Safety Data Sheet Revision Date: 07/16/18

Transcription

1 1. IDENTIFICATION Safety Data Sheet Revision Date: 07/16/18 Catalog Number / Product Name: / DHA Paraffins Standard Company: Address: Restek Corporation 110 Benner Circle Bellefonte, Pa Phone#: Fax#: Emergency#: (CHEMTREC) (Outside the US) Revision Number: 3 Intended use: For Laboratory use only 2. HAZARD(S)IDENTIFICATION Emergency Overview: 2 Letter ISO country code/language code: US/EN GHS Hazard Symbols: GHS Classification: GHS Signal Word: GHS Hazard: GHS Precautions: Safety Precautions: First Aid Measures: Flammable Liquid Category 2 Skin Corrosion/Irritation Category 2 Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure Category 2 Hazardous to the aquatic environment - Acute Category 2 Hazardous to the aquatic environment - Chronic Category 2 Danger Highly flammable liquid and vapour. Causes skin irritation. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life.. Toxic to aquatic life with long lasting effects. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilation and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and skin thoroughly after handling. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention if you feel unwell. Specific treatment see section 4. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use extinguishing media in section 5 for extinction. Collect spillage / DHA Paraffins Standard Page 1 of 7

2 Storage: Disposal: Single Exposure Target Organs: Repeated Exposure Target Organs: Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container according to section 13 of the SDS. Specific target organ toxicity - Single exposure - STOT SE 3: H336 May cause drowsiness or dizziness. Specific target organ toxicity - Repeated exposure - STOT RE 2: H373 May cause damage to organs through prolonged or repeated exposure. (C >= 5 %; Minimum classification, No information to prove exclusion of certain routes of exposure) 3. COMPOSITION / INFORMATION ON INGREDIENT CAS # EINEC # % Composition n-decane n-tetradecane n-pentadecane hexane n-pentane n-dodecane nonane Heptane tridecane N-Undecane n-octane FIRST-AID MEASURES Inhalation: Eyes: Skin Contact: Ingestion: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician. Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists.. Induce vomiting as a last measure. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal. 5. FIRE- FIGHTING MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when fighting fires. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the fire. Do not direct a water stream directly into the hot burning liquid. Use alcohol resistant foam, carbon dioxide, or dry chemical when fighting fires. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the surface of the fire. Do Not direct a stream of water into the hot burning liquid. Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water may be ineffective but water spray can be used extinguish a fire if swept across the base of the flames. Water can absorb heat and keep exposed material from being damaged by fire. Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and / DHA Paraffins Standard Page 2 of 7

3 Fire Fighting Methods and Protection: Hazardous Combustion Products: 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Methods for Clean-up: flash back Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury or death. Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Carbon dioxide, Carbon monoxide Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 7. HANDLING AND STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Use spark-proof tools and explosion-proof equipment Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep away from sources of ignition 8. EXPOSURE CONTROLS / PERSONAL PROTECTION United States: IDLH ACGIH STEL ACGIH TLV-TWA OSHA Exposure Limit n-decane Not None Known Not n-tetradecane Not None Known Not n-pentadecane Not None Known Not hexane ppm IDLH (10% LEL) n-pentane ppm IDLH (10% LEL) n-dodecane Not nonane Not Heptane ppm IDLH tridecane Not N-Undecane Not n-octane ppm IDLH (10% LEL) 1000 ppm 50 ppm TWA 500 ppm TWA; 1800 mg/m3 TWA None Known 600 ppm TWA (listed under Pentane, all isomers) 1000 ppm TWA; 2950 mg/m3 TWA None Known Not None Known 200 ppm TWA 500 ppm STEL (listed under Heptane, all isomers) 400 ppm TWA; 1640 mg/m3 TWA 500 ppm TWA; 2000 mg/m3 TWA None Known Not None Known Not (375) ppm STEL; (1750) mg/m3 STEL 300 ppm TWA; 1400 mg/m3 TWA 500 ppm TWA; 2350 mg/m3 TWA / DHA Paraffins Standard Page 3 of 7

