SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions ne. Printing ink. ne known. Manufacturer/Importer/Supplier/Distributor information Company name Diagraph Marking & Coding Address 507 Meadowland Parkway, Marion IL, USA Telephone Contact person Customer Service Emergency phone number Infotrac US only International 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Flammable liquids Acute toxicity, oral Skin corrosion/irritation Serious eye damage/eye irritation Specific target organ toxicity, single exposure t classified. Category Category 4 Category 2 Category 1 Category narcotic effects Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger Flammable liquid and vapor. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause drowsiness or dizziness. Keep away from heat/sparks/open flames/hot surfaces. - smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. In case of fire: Use dry chemical powder, carbon dioxide, dry sand to extinguish. Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. ne Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

2 . Composition/information on ingredients Mixtures Chemical name 1-Propanol Bis(2-ethylhexyl) hydrogen phosphate Ethylene glycol monophenyl ether CAS number % < < 2 Composition comments 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. Carbon dioxide (CO2). Dry chemical powder. Dry sand. Do not use water. Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Flammable liquid and vapor. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

3 Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 1 of the SDS. Avoid discharge into drains, water courses or onto the ground. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not get this material in contact with eyes. Avoid contact with skin and clothing. Avoid breathing mist or vapor. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Use care in handling/storage. Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Type Value US. ACGIH Threshold Limit Values PEL Type TWA 500 mg/m 200 ppm Value 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Type Value STEL 625 mg/m 250 ppm TWA 500 mg/m 200 ppm Biological limit values biological exposure limits noted for the ingredient(s). Exposure guidelines US - California OELs: Skin designation Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Skin designation applies. US. NIOSH: Pocket Guide to Chemical Hazards Can be absorbed through the skin Version #: 02 Revision date: 04-December-2018 Issue date: 04-December-2018 / 8

4 Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles) and a face shield. Eye/face protection Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Skin protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Wear appropriate chemical resistant clothing. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear appropriate thermal protective clothing, when necessary. When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Liquid. Liquid. According to product specification. Characteristic. 7.4 F (2.0 C) t applicable. Upper/lower flammability or explosive limits Explosive limit - lower (%) 2.1 % v/v Explosive limit - upper (%) 1.5 % v/v Vapor pressure Vapor pressure temp. Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Density Explosive properties Oxidizing properties 19 hpa (14 mm Hg) 68 F (20 C) t miscible or difficult to mix g/cm³ ( F/20 C t explosive. t oxidizing Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

5 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Protect against direct sunlight. Contact with incompatible materials. Strong oxidizing agents. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Causes skin irritation. Causes serious eye damage. Harmful if swallowed. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. Harmful if swallowed. Species Acute Test Results Dermal LD50 Rabbit 2251 mg/kg Oral LD50 Rat 186 mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes skin irritation. Causes serious eye damage. t a respiratory sensitizer. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. t classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity t listed. NTP Report on Carcinogens t listed. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects This product is not expected to cause reproductive or developmental effects. May cause drowsiness and dizziness. t classified. t an aspiration hazard. Prolonged inhalation may be harmful Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

6 12. Ecological information Ecotoxicity Aquatic Acute Algae Crustacea Fish Persistence and degradability Bioaccumulative potential The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. EC50 EC50 LC50 Species Scenedesmus subspicatus Daphnia magna Pimephales promelas data is available on the degradability of this product. Partition coefficient n-octanol / water (log Kow) Bis(2-ethylhexyl) hydrogen phosphate (CAS ) Mobility in soil Other adverse effects 1. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information Test Results > 500 mg/l, 72 Hours 488 mg/l, 48 Hours 44 mg/l, 96 Hours The product is immiscible in water. Expected to have low mobility in soil. ne known. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. DOT UN number UN1210 UN proper shipping name Printing ink, flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group III Environmental hazards Marine pollutant Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions B1, IB, T2, TP1 Packaging exceptions 150 Packaging non bulk 17 Packaging bulk 242 IATA UN number UN1210 UN proper shipping name Printing ink flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group III Environmental hazards ERG Code L Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

7 Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 7/78 and the IBC Code 15. Regulatory information US federal regulations Read safety instructions, SDS and emergency procedures before handling. UN1210 PRINTING INK flammable - III F-E, S-D Read safety instructions, SDS and emergency procedures before handling. t established. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 02.4) SARA 04 Emergency release notification Listed. t regulated. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 02 Extremely hazardous substance t listed. SARA 11/12 Hazardous chemical Classified hazard categories SARA 1 (TRI reporting) Chemical name Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) CAS number Ethylene glycol monophenyl ether < 2 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List % by wt. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.10) t regulated. Safe Drinking Water Act (SDWA) t regulated. FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act Bis(2-ethylhexyl) hydrogen phosphate (CAS ) Low priority Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8

8 US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, , subd. (a)) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Taiwan United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Taiwan Chemical Substance Inventory (TCSI) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 02 HMIS ratings NFPA ratings 04-December December-2018 Health: Flammability: Physical hazard: 0 0 Disclaimer Diagraph Marking & Coding cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available Version #: 02 Revision date: 04-December-2018 Issue date: 04-December / 8