Material Safety Data Sheet according to 91/155/EC - ISO

Transcription

1 Material Safety Data Sheet according to 91/155/EC - ISO Page 1 of 6 Lixtop MSDS-No. : Revision: printing date: Trade name: Lixtop 1. Identification of the substance/preparation and of the company/undertaking Intended use: Cleaners for Industrial Plastik Processing Company name: Henkel KGaA Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) Emergency information: The Henkel information service also provides an around-the-clock telephone service on phone no.++49-(0) for exceptional cases. Information office (content SDS): Henkel Technologies, Phone: +49-(0) , Fax: +49-(0) Declaration of ingredients according to 91/155/EC: 2. Composition / information on ingredients Hazardous components CAS-No. 1-Methoxypropan-2-ol Ethanol (2-Butoxyethoxy)ethanol Propoxypropan-2-ol Benzenesulfonic acid, C10-13-alkyl derivs., compds. with triethanolamine Amino-2-methylpropanol Dipropyleneglycol monomethylether EINECS content Classification % R % F - Highly flammable; R % Xi - Irritant; R % R % Xi - Irritant; R38, R % Xi - Irritant; R36/38 R52, R % No classification required. Declaration of ingredients according to Detergent Regulation 648/2004/EC < 5 % nonionic surfactants anionic surfactants Further ingredients perfumes

2 Lixtop Page 2 of 6 3. Hazards identification None if used properly. The product is not hazardous within the meaning of the valid (EU) preparation guideline. 4. First aid measures General information: If unconscious place recovery position and inform emergency services. Inhalation: Move to fresh air, administer oxygen, keep warm ; hospitalise. Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Combustion behaviour: In case of fire toxic gases can be released. Suitable extinguishing media: foam, extinguishing powder, carbon dioxide water spray jet 5. Fire fighting measures Extinguishing media which must not be used for safety reasons: Water jet (solvent-containing product). Special protection equipment for firefighters: Wear protective equipment. Additional information: In case of fire, keep containers cool with water spray. General information: Keep away from sources of ignition and naked flames. Personal precautions: Ensure adequate ventilation. Environmental precautions: Do not empty into drains / surface water / ground water. 6. Accidental release measures Clean-up methods: Wipe up using absorbent material and subject to waste incineration. Handling: Avoid skin and eye contact. Use only in well-ventilated areas. Avoid open flames and sources of ignition. Storage: Store only in the original container. 7. Handling and storage

3 Lixtop Page 3 of 6 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Germany Basis Germany - Occupational Exposure Limits Ingredient ppm mg/m 3 Type Category Remarks ethanol; ethyl alcohol amino-2-methylpropanol methoxy-2-propanol; monopropylene glycol methyl ether (2-METHOXYMETHYLETHOXY)- PROPANOL (ISOMERENGEMISCH) (2-butoxyethoxy)ethanol; diethylene glycol monobutyl ether Relevant German exposure-limit for working place (MAK-value) Occupational Exposure 1 4,6 Occupational Exposure Occupational Exposure Time Weighted Average (TWA) Limit (STEL): Skin designation Occupational Exposure Time Weighted Average (TWA). Skin designation. 100 Occupational Exposure 10 67,5 Time Weighted Average (TWA) ,2 Limit (STEL): Limit (STEL) - category 4. There is no risk of embryotoxicity when keeping the MAK and BAT levels. (OEL accord. to German regulations). 2 If in compliance with the MAK and BAT values, then there should be no risk to the fetus. Category II: substances with a resorptive effect. Listed. Listed. 2 If in compliance with the MAK and BAT values, then there should be no risk to the fetus. Can be absorbed through the skin. Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages. 1 Can be absorbed through the skin. Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages. 1 If in compliance with the MAK and BAT values, then there should be no risk to the fetus. Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages.

4 Lixtop Page 4 of 6 Engineering controls: Ensure good ventilation/suction at the workplace. Respiratory protection: When processing large amounts. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Protective goggles General protection and hygiene measures: Do not eat, drink or smoke while working. Avoid skin-contact. Use only in well-ventilated areas. 9. Physical and chemical properties Appearance Odor: liquid clear colourless characteristic ph-value (20 C (68 F); Conc.: 100 % product) Flash point Vapor pressure Density (20 C (68 F)) 9,50-10, C (118,4-131 F) The product does not support combustion in any way. Not available 0,980-0,999 g/cm3 Conditions to avoid: No decomposition if used according to specifications. Materials to avoid: Reaction with oxidants. Hazardous decomposition products: None if used for intended purpose. 10. Stability and reactivity 11. Toxicological information Oral toxicity: Acute oral toxicity: LD50 > 2000 mg/kg body weight (calculated). Inhalative toxicity: The toxicity of the product is due to its narcotic effect after inhalation. Skin irritation: Prolonged or repeated skin contact can lead to skin degreasing and hence to skin irritation.

5 Lixtop Page 5 of 6 Eye irritation: Prolonged or repeated contact may cause eye irritation. 12. Ecological information Persistence and degradability Degradation of surfactants Ultimate biodegradation: The biodegradability of the surfactants contained in the product is in accordance with the requirements of the EU Detergent Regulation (EC/648/2004) The surfactants contained in the products are primary biodegradable to at least 90% on average. The material is degraded quickly. The total of the organic substances contained in the product reach at least 60% BOD28/COD in the Closed Bottle Test or at least 70% DOC removal in the Modified OECD Screening Test. (OECD-limits for classification "readily biodegradable": at least 60% BOD28/COD resp. at least 70% DOC). 13. Disposal considerations Product Disposal methods: Waste incineration with the approval of the responsible local authority. Waste code(ewc ): The valid EWC wast code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Risk indication: Not classified as dangerous good if transport temperature is less than 48 degrees centigrade. Further information for transport: Not classified as dangerous good if transport temperature is less than 48 degrees centigrade. 15. Regulations - classification and identification Risk phrases: not applicable Safety phrases: not applicable Additional information: Not subject of the identification regulations. National regulations/information (Germany) WGK: Storage class VCI: WGK = 1, slightly water endangering product. Classification according to the mixture rules in German VwVwS regulation annex 4 from 27.July A

6 Lixtop Page 6 of Other information Full text of the R-phrases indicated by codes in this safety data sheet. The labeling of the product is indicated in Section 15. R10 Flammable. R11 Highly flammable. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R52 Harmful to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.