PRODUCT SAFETY DATA SHEET

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1 PRODUCT SAFETY DATA SHEET Print date: Sep PRODUCT AND COMPANY IDENTIFICATION Item Number / Product name: SANI-FLUSH AUTOMATIC TOILET BOWL CLEANER, FRESH SCENT - Validation / Revision Date: September Formula Number: ( ) UPC Number and Size: Product Description: Manufacturer: Emergency telephone number: (341 ml.) Toilet bowl cleaner (liquid). Reckitt Benckiser, Inc Wickman Tech Avenue Road Unit # 2 Toronto, Mississauga, Ontario ON M8Z L4W 5M5 5S9CANADA (Canada) Transportation Emergencies: (U.S. & Canada) CHEMTREC Outside the U.S. and Canada (North America), call: COMPOSITION / INFORMATION ON INGREDIENTS Components: Wt % ACGIH: OSHA: 1-5 None None ALCOHOL ETHOXYLATE 7EO HAZARDS IDENTIFICATION Page 1 of 6

2 EMERGENCY OVERVIEW May cause transient eye discomfort upon direct contact with the eyes. KEEP OUT OF REACH OF CHILDREN 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Notes to physician: Aggravated Medical Conditions: Move to fresh air. In keeping with good hygienic practices, wash exposed areas with soap and water. In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation occurs or persists, get medical attention. Product not expected to cause adverse effects by this route of exposure. If swallowed, rinse mouth with water (only if person is conscious). Contact a physician or Poison Control Center for treatment advice. Show the container or product label to the medical personnel. Contains surfactants. Contains dye, fragrance, a preservative and a low concentration of organic salt (<0.2%). 5. FIRE-FIGHTING MEASURES Flash point: Flammability Limits in Air: Lower: Upper: Autoignition temperature: Suitable extinguishing media: Extinguishing media which must not be used for safety reasons: Specific hazards: Unusual hazards: Special protective equipment for firefighters: Specific methods: CLOSED CUP: Higher than 93.3º C (>200º F). [Tagliabue]. As suitable for surrounding fire. None known. None known As in any fire, wear self-contained breathing apparatus, pressuredemand, MSHA / NIOSH (approved or equivalent) and full protective gear. Standard procedure for chemical fires. NFPA: Health: 0 Flammability: 0 Instability: 0 HMIS: Health: 0 Flammability: 0 Reactivity: 0 Key: Personal Protection Index = A. (Also see Section 3) Page 2 of 6

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for cleaning up: No special personal protection equipment or ventilation required for consumer use. Read container instructions and handle accordingly. No special environmental precautions required. Local authorities should be advised if significant spillages cannot be contained. Small spills: Soak up with an inert absorbent material and dispose of in an appropriate waste container such as household trash. Rinse surface residue and flush to sink or sanitary sewer. Large spills should be diked, contained and collected for later disposal according to local, provincial, state or federal regulations. 7. HANDLING AND STORAGE Handling: Safe handling advice: No special technical protective measures required. Avoid direct contact with eyes. Storage: Store in original container in areas inaccessable to small children and pets. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: For occupational exposures, ensure adequate ventilation. Personal Protective Equipment Respiratory protection: Hand protection: Skin and body protection: Eye protection: Hygiene measures: None required under normal use conditions. None required under normal use conditions. Emergency responders should wear impermeable gloves. Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions. Not required under normal conditions of use. Avoid contact with eyes. Emergency responders should wear full eye and face protection. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid. Appearance: Liquid. Colour: Dark blue Odour: Fresh scent (Wintergreen) ph: 7.0 [Neutral.] Flash point: Greater than 93º C (>200º F) Specific gravity: 25º C (77º F). Vapour pressure: Not determined. Page 3 of 6

4 Solubility: Completely soluble. Explosion limits: - upper: No data available. - lower: No data available. 10. STABILITY AND REACTIVITY Stability: Polymerization: Hazardous decomposition products: Materials to avoid: Conditions to avoid: Acute toxicity Stable under recommended storage conditions. Hazardous polymerisation does not occur. None known. Do not mix with other household chemicals. Do not freeze. 11. TOXICOLOGICAL INFORMATION Component Information: Product Information LC50/inhalation/4h/rat = LD50/dermal/rabbit = LD50/oral/rat = Local effects Skin irritation: Eye irritation: Inhalation None expected during normal conditions of use. None expected during normal use. May cause eye irritation upon direct contact with eyes. None expected during normal conditions of use. Ingestion Sensitization Chronic toxicity: Health injuries are not known or expected under normal use. Not expected to be a skin sensitiser. Specific effects Carcinogenic effects: Mutagenic effects: Reproductive toxicity: Target organ effects: Not listed as carcinogenic by OSHA, NTP or IARC. Information is based on data on the components and the toxicology of similar products. Product Information 12. ECOLOGICAL INFORMATION Aquatic toxicity: This product is not classified as an environmental hazard. Page 4 of 6

5 Component Information: Other information: Ozone depletion potential; ODP; (R-11 = 1) = Global warming potential (GWP) = Additional ecological information: 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Contaminated packaging: Waste Disposal: Dispose of in accordance with local regulations. Empty container can be disposed of as household trash or rinsed and recycled where appropriate. Large quantities of waste liquid: Contain and collect for evaluation and disposal according to local, state, provincial and federal regulations. 14. TRANSPORT INFORMATION UN / Id No: DOT: U.S. DOT - Hazard Class: Subsidiary risk: DOT RQ (lbs): ERG No: TDG (Canada): Status: WHMIS hazard class: IMDG / IMO Class: Subsidiary Risk: Packing group: IMDG page: Marine pollutant: EMS: MFAG: ADR / RID Class: Subsidiary risk: ADR/RID-labels: Hazard Identification Number: CEFIC Tremcard No: Not applicable Not a DOT regulated material. (United States) Not regulated under TDG Not a WHMIS controlled product. Not regulated under IMDG See Guide. Not applicable Page 5 of 6

6 ICAO / IATA: Class: Subsidiary Risk: Maximum quantity Not regulated under ICAO / IATA Not applicable 15. REGULATORY INFORMATION Components: PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No ALCOHOL ETHOXYLATE 7EO Present Present U.S. Regulations: Components: ALCOHOL ETHOXYLATE 7EO California Proposition 65 - None. Canada WHMIS hazard class: Not a WHMIS controlled product. 16. OTHER INFORMATION National Fire Protection Association (U.S.A.): HMIS (U.S.A.): Health Hazard 0 Fire Hazard Reactivity 0 0 Personal Protection A Reason for revision: Additional advice: Prepared by: Disclaimer: Revision of data and / or an update of the PSDS. This product should only be used as directed on the label and for the purpose intended. Reckitt Regulatory Benckiser Department (U.S.) Inc. Product Safety Department 1 Philips Parkway Montvale, New Jersey USA. Phone: FAX: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 6 of 6

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