Safety Data Sheet. SDS n : Version :3.01 Version of : This sheet supersedes the one dated :

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1 Page : 1/6 PRODUCT LABELS LABELLING (standard or EU): R-phrases : S-phrases : TRANSPORT LABELLING: Concerned R-52 Harmful to aquatic organisms. S-61 Avoid release to the environment. Refer to special instructions/safety Data Sheets. Not applicable. 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY UNDERTAKING Name of the product : Product application : Supplier : ARBOFINE Insecticide-acaricide paraffinic oil. TOTAL FLUIDES 51, Esplanade du Général de Gaulle Paris La Défense Cédex Contact : Service QSE : Tel : / Fax : rmfs.fds@total.com - Emergency number 24h/24h : Emergency telephones : ORFILA / Tel : See local details at end of sheet : 2. HAZARDS IDENTIFICATION Health effects : Environmental impact : Physico-chemical hazards : Product classification : This product does not present a danger of acute intoxication. Extended and repeated contacts with the skin can cause skin ailments which may be aggravated by minor injuries or contact with soiled clothing. Heavy concentrations of vapor are irritating to respiratory system Some components may have a harmful effect on the aquatic environment. No specific risk of fire or explosion. Harmful to aquatic organisms. 3. COMPOSITION/INFORMATION ON INGREDIENTS PREPARATION Chemical nature : Mixture of petroleum distillates and surfactants. Substances presenting a health hazard EC No. CAS No. Content Symbol(s) R-phrases Distillates (petroleum) hydrotreated middle >50 % Xn R-65 Fatty alcohol ethoxylate <5 % Xi,N R-41, 50 See section 16 for explanations of R-phrases : 4. FIRST AID MEASURES IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR EMERGENCY MEDICAL CARE.

2 Page : 2/6 Inhalation : Ingestion : Skin contact : Transport the person into fresh air, keep warm and allow to rest. An irritation of mouth and bronchial tubes can occur. - Symptoms : Irritation of the respiratory system. At high concentrations: Narcosis. Do not induce vomiting to avoid the risk of aspiration into the respiratory tract. Get medical attention immediately! - Symptoms : Nausea, vomiting, abdominal pains. Wash thoroughly with hot soapy water. If the skin is exposed to high-pressure spray, the product may enter the human body. In all such cases the affected person must be taken to hospital, even if no sign of injury can be detected. In case of repeated or prolonged contact with the skin: Skin irritation. Dryness. Chapping. Eye contact : Keep eyes open and rinse immediately and repeatedly with water for at least 15 minutes. If irritation persists, call an ophthamologist. - Symptoms : Burning feeling and temporary redness. Aspiration : If the product is believed to have entered the lungs (in case of vomiting, for example), take the person to hospital for immediate care. 5. FIRE FIGHTING MEASURES Flash point: see heading 9 - "Physical and chemical properties" Extinguishing media : Specific fire-fighting methods : Specific hazards : Protective measures for firefighters : - suitable: Foam, CO2, powder - not recommended: Water jet. Cool any containers exposed to fire, with water spray. Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled. Insulated breathing apparatus must be worn in confined premises with heavy concentrations of fumes and gases. 6. ACCIDENTAL RELEASE MEASURES Personal protection : After spillage / leakage : Spill cleanup methods : Prevention of secondary risks : Hydrocarbon-proof gloves, goggles, boots, and clothing should be worn, as applicable to risks of exposure. Spills of this product can make surfaces slippery. Design installations so as to prevent water and ground pollution. Protect environmentally sensitive areas and water resources. Set up sewer protection to reduce the risk of pollution through accidental release. - Recovery: Contain and recover by physical means. Smaller quantities of residue must be collected by an absorbent. - Elimination: Hand over contaminated materials to an approved collector - see also section 13. Remove all sources of ignition.

3 Page : 3/6 7. HANDLING AND STORAGE HANDLING : Prevention of user exposure : Prevention of fire and explosion : Precautions : Ventilate extensively if the formation of vapours, fumes, mists or aerosol is a risk. Empty containers may contain flammable or explosive vapours. Make provision for water network to avoid any spread of fire. Avoid extended and repeated contact with the skin as this may cause skin conditions. Avoid breathing in vapours, fumes or mists. Do not spray at high pressure (> 3 bar). Do not eat or drink or smoke during use. STORAGE : Technical measures : Storage precautions : Packaging materials : Prevent any build-up of static electricity. - Suitable: Containers and equipments must be earthed in order to prevent sparks due to static electricity. Use only hydrocarbon resistant containers, joints, pipe-lines... Keep containers closed when not in use Keep away from heat. Recommended storage temperature: 5 to 35 C. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. - Recommended: Steel 8. EXPOSURE CONTROLS/PERSONAL PROTECTION The personal protective equipment (PPE) recommendations apply to the product ITSELF. In case of mixtures or formulations, it is suggested that you contact the relevant PPE suppliers. Technical measures : Occupational exposure limit : Respiratory protection : Use this product in a well-ventilated atmosphere with explosion-proof equipment. For exposure to oil mist, a mean exposure value of 5 mg/m3 is recommended (TLV-TWA). In case of risk of exposure exceeding the mean exposure value, an appropriate breathing apparatus must be worn by each individual. When using a mask or half-mask : Recommendation for filters : Combined gas cartridge (organic gases and dust, filter A/P2). Hand protection : Liquid proof aliphatic solvent resisting gloves : - In case of prolonged or repeated contact : Nitrile. Thickness > 0.45 mm - Permeation time according to EN : > 480 minutes Fluoro polymer and PVA - any thickness. Permeation time according to EN : > 480 minutes - In case of splashes or limited contact : Nitrile. Thickness > 0.3 mm Permeation time according to EN : > 60 minutes The materials listed here are a recommendation. Other materials may also be suitable. The demands on the gloves are determined by the conditions in practice (e.g. multiple use, mechanical load, temperature, strength and duration of exposition). Before choosing suitable gloves, it is recommended that the user tests the gloves. For more precise details about the choice of appropriate protective glove, please contact the manufacturer. Eye protection : Goggles, in case of risk of splashing.

