: Isobutane (8% - 20%) in Nitrogen
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- Eustace Nash
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1 SECTION 1: Identification 1.1. Identification Product name Isobutane (8% - 20%) in Nitrogen Date of issue: 04/01/2015 Revision date: 12/29/2015 Supersedes: 04/01/2015 Version: 1.1 : Isobutane (8% - 20%) in Nitrogen 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Calgaz, division of Airgas USA LLC 821 Chesapeake Drive Cambridge, USA T F info@calgaz.com Emergency telephone number : Test gas/calibration gas Emergency number : CHEMTREC: Internationally: SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable gases Category 1 Gases under pressure Compressed gas H220 H280 Full text of H statements : see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS02 GHS04 : H220 - Extremely flammable gas H280 - Contains gas under pressure; may explode if heated OSHA-H01 - May displace oxygen and cause rapid suffocation CGA-HG04 - May form explosive mixtures with air : P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective gloves, protective clothing P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely P381 - Eliminate all ignition sources if safe to do so P403 - Store in a well-ventilated place P501 - Dispose of contents/container in accordance with local/regional/national/international regulations CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52 C/125 F CGA-PG05 - Use a back flow preventive device in the piping CGA-PG06 - Close valve after each use and when empty CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG14 - Approach suspected leak area with caution CGA-PG21 - Open valve slowly 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable 10/03/2016 EN (English US) SDS ID: Page 1
2 SECTION 3: Composition/Information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Nitrogen (CAS No) Compressed gas, H280 Isobutane (CAS No) Flam. Gas 1, H220 Liquefied gas, H280 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. : Ingestion is not considered a potential route of exposure Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Symptoms/injuries upon intravenous administration Chronic symptoms : May displace oxygen and cause rapid suffocation. : Ingestion is not considered a potential route of exposure. : Not known Indication of any immediate medical attention and special treatment needed If you feel unwell, seek medical advice. If breathing is difficult, give oxygen. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : Do not use water jet to extinguish Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity : This product is flammable. : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. May form flammable/explosive vapor-air mixture. : None known Advice for firefighters Firefighting instructions Protection during firefighting Specific methods : In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. : Standard protective clothing and equipment (e.g., Self Contained Breathing Apparatus) for fire fighters. Do not enter fire area without proper protective equipment, including respiratory protection. : Exposure to fire may cause containers to rupture/explode. Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous/explosive re-ignition may occur. Extinguish any other fire. Continue water spray from protected position until container stays cool. Move containers away from the fire area if this can be done without risk. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Ensure adequate ventilation For non-emergency personnel Protective equipment Emergency procedures : Wear protective equipment consistent with the site emergency plan. : Evacuate personnel to a safe area. Close doors and windows of adjacent premises. Keep containers closed. Mark the danger area. Seal off low-lying areas. Keep upwind. 10/03/2016 EN (English US) SDS ID: /8
3 For emergency responders Protective equipment Emergency procedures : Standard protective clothing and equipment (e.g., Self Contained Breathing Apparatus) for fire fighters. Equip cleanup crew with proper protection. : Evacuate and limit access. Ventilate area. Remove ignition sources. Monitor concentration of released product. Consider the risk of potentially explosive atmospheres. Wear self-contained breathing apparatus when entering atmospheres of unknown contaminant concentration until proven to be safe Environmental precautions Try to stop release if without risk Methods and material for containment and cleaning up For containment Methods for cleaning up : Try to stop release if without risk. : Dispose of contents/container in accordance with local/regional/national/international regulations Reference to other sections See also Sections 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Safe handling of the gas receptacle Safe use of the product Hygiene measures : Pressurized container: Do not pierce or burn, even after use. Use only with equipment rated for cylinder pressure. Close valve after each use and when empty. Handle empty containers with care because residual vapors are flammable. In use, may form flammable vapor-air mixture. : Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools. : Do not remove or deface labels provided by the supplier for the identification of the cylinder contents. Protect cylinders from physical damage; do not drag, roll, slide or drop. : Only experienced and properly instructed persons should handle gases under pressure. Consider pressure relief device(s) in gas installations. Ensure the complete gas system was (or is regularly) checked for leaks before use. Do not smoke while handling product. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Assess the risk of potentially explosive atmospheres and the need for explosion-proof equipment. Keep away from ignition sources (including static discharges). Consider the use of flash back arrestors. : Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials Storage area : Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. : Do not expose to temperatures exceeding 52 C/ 125 F. Keep container closed when not in use. Protect cylinders from physical damage; do not drag, roll, slide or drop. Store in well ventilated area. : None known. : Oxidizing materials. Air. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store away from heat. Store in a well-ventilated place. ACGIH ACGIH STEL (ppm) 1000 ppm NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 800 ppm Not applicable 10/03/2016 EN (English US) SDS ID: /8
