HENKEL LOCTITE CORPORATION 02/02/03 ROCKY HILL, CONNECTICUT EMERGENCY PHONE: (860) MATERIAL SAFETY DATA SHEET Page 01 of 05

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1 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL SAFETY DATA SHEET Page 01 of 05 Part of Kit: Product Type: Epoxy Resin 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Epoxy resin ETHER Benzyl alcohol Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER ETHER 100 ppm TWA 100 ppm TWA 360 mg/m3 Exposure Limits (STEL) ACGIH OSHA ETHER 150 ppm 150 ppm 540 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Eye, skin and respiratory tract irritant. May cause allergic skin reaction and/ or dermatitis with prolonged exposure. Skin and eye contact, inhalation. Skin and eye irritant. May cause headaches, nausea, dizziness and respiratory tract irritation if inhaled. eczema and other skin conditions, allergies. MATERIAL SAFETY DATA SHEET Page 02 of HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Epoxy resin ALG IRR NO NO NO ETHER CNS IRR NO NO NO Benzyl alcohol ALG CNS COR IRR NO NO NO Abbreviations ALG Allergen COR Corrosive CNS Central nervous system IRR Irritant 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: Do not induce vomiting. If conscious, give large amounts of water to dilute. Get medical attention Move to an area free from risk of further exposure. Give oxygen if breathing is difficult. Get medical attention. Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Flush with large quantities of water for at least 15 minutes. Get medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200 F Method: Tag Closed Cup Recommended Extinguishing Agents: Caron dioxide, foam, dry chemical Special Firefighting 1

2 Procedures: Hazardous Products formed by Fire or Thermal Decomp Carbon Monoxide, Carbon Dioxide, and oxides of Nitrogen. Unusual Fire or Explosion Hazards: Explosive Limits: (% by volume in air)lower (% by volume in air)upper Closed containers may rupture when exposed to extreme heat, due to build up of pressure. Decomposition and combustion products may be toxic. MATERIAL SAFETY DATA SHEET Page 03 of ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up as much as possible with an inert absorbent and store in a closed container until disposal. Flush contaminated area with water; prevent washings from entering waterways. 7. HANDLING AND STORAGE Safe Storage: Store in closed containers in a cool, well ventilated area. Do not exceed teperatures above 110 F. (Contact Loctite Customer Service for shelf life information) Handling: Avoid contact with skin and eyes. Avoid inhaling or swallowing. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Safety glasses or goggles. Impervious gloves Local exhaust recommended to maintain levels below the TLV. Mechanical exhaust is not recommended as the sole means of controlling employee exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES See Section 2 for Exposure Limits. Appearance: Clear liquid Odor: Mild sweet Boiling Point: 212 F ph: Does not apply Solubility in Water: Specific Gravity Volatile Organic Compound (EPA Method 24) 50 60% volatile by volume Vapor Pressure: 2 mm Hg Vapor Density: Heavier than air Evaporation Rate (Ether = 1) 1.0 (Butyl Acetate = 1) 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents, acids. Conditions to Avoid: MATERIAL SAFETY DATA SHEET Page 04 of STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non thermal): 11. TOXICOLOGICAL INFORMATION See Section ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS 2

3 Recommended methods of disposal: EPA Hazardous Waste Number Incinerate following EPA and local regulations. 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Hazard Class or Division: Identification Number: Marine Pollutant: IATA Proper Shipping Name: Class or Division: UN or ID Number: Paint 15. REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Flammability Hazard: 1 MATERIAL SAFETY DATA SHEET Page 05 of OTHER INFORMATION (continued) Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Rajal Dhruva Title: Health and Regulatory Affairs Specialist Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: February 13, 2002 Revision: First Issue 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL SAFETY DATA SHEET Page 01 of 05 Part of Kit: Product Type: Epoxy Hardener 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyamide Polymer Proprietary ETHER TETRAETHYLENEPENTAMINE Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER ETHER 100 ppm TWA 100 ppm TWA 360 mg/m3 Exposure Limits (STEL) ACGIH OSHA 3

4 ETHER 150 ppm 150 ppm 540 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: May cause sever eye and skin irritation. May cause allergic skin reaction and/or dermatitis with prolonged exposure. May cause respiratory tract irritation. Skin and eye contact, inhalation. Skin and eye irritation. May cause nose and throat irritation, headaches, dizziness and nausea if inhaled. eczema and other skin conditions, allergies. MATERIAL SAFETY DATA SHEET Page 02 of HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyamide Polymer No Data NO NO NO ETHER CNS IRR NO NO NO TETRAETHYLENEPENTAMINE ALG IRR MUT NO NO NO Abbreviations ALG Allergen IRR Irritant CNS Central nervous system MUT Mutagen 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: Do not induce vomiting. Drink 1 2 glasses of water. Get medical attention. Move to an area free from risk of further exposure. Give oxygen if breathing is difficult. Get medical attention. Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Flush with large quantities of water for at least 15 minutes. Get medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200 F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical. Special Firefighting Procedures: Hazardous Products formed by Fire or Thermal Decomp Carbon Monoxide, Carbon Dioxide, and Oxides of Nitrogen. Unusual Fire or Explosion Hazards: Explosive Limits: (% by volume in air)lower (% by volume in air)upper Closed containers may rupture when exposed to extreme heat. Decomposition and combustion products may be toxic. MATERIAL SAFETY DATA SHEET Page 03 of ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Remove all sources of ignition. Soak up as much as possible with an inert absorbent and store in a closed container until disposal. Flush contaminated area with water, prevent washings from entering the waterways. 7. HANDLING AND STORAGE Safe Storage: Store below 110 F. (Contact Loctite Customer Service for shelf life information) 4

5 Handling: Avoid contact with skin and eyes. Avoid inhaling or swallowing. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Safety glasses or goggles. Impervious gloves Explosion proof mechanical ventilation and local exhaust should be used to maintain levels below the TLV. Mechanical exhaust is not recommended as the sole means of controlling employee exposure. NIOSH approved respirtor with organic vapor cartridge if required. 9. PHYSICAL AND CHEMICAL PROPERTIES See Section 2 for Exposure Limits. Appearance: Clear liquid Odor: Mild sweet Boiling Point: 275 F ph: Does not apply Solubility in Water: Specific Gravity 1.08 Volatile Organic Compound (EPA Method 24) % volatile by volume Vapor Pressure: 3.8 mm Hg Vapor Density: Heavier than air Evaporation Rate (Ether = 1) 1.0 (Butyl Acetate = 1) 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents, acids Conditions to Avoid: MATERIAL SAFETY DATA SHEET Page 04 of STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non thermal): 11. TOXICOLOGICAL INFORMATION See Section ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: EPA Hazardous Waste Number Incinerate following EPA and local regulations. 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Hazard Class or Division: Identification Number: Marine Pollutant: IATA Proper Shipping Name: Class or Division: UN or ID Number: 15. REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: 5

6 Flammability Hazard: 1 MATERIAL SAFETY DATA SHEET Page 05 of OTHER INFORMATION (continued) Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Rajal Dhruva Title: Health and Regulatory Affairs Specialist Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: February 13, 2002 Revision: First Issue application assistance. browse catalog. troubleshooting. equipment datasheets. distributor locator.what's new. career opportunities about loctite. contact loctite. literature. loctite world wide. search. home copyright Loctite 6