious damage to eyes. Health Warnings Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of reach of children. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Avoid release to the environment Toxicity No data available Persistence and degradability Degradability The degradability of the product has not been stated Bioaccumulative potential 4 / 6

5 Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: Do not discharge into drains, water courses or onto the ground Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS General information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Waste Class SECTION 14: TRANSPORT INFORMATION General UN number The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN proper shipping name Transport hazard class(es) ADR Label No. 0 Transport Labels No transport warning sign required Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date 13/11/2012 Revision 2 5 / 6

6 Supersedes date 07/06/2005 Date Risk Phrases In Full R36/37/38 Irritating to eyes, respiratory system and skin. Hazard Statements In Full H319 Causes serious eye irritation. H315 Causes skin irritation. H335 May cause respiratory irritation. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6