SAFETY DATA SHEET. Emergency Telephone: (National Poison Centre)

Transcription

1 ISOPON SCRATCH & STONE CHIP FILLER (SSCF-R- NZ) Safety Data Sheet Date of issue:17/7/17 Revision date: : Version: 1.0 SAFETY DATA SHEET Section 1. Identification of the material and the supplier Product: ISOPON SCRATCH & STONE CHIP FILLER Item Code: SSCF/PBX Product Use: Bodyfiller Restriction of Use: Refer to Section 15 New Zealand Supplier: Address: U-POL NZ Ltd c/o Lindsay & Associates Unit H, 12 Amera Place East Tamaki, Auckland Telephone: technical.department@u-pol.com Emergency Telephone: (National Poison Centre) Section 2. Hazards Identification This substance is hazardous according to the HSNO (Minimum Degrees of Hazard) Regulations 2001 EPA Approval No: Surface Coatings and Colourants (Flammable, Toxic[6.7]) HSR Pictograms Flammable Irritant Chronic Signal Word: Danger HSNO Class. Hazard Hazard Statement GHS Category Code 3.1C H226 Flammable liquid and vapour. Category 3 6.3B H316 Causes mild skin irritation. Category 3 6.4A H319 Causes serious eye irritation. Category 2A 6.7B H351 Suspected of causing cancer. Category 2 6.8B H361 Suspected of damaging fertility or the unborn child. Category 2 May cause damage to organs through prolonged or 6.9B H373 Category 2 repeated exposure. Prevention Code Prevention Statement Page 1

2 P103 P202 P210 P233 P240 P241 P242 P243 P260 P264 P280 P281 Response Code P314 P303 + P361+P353 P305 + P351+P338 P308 + P313 P332 + P313 P337 + P313 P370 + P378 Storage Code P405 P403 + P235 Disposal Code P501 Section 3. Read label before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames or hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe fumes, mist, vapours or spray. Wash hands thoroughly after handling. Wear protective clothing. Use personal protective equipment as required. Response Statement Get medical advice/attention if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/attention. In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. Storage Statement Store locked up. Store in a well-ventilated place. Keep cool. Disposal Statement Dispose of according to Local Regulations or Authorities Composition / Information on Hazardous Ingredients Ingredients Wt% CAS NUMBER. Xylene n-butyl acetate Ethylbenzene Non-hazardous ingredients To Bal Section 4. First Aid Measures Routes of Exposure: If in Eyes If on Skin If Swallowed If Inhaled Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. Wash with plenty of soap and water. Take off contaminated clothing and wash before re-use. If skin irritation occurs: get medical advice/attention. Rinse mouth. Never give anything to the mouth of an unconscious person. If vomiting occurs, place victim face downwards, with the head turned to the side and lower than the hips to prevent vomit entering the lungs. Seek medical attention if needed. Remove person to fresh air. Remove contaminated clothing and loosen remaining clothing. Allow person to assume most comfortable position Page 2

3 and keep warm. Keep at rest until fully recovered. Get medical advice if breathing becomes difficult. Section 5. Hazard Type Hazards from combustion products Suitable Extinguishing media Precautions for firefighters and special protective clothing HAZCHEM CODE Section 6. Fire Fighting Measures Flammable Liquid or Vapour Under normal conditions of storage and use, hazardous decomposition products should not be produced. Water spray. Dry powder. Foam. Carbon dioxide. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 3Y Accidental Release Measures Wear protective equipment as detailed in Section 8. Clear area of any unprotected personnel. Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe Fumes, mist or vapours. Avoid contact with skin and eyes. Collect spillage. Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Dispose of according to Local Regulations. Section 7. Handling and Storage Precautions for Handling: Read label before use. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames or hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe fumes, mist, vapours or spray. Wash hands thoroughly after handling. Ensure good ventilation. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Avoid release to the environment. Wear protective clothing. Use personal protective equipment as required. Precautions for Storage: Store away from incompatible materials listed in Section 10. Store locked up. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Storage Temperature: <20 0 C. Section 8 Exposure Controls / Personal Protection WORKPLACE EXPOSURE STANDARDS (provided for guidance only) TWA STEL Page 3

