Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : BioKelp Humic : M Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet JR Simplot Company P.O. Box Boise, ID T Emergency telephone number Emergency number : CHEMTREC SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Corr. 1A H314 Full text of H statements : see section Label elements GHS-US labelling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning : H314 - Causes severe skin burns and eye damage : P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor/ P321 - Specific treatment (see supplemental first aid instruction on this label) P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to Other hazards 2.4. Unknown acute toxicity (GHS US) data available SECTION 3: Composition/information on ingredients 3.1. Substance t applicable 3.2. Mixture Name Product identifier % GHS-US classification t classified *ingredients without WT% are considered proprietary based on trade secrets 06/23/2017 EN (English) Page 1

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. tify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. : Wash hands, forearms and face thoroughly after handling. : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. 06/23/2017 EN (English) 2/6

3 Incompatible products Incompatible materials : Strong bases. Strong acids. : Sources of ignition. Direct sunlight Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Brown-black Odour : Marine odor Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 9.5 lbs./gal Solubility : Water: Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability 06/23/2017 EN (English) 3/6

4 10.3. Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Causes severe skin burns and eye damage. : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity Persistence and degradability BioKelp Humic Persistence and degradability Persistence and degradability Bioaccumulative potential BioKelp Humic Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects Effect on ozone layer Effect on the global warming : : known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to... 06/23/2017 EN (English) 4/6

5 Ecology - waste materials SECTION 14: Transport information In accordance with DOT t regulated for transport Additional information : Avoid release to the environment. : supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Kelp CAS % CAS % t listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations Classification according to Regulation (EC). 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] t classified National regulations US State regulations BioKelp Humic() Carcinogens List Developmental Toxicity Reproductive Toxicity - Female Reproductive Toxicity - Male California This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm Carcinogens List Developmental Toxicity Reproductive Toxicity - Female Reproductive Toxicity - Male n-significant risk level (NSRL) SECTION 16: : 06/23/2017 EN (English) 5/6

6 : ne. Full text of H-statements: H314 Causes severe skin burns and eye damage SDS US (GHS HazCom 2012) - Custom Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. 06/23/2017 EN (English) 6/6