4-NITROBENZOIC ACID FOR SYNTHESIS MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)
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1 4-NITROBENZOIC ACID FOR SYNTHESIS MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance : CAS No : Product code : Chemical structure : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (oral), Category 4 Serious eye damage/eye irritation, Category 1 H302 H318 Full text of classification categories and H statements : see section /04/2015 1/8
2 Classification according to Directive 67/548/EEC or 1999/45/EC Xn; R22 C; R34 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS05 : Danger GHS07 : H302 - Harmful if swallowed H318 - Causes serious eye damage : P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Name : 4-NITROBENZOIC ACID For Synthesis CAS No : Full text of R- and H-phrases: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. 09/04/2015 2/8
3 First-aid measures after eye contact First-aid measures after ingestion : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after ingestion : Harmful if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Use personal protective equipment as required. : Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Clean up immediately by sweeping or vacuum Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not breathe dust/fume/gas/mist/vapours/spray. : Do not eat, drink or smoke when using this product. Wash... thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Store in original container. Keep container tightly closed. Store in a dry place Specific end use(s) 09/04/2015 3/8
4 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : protective gloves : Chemical goggles or face shield : Wear suitable protective clothing : Wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) : Yellow crystalline. Melting point : Freezing point Boiling point Flash point : 237 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties : g/cm³ : Water: Soluble in water 09/04/2015 4/8
5 Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Air contact. Moisture Incompatible materials Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes serious eye damage. Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Harmful if swallowed. 09/04/2015 5/8
6 SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose of contents/container to... SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No.(IATA) UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) 09/04/2015 6/8
7 IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions 4-NITROBENZOIC ACID For Synthesis is not on the REACH Candidate List 4-NITROBENZOIC ACID For Synthesis is not on the REACH Annex XIV List 09/04/2015 7/8
8 National regulations Germany AwSV/VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 1505) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 H302 Harmful if swallowed H318 Causes serious eye damage R22 Harmful if swallowed R34 Causes burns C Corrosive Xn Harmful This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/04/2015 8/8
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