SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.2 Revision Date: 07/21/2018

Transcription

1 1. Identification SAFETY DATA SHEET Material name: Vulkem 951 NF Material: Recommended use and restriction on use Recommended use: Curative Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco Canadian Sealants 220 Wicksteed Ave Toronto ON M4H 1G7 CA Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Label Elements Hazard Symbol: Signal Word: Hazard Statement: Danger Causes severe skin burns and eye damage.may cause an allergic skin reaction.combustible liquid. Precautionary Statements Prevention: Response: Do not breathe dust/fume/gas/mist/vapors/spray.wash thoroughly after handling.wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove person to fresh air and keep 1/11

2 comfortable for breathing. Immediately call a POISON CENTER/doctor. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Hazard(s) not otherwise classified (HNOC): None. 3. Composition/information on ingredients Mixtures Composition Comments: The components are not hazardous or are below required disclosure limits. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Move to fresh air. Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Rinse immediately with plenty of water. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: 2/11

3 Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. 7. Handling and storage Precautions for safe handling: Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities: Store away from incompatible materials. Store in original tightly closed container. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits None of the components have assigned exposure limits. None of the components have assigned exposure limits. Appropriate Engineering Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Use personal protective equipment as required. Wear goggles/face shield. Use suitable protective gloves if risk of skin contact. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. 3/11

4 Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing to remove contaminants. Discard contaminated footwear that cannot be cleaned. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: Pale yellow Odor: amine like Odor threshold: ph: Melting point/freezing point: Initial boiling point and boiling range: Flash Point: 86 C 187 F(Pensky-Martens Closed Cup) Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: Solubility(ies) Solubility in water: Insoluble in water Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Conditions to avoid: Material is stable under normal conditions. Avoid heat or contamination. 4/11

5 Incompatible Materials: Hazardous Decomposition Products: Strong acids. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Eye contact: Ingestion: Moderately irritating to skin with prolonged exposure. Eye contact is possible and should be avoided. May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: Skin Contact: Eye contact: Ingestion: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal ATEmix: 4,150 mg/kg Not classified for acute toxicity based on available data. Inhalation Repeated dose toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization 5/11

6 Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates Chronic hazards to the aquatic environment: 6/11

7 Fish Aquatic Invertebrates Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Mobility in soil: Other adverse effects: 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: UN1760, CORROSIVE LIQUID, N.O.S. (Aliphatic Amine), 8, PG III CFR / DOT: IMDG: UN1760, Corrosive liquids, n.o.s. (Aliphatic Amine), 8, PG III UN1760, CORROSIVE LIQUID, N.O.S. (Aliphatic Amine), 8, PG III Further Information: The above shipping description may not be accurate for all container sizes and all modes of transportation. Please refer to Bill of Lading. 7/11

8 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) CERCLA Hazardous Substance List (40 CFR 302.4): Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Not listed. SARA 302 Extremely Hazardous Substance SARA 304 Emergency Release Notification SARA 311/312 Hazardous Chemical SARA 313 (TRI Reporting) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) US State Regulations US. California Proposition 65 No ingredient regulated by CA Prop 65 present. US. New Jersey Worker and Community Right-to-Know Act No ingredient regulated by NJ Right-to-Know Law present. US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances No ingredient regulated by PA Right-to-Know Law present. US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. International regulations 8/11

9 Montreal protocol Not applicable Stockholm convention Not applicable Rotterdam convention Not applicable Kyoto protocol Not applicable VOC: Regulatory VOC (less water and exempt solvent) : 0 g/l VOC Method 310 : 0.00 % 9/11

10 Inventory Status: Australia AICS: Canada DSL Inventory List: EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: Mexico INSQ: Ontario Inventory: Taiwan Chemical Substance Inventory: not listed on or not listed on or not listed on or not listed on or not listed on or not listed on or not listed on or 10/11

11 16.Other information, including date of preparation or last revision Version #: 1.2 Further Information: Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 11/11

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