Version 1.0 Revision Date 10/08/2016 Print Date 12/20/2016. : Honeywell International Inc. 115 Tabor Road Morris Plains, NJ

Size: px

Start display at page:

Download "Version 1.0 Revision Date 10/08/2016 Print Date 12/20/2016. : Honeywell International Inc. 115 Tabor Road Morris Plains, NJ"

Camilla McKenzie
5 years ago
Views:

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Cobalt(II) chloride hexahydrate Number : Product Use Description : Laboratory chemicals Manufacturer or supplier's details : Honeywell International Inc. 115 Tabor Road Morris Plains, NJ For more information call : (Monday-Friday, 9:00am-5:00pm) In case of emergency call : Medical: or : Transportation (CHEMTREC): or : : (24 hours/day, 7 days/week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form Color Odor : crystalline : light red : odourless Classification of the substance or mixture Classification of the substance or mixture : Acute toxicity, Category 4, Oral Respiratory sensitisation, Category 1 Skin sensitisation, Category 1 Germ cell mutagenicity, Category 2 Carcinogenicity, Category 1B Reproductive toxicity, Category 1B GHS Label elements, including precautionary statements Page 1 / 11

: Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

2 Symbol(s) : Signal word Hazard statements Precautionary statements : Danger : Harmful if swallowed. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child. : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Response: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/ attention. Rinse mouth. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Carcinogenicity Page 2 / 11

3 IARC: Cobalt chloride hexahydrate Group 2B: Possibly carcinogenic to humans Group 2B: Possibly carcinogenic to humans ACGIH: Cobalt chloride hexahydrate A3: Confirmed animal carcinogen SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Chemical nature : Cl2Co 6H2O : Substance Chemical name CAS-No. Concentration Cobalt chloride hexahydrate % SECTION 4. FIRST AID MEASURES General advice : First aider needs to protect himself. Move out of dangerous area. Immediately take off contaminated clothing and rinse body with plenty of water. Inhalation : If inhaled, remove to fresh air. Call a physician immediately. Skin contact : After contact with skin, wash immediately with plenty of water. Eye contact : Protect unharmed eye. Rinse thoroughly with plenty of water, also under the eyelids. Call a physician immediately. Ingestion : A person suspected to have swallowed the substance who is conscious should be given water to drink. Take to a doctor immediately together with this card SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Foam Carbon dioxide (CO2) Page 3 / 11

4 Dry powder Specific hazards during firefighting Special protective equipment for firefighters Further information : Hazardous decomposition products formed under fire conditions. Exposure to decomposition products may be a hazard to health. Fire or intense heat may cause violent rupture of packages. Do not allow run-off from fire fighting to enter drains or water courses. : Wear self-contained breathing apparatus and protective suit. : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not burn. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Evacuate personnel to safe areas. Wear personal protective equipment. Unprotected persons must be kept away. Avoid dust formation. Do not breathe dust. Do not get in eyes, on skin, or on clothing. Environmental precautions : Do not flush into surface water or sanitary sewer system. Clean contaminated floors and objects thoroughly while observing environmental regulations. Prevent further leakage or spillage if safe to do so. Methods for cleaning up : Use mechanical handling equipment. Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with local regulations. Personal protection through wearing a tightly closed chemical protection suit and a self-contained breathing apparatus. SECTION 7. HANDLING AND STORAGE Handling Handling : Wear personal protective equipment. Refill and handle product only in closed system. Use only in well-ventilated areas. Never return unused material to storage receptacle. Page 4 / 11

5 Do not breathe dust. Do not get in eyes, on skin, or on clothing. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage areas and containers : Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. Legal requirements are to be considered in regard of the selection, use and care of personal protective equipment. Avoid exposure - obtain special instructions before use. Do not breathe dust. Do not get in eyes, on skin, or on clothing. Engineering measures : Use with local exhaust ventilation. Eye protection : Safety glasses with side-shields Hand protection : Latex gloves Gloves must be inspected prior to use. Replace when worn. Skin and body protection : Wear suitable protective equipment. Protective suit Lab coat Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Hygiene measures : Separate rooms are required for washing, showering and changing clothes. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing. Exposure Guidelines Components CAS-No. Value Control Upda Basis Page 5 / 11

6 Cobalt chloride hexahydrate Further information TWA : Time weighted average : Expressed as : as Co parameters te 0.02 mg/m ACGIH:US. ACGIH Threshold Limit Values SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : crystalline Color Odor ph : light red : odourless : Note: no data available Melting point/range : 86 C Boiling point/boiling range : Note: Decomposes on heating. Flash point Flammability : The product is not flammable. Lower explosion limit Upper explosion limit Vapor pressure : Note: no data available Density : ca. 1.9 g/cm3 at 20 C Water solubility : g/l at 20 C at 7 ph Page 6 / 11

