SAFETY DATA SHEET SILCOSET PRIMER

Transcription

1 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME SUPPLIER EMERGENCY TELEPHONE ACC SILICONES LIMITED Amber House, Showground Rd Bridgwater, Somerset TA6 6AJ TEL: +44 (0) FAX: +44 (0) sdsadmin@acc-silicones.com DEUTSCHLAND (24hrs) ITALIA (24hrs) UK +44 (0) (24hrs) 2 HAZARDS IDENTIFICATION Highly flammable. Harmful by inhalation and in contact with skin. Irritating to eyes and skin. CLASSIFICATION Xn;R20/21. Xi;R6/8. F;R11. COMPOSITION/INFORMATION ON INGREDIENTS EC No. CAS-No. Content Classification % F;R11 Xi;R6 R66 R67 BUTANOL-norm % R10 Xn;R22 Xi;R7/8,R41 R67 ETHYLBENZENE % F;R11 Xn;R20 PROPAN-2-OL % F;R11 Xi;R6 R % R10 Xn;R20 Xi;R6/ % R10 Xn;R20/21 Xi;R8 The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and take along these instructions. INGESTION DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Promptly flush contaminated skin with soap or mild detergent and water. Promptly remove clothing if penetrated and flush the skin with water. Get medical attention if irritation persists after washing. EYE CONTACT Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists continue rinsing and transport to hospital taking these instructions. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. SPECIAL FIRE FIGHTING PROCEDURES Avoid breathing fire vapours. Use water to keep fire exposed containers cool and disperse vapours. Keep run-off water out of sewers and water sources. Dike for water control. UNUSUAL FIRE & EXPLOSION HAZARDS Solvent vapours may form explosive mixtures with air. 1 / 5

2 SPECIFIC HAZARDS Fire creates: Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2). 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Avoid release to the environment. Contain spillages with sand, earth or any suitable adsorbent material. SPILL CLEAN UP METHODS Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see section 1. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. During application and drying, solvent vapours will be emitted. STORAGE PRECAUTIONS Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and well-ventilated place. STORAGE CLASS Flammable liquid storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Std TWA - 8 hrs STEL - 15 min Notes WEL 500 ppm 1210 mg/m 1500 ppm 620 mg/m BUTANOL-norm ETHYLBENZENE PROPAN-2-OL WEL 50 ppm(sk) 154 WEL ppm(sk) ppm(sk) 552 WEL 400 ppm 999 mg/m 500 ppm 1250 mg/m WEL 50 ppm(sk) ppm(sk) 441 WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit is not exceeded. RESPIRATORY EQUIPMENT If ventilation is insufficient, suitable respiratory protection must be provided. HAND PROTECTION Protective gloves must be used if there is a risk of direct contact or splash. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable. EYE PROTECTION Wear approved safety goggles. HYGIENE MEASURES No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR Liquid Pink of solvents 2 / 5

3 SOLUBILITY Slightly soluble in water. Miscible with Organic solvents. BULK DENSITY 0.86 FLASH POINT ( C) -12 CC (Closed Cup) AUTO IGNITION TEMPERATURE ( C) >58 10 STABILITY AND REACTIVITY STABILITY Avoid: Heat, sparks, flames. Stable under normal temperature conditions and recommended use. MATERIALS TO AVOID Strong oxidising substances. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Silicon. 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION No data recorded. GENERAL INFORMATION This product has low toxicity. Only large volumes may have adverse impact on human health. INHALATION Vapour may irritate respiratory system or lungs. INGESTION Liquid irritates mucous membranes and may cause abdominal pain if swallowed. SKIN CONTACT Irritating to skin. EYE CONTACT Irritation, burning, lachrymation, blurred vision after liquid splash. Toxic Dose 1 - LD 50 Toxic Conc. - LC 50 Toxic Dose 1 - LD 50 >2000 mg/kg (oral rat) 10 mg/l/4h (inh-rat) 5800 mg/kg (oral rat) 12 ECOLOGICAL INFORMATION ECOTOXICITY No data on possible environmental effects have been found. LC 50, 96 Hrs, FISH mg/l EC 50, 48 Hrs, DAPHNIA, mg/l > DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. 14 TRANSPORT INFORMATION UK ROAD CLASS PROPER SHIPPING NAME FLAMMABLE LIQUID, N.O.S. (, PROPAN-2-OL) UN NO. ROAD 199 UK ROAD PACK GR. ADR CLASS NO. ADR CLASS Class : Flammable liquids. / 5

4 ADR PACK GROUP HAZARD No. (ADR) ADR LABEL NO. HAZCHEM CODE YE CEFIC TEC(R) NO. 0GF1-I+, 0GF1-sp RID CLASS NO. RID PACK GROUP UN NO. SEA 199 IMDG CLASS IMDG PAGE NO. IMDG PACK GR. EMS F-E, S-E MFAG See Guide MARINE POLLUTANT No. UN NO. AIR 199 AIR CLASS AIR PACK GR. 15 REGULATORY INFORMATION LABELLING Harmful Highly Flammable CONTAINS RISK PHRASES R11 Highly flammable. R20/21 Harmful by inhalation and in contact with skin. R6/8 Irritating to eyes and skin. SAFETY PHRASES S16 S26 S51 S/7/9 Keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Use only in well-ventilated areas. Keep container tightly closed, in a cool, well ventilated place. S24/25 Avoid contact with skin and eyes. S7/9 Wear suitable gloves and eye/face protection. S62 S2A If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Do not breathe gas/fumes/vapour/spray. EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EEC. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. NATIONAL REGULATIONS The Chemicals (Hazard Information and Packaging for Supply) Regulations No Control of Substances Hazardous to Health Regulations 2002 (as amended) The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007 (CDG 2007) 16 OTHER INFORMATION REVISION COMMENTS NOTE: Lines within the margin indicate significant changes from the previous revision. REVISION DATE 21/08/2007 REV. NO./REPL. SDS GENERATED RISK PHRASES IN FULL R10 Flammable., R20/21 Harmful by inhalation and in contact with skin., R20 Harmful by inhalation., R22 Harmful if swallowed., R11 Highly flammable., R6/7 Irritating to eyes and respiratory system., R6 Irritating to eyes., R7/8 Irritating to respiratory system and skin., R8 Irritating to skin., R66 Repeated exposure may cause skin dryness or cracking., R41 Risk of serious damage to eyes., R67 Vapours may cause drowsiness and dizziness. 4 / 5

5 DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 5 / 5