4 Personal Protection: Engineering Measures: Respiratory Protection: Eye Protection: Skin Protection: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate symptoms. Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an eye wash station available. Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance, color: Odor: Mild Physical State: ph: Not applicable Vapor Pressure: Boiling Point ( C): C at 760 mmhg (HSDB) C at 760 mmhg (HSDB) C at 760 mmhg (HSDB) 98.5 C (HSDB) C (HSDB) C (HSDB) 36.1 C (HSDB) C (HSDB) C at 760 mmhg (HSDB) C (HSDB) Flash Point ( F): -56 Flammability: Extremely Flammable Upper Flammable/Explosive Limit, % in air: 6.5 Lower Flammable/Explosive Limit, % in air: 0.5 Autoignition Temperature ( C): deg C Decomposition Temperature ( C): Evaporation Rate: Odor Threshold: ND Solubility: Negligible; 0-1% Partition Coefficient: n-octanol in water: VOC % by weight: 0 Molecular Weight: 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid / Chemical Incompatiability: Hazardous Decomposition Products: Stable under normal conditions. Temperatures above flash point in combination with sparks, open flames, or other sources of ignition.contamination High temperatures Strong oxidizing agents Carbon dioxide Carbon monoxide 11. TOXICOLOGICAL INFORMATION Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: Eyes, Central nervous system stimulation, Respiratory Tract, Skin, Peripheral Nervous System Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Eye Contact: Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Ingestion Irritation: May be harmful if swallowed / DHA Paraffins Standard Page 4 of 7

5 Long-Term (Chronic) Health Effects: Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: Skin Absorption:. to indicate product or any components present at greater than 0.1% may cause birth defects. Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.toxic! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs). Harmful! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs) Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause minor systemic damage. Component Toxicological Data: NIOSH: LD50/LC50 n-octane Inhalation LC50 Rat : 118 gm/m3/4h Octane n-tridecane Dermal LD50 Rabbit >5000 mg/kg (no deaths occurred); Inhalation LC50 Rat >41 ppm 8 h; Oral LD50 Rat >5000 mg/kg N-Undecane Inhalation LC50 Rat >2.82 mg/l 8 h Heptane Dermal LD50 Rabbit 3000 mg/kg Nonane Inhalation LC50 Rat 3200 ppm 4 h (Source: IUCLID) Dodecane Inhalation LC50 Rat >142 ppm 8 h (Source: IUCLID) Pentane Oral LD50 Rat >2000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg; Inhalation LC50 Rat 364 g/m3 4 h n-hexane Dermal LD50 Rabbit 3000 mg/kg; Inhalation LC50 Rat ppm 4 h; Oral LD50 Rat 25 g/kg Tetradecane Dermal LD50 Rat >5000 mg/kg Decane Dermal LD50 Rat >2000 mg/kg (no deaths occurred); Inhalation LC50 Rat >1369 ppm 8 h (no deaths occurred, vapor); Oral LD50 Rat >5000 mg/kg Component Carcinogenic Data: OSHA: ACGIH: NIOSH: NTP: IARC: Group No. 12. ECOLOGICAL INFORMATION Overview: Mobility: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife / DHA Paraffins Standard Page 5 of 7

6 Persistence: Bioaccumulation: Degradability: Ecological Toxicity Data: 13. DISPOSAL CONSIDERATIONS Waste Description of Spent Product: Disposal Methods: Waste Disposal of Packaging: Spent or discarded material is a hazardous waste.mixing spent or discarded material with other materials may render the mixture hazardous. Perform a hazardous waste determination on mixtures. Dispose of by incineration following Federal, State, Local, or Provincial regulations. Comply with all Local, State, Federal, and Provincial Environmental Regulations. 14. TRANSPORTATION INFORMATION United States: DOT Proper Shipping Name: Flammable liquids, n.o.s. (Hexane, Heptane) UN Number: UN1993 Hazard Class: 3 Packing Group: II International: IATA Proper Shipping Name: Flammable liquids, n.o.s. (Hexane, Heptane) UN Number: UN1993 Hazard Class: 3 Packing Group: II Marine Pollutant: No CAS# Marine Pollutant Severe Marine Pollutant 15. REGULATORY INFORMATION United States: CAS# CERCLA SARA 313 SARA EHS TSCA 313 n-decane X n-tetradecane X n-pentadecane X hexane X X - X n-pentane X n-dodecane X nonane X Heptane X tridecane X N-Undecane X n-octane X The following chemicals are listed on CA Prop 65: CAS # Regulation State Right To Know Listing: CAS# New Jersey Massachusetts Pennsylvania California n-decane X - X - n-tetradecane n-pentadecane hexane X X X - n-pentane X X X X n-dodecane nonane X X X X Heptane X X X X tridecane / DHA Paraffins Standard Page 6 of 7

7 N-Undecane X n-octane X X X X 16. OTHER INFORMATION Prior Version Date: 11/21/16 Other Information: Any changes to the SDS compared to previous versions are marked by a vertical line in front of the concerned paragraph. References: Disclaimer: Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a particular purpose, are made regarding products described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk / DHA Paraffins Standard Page 7 of 7