4 Page : 4/6 Skin and body (other than the hands) protection : Hygienic work practices : Appropriate protective clothing. Avoid prolonged and repeated contact with the skin. Do not eat, drink or smoke whilst handling the product. Do not dry hands with rags that have been contaminated with product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Liquid at 20 C Colour : Density/specific gravity : Colourless kg/m3 Temperature ( C) 15 Flash point : >= 150 C (ISO 2719) Comments on flash points : (Pensky/Martens Closed cup) Température d'auto-inflammation : > 250 ºC (ASTM E 659) Flammability limit - lower(%) : 1 Flammability limit - upper(%) : 6 Comments on explosivity : The lower flammable limit of oil mist is reached at concentrations in the range of 45 g/m³. Temperatures at phase change : Solubility : Flowing point: 0 C (ISO 3016) Emulsifiable in water. Viscosity : > mm2/s (ISO 3104) Temperature ( C) STABILITY AND REACTIVITY Stability : Materials to avoid : Hazardous decomp. products : The product is stable at normal storage, handling and use temperatures. Strong acids and oxidising agents Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. 11. TOXICOLOGICAL INFORMATION Acute toxicity / Local effect : Inhalation, comments: Skin contact, comments: Eye contact, comments: Ingestion : Ingestion, comments: Not classified Strong concentrations of vapour and spray may be irritating for the respiratory tract and mucous membranes. Frequent and prolonged contact may cause skin irritation Not classified as irritating, but may cause a burning feeling and temporary reddening. Acute toxicity LD50(Rat) > 5000 mg/kg Not classified. CHRONIC TOXICITY OR LONG-TERM TOXICITY :

5 Page : 5/6 Skin contact : Frequent or prolonged skin contact destroys the lipoacid cutaneous layer and may cause dermatosis. Characteristic skin affections (oil blisters) may develop following prolonged and repeated exposure through contact with stained clothing 12. ECOLOGICAL INFORMATION Ecotoxicity : Acute toxicity. IC50 72 hours algae 89.9 mg/l OECD 201 Acute toxicity. EC50 48 hours Daphnia magna 31.8 mg/l OECD 202 Acute toxicity. LC50 96 hours fish > 100 mg/l OECD 203 Comments about ecotoxicity : Mobility : Persistence and degradability : Harmful to aquatic organisms. (Results obtained on a similar product) - Water: Forms an emulsion - Soil: Given its physical and chemical characteristics, the product generally shows little mobility in the ground. The "mineral oil" fraction of the new product is intrinsically biodegradable. 13. DISPOSAL CONSIDERATIONS Waste disposal : Disposal of contaminated packaging : National regulations : Prevent from entering sewers or the immediate environment. - Relevant disposal method: The only method authorized is collection by an authorized waste contractor and regeneration or incineration in an approved installation. - Relevant disposal method: Disposal via an authorised waste contractor. Storage of liquid hydrocarbons : decree of (Journal Officiel of ); decree of (JO of ); circular of (JO of ). When cleaning tanks, the disposal of sludge is to be carried out in compliance with regulations concerning waste : Decree n of (book V "code del'environnement"). Decree N of (JO of ) Decree of concerning waste (JO of ) Waste classification: Decree of April 18, TRANSPORT INFORMATION Not concerned by the transport regulations below. Road (ADR) / Rail (RID) : Transport by barge (ADNR) : Marine (IMO-IMDG) : Air (ICAO/IATA) : 15. REGULATORY INFORMATION Symbol : none Risk phrases : Safety phrases : R-52 Harmful to aquatic organisms. S-61 Avoid release to the environment. Refer to special instructions/safety Data Sheets. Social Security code : - Art. L 461-6, Art. D.461-1, annexe A, n 601

6 Page : 6/6 Labor code : Listed installations : - Art. R , decree of (special medical surveillance). Follow the regulations applicable for hazard-rated facilities. INVENTORIES: EUROPE (EINECS) : All components on EINECS inventory 16. OTHER INFORMATION Explanations of R-phrases in section 2 : R-65 Harmful: may cause lung damage if swallowed. R-41 Risk of serious damage to eye. R-50 Very toxic to aquatic organisms. RECOMMENDED USES AND RESTRICTIONS ON USE : Recommended uses and restrictions : see section 1 Revision date: Supersedes the data sheet of: * Information revised since the previous version of the SDS : Emergency number : For France, in case of poisoning call the Antipoison Centre (if possible in your area) and/or the SAMU (15), see ORFILA in heading 1 - Tel : Angers Bordeaux Lille Lyon Marseille Nancy Paris Rennes Strasbourg Toulouse This safety data sheet serves to complete but not to replace the technical product sheets. The information contained herein is given in good faith and is accurate to the best of knowledge at the date indicated above.it is understood by the user that any use of the product for purposes other than those for which it was designed entails potential risk.the information given herein in no way dispenses the user from knowing and applying all provisions regulating his activity.the user bears sole liability for the precautions required when using the product.the regulatory texts indicated herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.it is the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

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