4 Substance ppm mg/m 3 ppm mg/m 3 Xylene (o-, m-, p-isomers) n-butyl acetate Ethyl benzene Workplace Exposure Standard Time Weighted Average (WES-TWA).The time-weighted average exposure standard designed to protect the worker from the effects of long-term exposure. Workplace Exposure Standard Short-Term Exposure Limit (WESSTEL). The 15-minute average exposure standard. Applies to any 15- Minute period in the working day and is designed to protect the worker against adverse effects of irritation, chronic or irreversible tissue change, or narcosis that may increase the likelihood of accidents. The WES-STEL is not an alternative to the WES-TWA; both the short-term and time-weighted average exposures apply. Engineering Controls Ensure good ventilation of the work station. Personal Protection Equipment Eyes Materials for protective clothing Hands Skin Respiratory Section 9 Tightly fitting safety glasses with side shields. Avoid wearing contact lenses. Impermeable clothing. Wear protective gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Physical and Chemical Properties Appearance Colour Odour Odour Threshold ph Boiling Point Melting Point Freezing Point Flash Point Flammability Upper and Lower Explosive Limits Vapour Pressure Vapour Density Density Solubility Partition Coefficient: Auto-ignition Temperature Decomposition Temperature Viscosity, dynamic Particle Characteristics VOC content - Actual Liquid Green-brown Characteristic Not applicable >35 0 C 28 0 C Flammable. Density : g/cm Pa.s Not applicable 375 g/l Section 10. Stability and Reactivity Stability of Substance This product is stable under normal conditions. Possibility of hazardous No dangerous reactions known under normal conditions of use. Page 4

5 reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. None known. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11 Toxicological Information Acute Effects: Swallowed Dermal Inhalation Eye Skin Causes serious eye irritation. Causes mild skin irritation. Chronic Effects: Carcinogenicity Reproductive Toxicity Germ Cell Mutagenicity Aspiration STOT/SE STOT/RE Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Section 12. Ecotoxicological Information The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. Persistence and degradability Bioaccumulation Mobility in Soil Other adverse effects Section 13. Disposal Considerations Disposal Method: Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulation. Any container holding unwanted product or contaminated spill media should be labelled Hazardous Waste Flammable Precautions or methods to avoid: None known. Section 14 Transport Information This product is classified as a Dangerous Good for transport in NZ ; NZS 5433:2012 Road and Rail Transport Page 5

6 UN No: 1866 Class-primary 3 Packing Group III Proper Shipping Name: RESIN SOLUTION, Flammble Air Transport UN No: 1263 Class-primary 3 Packing Group II Proper Shipping Name: PAINT Marine Transport UN No: 1263 Class-primary 3 Packing Group II Proper Shipping Name: PAINT Dangerous Goods exemption if shipped in quantities < 5kg/l. Section 15 Regulatory Information EPA Approval Code: Surface Coatings and Colourants (Flammable, Toxic[6.7]) HSR HSNO Classification: 3.1C, 6.3B, 6.4A, 6.7B, 6.8B, 6.9B HSNO Controls: Trigger quantities for this substance: Approved Handler Location Certificate Tracking Trigger Quantities Signage Trigger Quantities Emergency Response Plan Secondary Containment Restriction of Use Trigger Quantity Not required 500L(>5L), 1500L(<5L), 250L open Not required 1000L (3.1C) 10000L(3.1C) 10000L(3.1C) None Section 16 Glossary EC50 EEL EPA HSNO LC50 LD50 LEL OSHA TEL TLV UEL WES Other Information Median effective concentration. Environmental Exposure Limit. Environmental Protection Authority Hazardous Substances and New Organisms. Lethal concentration that will kill 50% of the test organisms inhaling or ingesting it. Lethal dose to kill 50% of test animals/organisms. Lower explosive level. American Occupational Safety and Health Administration. Tolerable Exposure Limit. Threshold Limit Value-an exposure limit set by responsible authority. Upper Explosive Level Workplace Exposure Limit 1. HSNO Approved Code of Practice: Preparation of Safety Data Sheets, September Disclaimer This document has been issued by TCC (NZ) Ltd and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to TCC (NZ) Ltd or obtained from third party sources and is believed to represent the current state of knowledge as Page 6

7 to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer. While TCC (NZ) have taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, TCC (NZ) Ltd accept no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS The information herein is given in good faith, but no warranty, express or implied is made. Please contact the New Zealand distributor, if further information is required. Issue Date: 17 July 2017 Review Date: 17 July 2022 Page 7