4 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection : Ensure exposure is below occupational exposure limits (where available). Provide adequate general and local exhaust ventilation. Systems under pressure should be regularly checked for leakages. Oxygen detectors should be used when asphyxiating gases may be released. Consider work permit system e.g. for maintenance activities. : Wear working gloves when handling gas containers. 29 CFR : Hand protection. : Wear safety glasses with side shields. 29 CFR : Eye and Face Protection. : Wear suitable protective clothing, e.g. lab coats, coveralls or flame resistant clothing. Respiratory protection : None necessary during normal and routine operations. See Sections 5 & 6. Thermal hazard protection Environmental exposure controls Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Relative gas density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity None known Chemical stability Stable under normal conditions Possibility of hazardous reactions Can form explosive mixture with air Conditions to avoid : None necessary during normal and routine operations. : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment. : Wear safety shoes while handling containers. 29 CFR : Foot Protection. : Gas : Clear, colorless gas. : Colorless : gasoline-like : Without adequate ventilation formation of explosive mixtures may be possible. : None. : Similar to air : Water None under recommended storage and handling conditions (see section 7). 10/03/2016 EN (English US) SDS ID: /8
5 10.5. Incompatible materials Oxidizing materials. Air Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Likely routes of exposure Acute toxicity LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) ATE US (gases) ATE US (vapors) ATE US (dust, mist) LC50 inhalation rat (ppm) ATE US (gases) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Symptoms/injuries upon intravenous administration Chronic symptoms : Inhalation 658 mg/l/4h ppm/4h ppmv/4h mg/l/4h mg/l/4h ppm/4h ppmv/4h : May displace oxygen and cause rapid suffocation. : Ingestion is not considered a potential route of exposure. : Not known. SECTION 12: Ecological information Toxicity No additional information available Persistence and degradability Persistence and degradability Persistence and degradability The substance is biodegradable. Unlikely to persist. No ecological damage caused by this product Bioaccumulative potential BCF fish Log Pow 2.76 Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. 10/03/2016 EN (English US) SDS ID: /8
6 Log Pow Bioaccumulative potential Not applicable for inorganic gases. No ecological damage caused by this product Mobility in soil Ecology - soil Ecology - soil Other adverse effects Effect on ozone layer Effect on the global warming Because of its high volatility, the product is unlikely to cause ground or water pollution. No ecological damage caused by this product. : No known effects from this product : No known ecological damage caused by this product. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT : Contact supplier if guidance is required. Do not discharge into any place where its accumulation could be dangerous. Ensure that the emission levels from local regulations or operating permits are not exceeded. Waste gas should be flared through a suitable burner with flash back arrestor. Do not discharge into areas where there is a risk of forming an explosive mixture with air. : Refer to the CGA Pamphlet P-63 "Disposal of Gases" available at for more guidance on suitable disposal methods. Transport document description : UN1954 Compressed gas, flammable, n.o.s. (Nitrogen, Isobutane), 2.1 UN-No.(DOT) Proper Shipping Name (DOT) : UN1954 : Compressed gas, flammable, n.o.s. Class (DOT) : Class Flammable gas 49 CFR Hazard labels (DOT) : Flammable gas DOT Packaging Non Bulk (49 CFR 173.xxx) : 302;305 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 DOT Symbols DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Quantity Limitations Passenger aircraft/rail (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 CFR ) DOT Vessel Stowage Location DOT Vessel Stowage Other Other information : G - Identifies PSN requiring a technical name : Forbidden : 150 kg : D - The material must be stowed on deck only on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on passenger vessels in which the limiting number of passengers is exceeded : 40 - Stow clear of living quarters : No supplementary information available. TDG Transport document description : UN1954 Compressed gas, flammable, n.o.s., 2.1 UN-No. (TDG) : UN1954 Proper Shipping Name : Compressed gas, flammable, n.o.s. 10/03/2016 EN (English US) SDS ID: /8
7 TDG Primary Hazard Classes : Class Flammable Gas. Transport by sea UN-No. (IMDG) : 1954 Proper Shipping Name (IMDG) : Compressed gas, flammable, n.o.s. Class (IMDG) : 2 - Gases Air transport UN-No. (IATA) : 1954 Proper Shipping Name (IATA) : Compressed gas, flammable, n.o.s. Class (IATA) : 2 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class A - Compressed Gas Class B Division 1 - Flammable Gas Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class A - Compressed Gas EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) US State regulations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 10/03/2016 EN (English US) SDS ID: /8
8 U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 12/29/2015 Other information : This is offered pursuant to OSHA s Hazard Communication Standard, 29 CFR, Other government regulations must be reviewed for applicability to this product. Full text of H-phrases: H220 Extremely flammable gas H280 Contains gas under pressure; may explode if heated SDS US (GHS HazCom 2012) This is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR, Other government regulations must be reviewed for applicability to this gas mixture. To the best of Calgaz's knowledge, the information contained herein is reliable and accurate as of this date; however, accruacy, suitability or completeness are not guaranteed and no warranties of any type, either express or implied, are provided. The information contained herein relates only to this specific product. If this gas mixture is combined with other materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition. 10/03/2016 EN (English US) SDS ID: /8
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