7 Method: OECD Test Guideline 105 Partition coefficient: n- octanol/water Ignition temperature Auto-ignition temperature : Note: no data available : Note: not auto-flammable Decomposition temperature : 318 C Note: Decomposition temperature Viscosity, dynamic Viscosity, kinematic Oxidizing properties Molecular weight : The substance or mixture is not classified as oxidizing. : g/mol Bulk density : ca. 900 kg/m3 SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials to avoid Hazardous decomposition products : Stable under recommended storage conditions. : Decomposes on heating. : Protect against water. To avoid thermal decomposition, do not overheat. : Incompatible with bases. : Elimination of water of crystallisation Toxic metal oxide fumes Hydrogen chloride gas SECTION 11. TOXICOLOGICAL INFORMATION Page 7 / 11

8 Acute oral toxicity : LD50: 537 mg/kg Species: Rat, male and female Method: OECD Test Guideline 401 : LD50: 766 mg/kg Species: Rat, male and female Acute inhalation toxicity : Note: Not classified due to data which are conclusive although insufficient for classification. Acute dermal toxicity : Note: Not classified due to data which are conclusive although insufficient for classification. Skin irritation : Species: Rabbit Result: slight irritation Method: OECD Test Guideline 404 Eye irritation : Species: Bovine eye Result: slight irritation Method: OECD Test Guideline 437 Sensitisation : Note: Classification based on Annex VI of regulation 1272/2008/EC. Further information : Note: May cause sensitisation by inhalation and skin contact. May cause cancer. May damage fertility or the unborn child. Suspected of causing genetic defects. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish : Note: Classification based on Annex VI of regulation 1272/2008/EC. Toxicity to daphnia and other aquatic invertebrates : Note: Classification based on Annex VI of regulation 1272/2008/EC. Page 8 / 11

9 Toxicity to algae : Note: Classification based on Annex VI of regulation 1272/2008/EC. Further information on ecology SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : Observe all Federal, State, and Local Environmental regulations. SECTION 14. TRANSPORT INFORMATION DOT UN/ID No. : UN 3077 Proper shipping name : Environmentally hazardous substances, solid, n.o.s. (Cobalt dichloride) Class 9 Packing group III Hazard Labels 9 IATA UN/ID No. : UN 3077 Description of the goods : Environmentally hazardous substances, solid, n.o.s. (Cobalt dichloride) Class : 9 Packaging group : III Hazard Labels : 9 Packing instruction (cargo : 956 aircraft) Packing instruction : 956 (passenger aircraft) Packing instruction (passenger aircraft) : Y956 IMDG UN/ID No. : UN 3077 Description of the goods : Environmentally hazardous substances, solid, n.o.s. (COBALT(II) CHLORIDE) Class : 9 Packaging group : III Hazard Labels : 9 EmS Number : F-A, S-F Page 9 / 11

10 Marine pollutant : yes IMDG Code segregation group 7 Heavy metals and their salts, SECTION 15. REGULATORY INFORMATION Inventories US. Toxic Substances Control Act Australia. Industrial Chemical (Notification and Assessment) Act Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL) Japan. Kashin-Hou Law List Korea. Toxic Chemical Control Law (TCCL) List Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On TSCA Inventory : All components of this product are on the Canadian DSL National regulatory information SARA 302 Components SARA 313 Components : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : The following components are subject to reporting levels established by SARA Title III, Section 313: : Cobalt chloride hexahydrate Page 10 / 11

11 SARA 311/312 Hazards California Prop. 65 : Acute Health Hazard Chronic Health Hazard : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. New Jersey RTK : Cobalt chloride hexahydrate Pennsylvania RTK : Cobalt chloride hexahydrate SECTION 16. OTHER INFORMATION HMIS III NFPA Health hazard : 2* 2 Flammability : 0 0 Physical Hazard : 0 Instability : 0 * - Chronic health hazard Hazard rating and rating systems (e.g. HMIS III, NFPA): This information is intended solely for the use of individuals trained in the particular system. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties. Changes since the last version are highlighted in the margin. This version replaces all previous versions. Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group Page 11 / 11

Sodium thiosulfate concentrate X1EA Version 1.1 Revision Date 10/08/2018 Print Date 10/19/2018

Sodium thiosulfate concentrate X1EA Version 1.1 Revision Date 10/08/2018 Print Date 10/19/2018 SECTION 1. IDENTIFICATION Product name : Number : 000000021836 Product Use Description : Laboratory chemicals Manufacturer or supplier's details : Honeywell International Inc. 1953 South Harvey Street