Chemical Name: Super Spec Aliphatic Acrylic Urethane Gloss Catalyst

Transcription

1 Chemical Name: Super Spec Aliphatic Acrylic Urethane Gloss Catalyst Manufacturer: Benjamin Moore Container size: NA Location: VLA Disposal: Place empty container in trash.

2 Material Safety Data Sheet Revision Number: 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Product Code Product Class Color Manufacturer Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ Phone: SUPER SPEC HP ACRYLIC EPOXY COATING P4384 WATER THINNED PAINT All Emergency Telephone Number(s) CHEMTREC: COMPOSITION INFORMATION ON COMPONENTS Hazardous Components Chemical Name CAS- Weight % (max) Epoxy resin Epoxy phenol novolac resin Ethylene glycol mono-2-ethylhexyl ether HAZARDS IDENTIFICATION Emergency Overview WARNING Harmful by inhalation. Irritating to eyes. Irritating to skin. May cause sensitization by skin contact. May be harmful if swallowed. IMPORTANT: Designed to be mixed with other components. Mixture will have hazards of all components. Appearance liquid OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ).. Odor epoxy Potential Health Effects Principal Routes of Exposure Eye contact, skin contact and inhalation. Page 1 / 8

3 Acute Effects Eyes Skin Inhalation Ingestion Chronic Effects Moderately irritating to the eyes. Irritating to skin. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause skin sensitization. Harmful by inhalation. High vapor / aerosol concentrations are irritating to the eyes, nose, throat and lungs and may cause headaches, dizziness, drowsiness, unconsciousness, and other central nervous system effects. Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons. See Section 11 for additional Toxicological information. Aggravated Medical Conditions ne known HMIS Health: 2 Flammability: 0 Reactivity: 0 PPE: - HMIS Legend 0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions. te: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use. Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer, has choosen to provide them. HMIS ratings are to be used only in conjunction with a fully implemented HMIS program by workers who have received appropriate HMIS training. HMIS is a registered trade and service mark of the NPCA. HMIS materials may be purchased exclusively from J. J. Keller (800) FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Immediate medical attention is not required. Show this safety data sheet to the doctor in attendance. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Move to fresh air. If symptoms persist, call a physician. If not breathing, give artificial respiration. Call a physician immediately. Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Consult a physician.. Page 2 / 8

4 tes To Physician Protection Of First-Aiders Treat symptomatically. Use personal protective equipment. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Protective Equipment And Precautions For Firefighters Specific Hazards Arising From The Chemical Sensitivity To Mechanical Impact Sensitivity To Static Discharge Flash Point Data Flash Point ( F) Flash Point ( C) Flash Point Method Flammability Limits In Air Lower Explosion Limit Upper Explosion Limit Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Closed containers may rupture if exposed to fire or extreme heat. Thermal decomposition can lead to release of irritating gases and vapors. t applicable t applicable t applicable t applicable t applicable NFPA Health: 2 Flammability: 0 Instability: 0 Special: t Applicable NFPA Legend 0 - t Hazardous 1 - Slightly 2 - Moderate 3 - High 4 - Severe The ratings assigned are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods For Clean-Up Use personal protective equipment. Avoid contact with skin, eyes and clothing. Prevent further leakage or spillage if safe to do so.. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Page 3 / 8

5 Other Information ne known 7. HANDLING AND STORAGE Handling Storage Use only in area provided with appropriate exhaust ventilation. Avoid contact with skin, eyes and clothing. Avoid breathing vapors, spray mists or sanding dust. In case of insufficient ventilation, wear suitable respiratory equipment. Keep container tightly closed. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Hazardous Components Chemical Name ACGIH OSHA Epoxy resin N/E N/E Epoxy phenol novolac resin N/E N/E Ethylene glycol mono-2-ethylhexyl ether N/E N/E Legend ACGIH - American Conference of Governmental Industrial Hygienists Exposure Limits OSHA - Occupational Safety & Health Administration Exposure Limits N/E - t Established Engineering Measures Personal Protective Equipment Eye/Face Protection Skin Protection Respiratory Protection Hygiene Measures Ensure adequate ventilation, especially in confined areas. Safety glasses with side-shields. Protective gloves and impervious clothing. In operations where exposure limits are exceeded, use a NIOSH approved respirator that has been selected by a technically qualified person for the specific work conditions. When spraying the product or applying in confined areas, wear a NIOSH approved respirator specified for paint spray or organic vapors.. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. When using do not eat, drink or smoke.. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Odor epoxy Density (lbs/gal) Specific Gravity ph t available Evaporation Rate t available Vapor Pressure t available Page 4 / 8

6 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Density t available Wt. % Solids Vol. % Solids Wt. % Volatiles Vol. % Volatiles VOC Regulatory Limit (g/l) < 340 Boiling Point ( F) 212 Boiling Point ( C) 100 Freezing Point ( F) 32 Freezing Point ( C) 0 Flash Point ( F) t applicable Flash Point ( C) t applicable Flash Point Method t applicable Upper Explosion Limit t applicable Lower Explosion Limit t applicable 10. STABILITY AND REACTIVITY Chemical Stability Conditions To Avoid Incompatible Materials Hazardous Decomposition Products Possibility Of Hazardous Reactions Stable under recommended storage conditions. Prevent from freezing Incompatible with strong acids and bases and strong oxidizing agents. Thermal decomposition can lead to release of irritating gases and vapors. ne under normal conditions of use. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product information available Component Epoxy resin LD50 Oral: 11,400 mg/kg (Rat) Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product above reportable levels. Page 5 / 8

7 Ecotoxicity Effects Product Acute Toxicity to Fish information available Acute Toxicity to Aquatic Invertebrates information available Acute Toxicity to Aquatic Plants information available Component Acute Toxicity to Fish Epoxy resin LC50: 1.5 mg/l (Rainbow Trout - 96 hr.) Acute Toxicity to Aquatic Invertebrates information available Acute Toxicity to Aquatic Plants information available 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options. 14. TRANSPORT INFORMATION DOT t regulated ICAO / IATA IMDG / IMO t regulated t regulated 15. REGULATORY INFORMATION International Inventories Page 6 / 8

8 United States TSCA Canada DSL 15. REGULATORY INFORMATION Yes - All components are listed or exempt. Yes - All components are listed or exempt. Federal Regulations SARA 311/312 hazardous categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: This product may contain trace amounts of (other) SARA reportable chemicals. Contact the preparer for further information. Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: State Regulations California Proposition 65 This product may contain small amounts of materials known to the state of California to cause cancer or reproductive harm. State Right-to-Know Legend X - Listed This product may contain trace amounts of (other) HAPs chemicals. Contact the preparer for further information. 16. OTHER INFORMATION WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by contacting the National Lead Information Hotline at LEAD or log on to Page 7 / 8

9 Prepared By Revision Date: Revision Summary Product Stewardship Department Benjamin Moore & Co. 360 Route P.O. Box 4000 Flanders, NJ Dec-2011 t available Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. End of MSDS Page 8 / 8