SECTION 1: Identification. SECTION 2: Hazards Identification. SECTION 3: Composition/Information On Ingredients Product Identifier

Transcription

1 SECTION 1: Identification 1.1. Product Identifier Date of issue: 05/17/2016 Version: 1.0 Product Form : Mixture Product Name : Product Code : Intended Use of the Product Use of the substance/mixture 1.3. Name, Address, and Telephone of the Responsible Party Company STERIS Corporation P. O. Box 147, St. Louis, MO 63166, US Telephone Number for Information: (Customer Service - Scientific Products) US Emergency Telephone No (STERIS); (CHEMTREC) web: asksteris_msds@steris.com SECTION 2: Hazards Identification 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 3 H226 Eye Irrit. 2A H319 STOT SE 3 H336 Full text of H-phrases: see section 16 : Hospital/Medical/Surgical Sanitizer & Disinfectant Cleaner, Bactericidal, Fungicidal, Virucidal, Tuberculocidal For professional use only Label Elements - This label is requlated by the EPA under FIFRA. Refer to Section 15. GHS-US Labeling Hazard Pictograms (GHS-US) : Signal Word (GHS-US) Hazard Statements (GHS-US) Precautionary Statements (GHS-US) 2.3. Other Hazards GHS02 GHS07 : Warning : H226 - Flammable liquid and vapor. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. : P210 - Keep away from heat, open flames, hot surfaces, sparks. - No smoking. P261 - Avoid breathing vapours, spray, mist P264 - Wash hands, forearms, and exposed areas thoroughly after handling P280 - Wear protective clothing, protective gloves, eye protection. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of contents/container in accordance with applicable local, national and international regulation. Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. If involved in a fire and thermal decomposition occurs, corrosive, toxic, and acrid vapors may be released Unknown Acute Toxicity (GHS-US) 1% of the mixture consists of ingredients (s) of unknown acute toxicity. SECTION 3: Composition/Information On Ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Isopropyl alcohol (CAS No) Flam.Liq 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 05/17/2016 EN (English US) SDS Ref.: 1629US 1/6

2 2-Butoxyethanol (CAS No) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal),H312 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Full text of H-phrases: see section 16 SECTION 4: First Aid Measures 4.1. Description of First Aid Measures First-aid Measures After Inhalation : If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a Poison Center/doctor/physician if you feel unwell. First-aid Measures After Eye Contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do so, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid Measures After Ingestion : If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by moutn to an unconscious person. Get medical advice/attention if you feel unwell. First-aid Measures After Skin Contact : In case of contact, immediately flush with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists Most important symptoms and effects, both acute and delayed Symptoms/Injuries After Inhalation : Vapors may cause drowsiness and dizziness. May cause respiratory tract irritation. Symptoms/Injuries After Eye Contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swell of the conjunctiva. Symptoms/Injuries After Ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Symptoms/Injuries After Skin Contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin Indication of Any Immediate Medical Attention and Special Treatment Needed Note to Physician: Treat symptomatically. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing Media Suitable Extinguishing Media : Water fog, carbon dioxide, dry chemical or alcohol foam. Unsuitable Extinguishing Media : None known Special Hazards Arising From the Substance or Mixture Products of combustion include but are not limited to: oxides of carbon Advice for Firefighters Firefighting Instructions : Keep upwind of fire. Protection During Firefighting : Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Hazardous Combustion Products : Products of combustion include but are not limited to: oxides of carbon SECTION 6: Accidental Release Measures 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures : Handle in accordance with good industrial hygiene and safety practice For Non-emergency Personnel Protective Equipment : Use personal protection recommended in Section 8. Emergency Procedures : Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition For Emergency Responders Protective Equipment : Use personal protection recommended in Section 8. Emergency Procedures : Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition Environmental Precautions See section 12 for ecological information Methods and Material for Containment and Cleaning Up For Containment : Contain and /or absorb spill with inert material (e.g sand, vermiculite), then place in a suitable container. Methods for Cleaning Up : Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Scoop up material and place in a disposal container. Provide ventilation Reference to Other Sections See Section 8: Exposure Controls and Personal Protection. 05/17/2016 EN (English US) SDS Ref.: 1629US 2/6

3 SECTION 7: Handling And Storage 7.1. Precautions for Safe Handling Pesticide Storage : Store in original container in a cool, well ventilated area inaccessible to children and pets. Additional Hazards When Processed : Keep away from sources of ignition. No smoking. Take precautionary measures against static discharge. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using, do not eat, drink or smoke. Use only non-sparking tools. Hygiene Measures : Launder contaminated clothing before use. Wash hands before eating, drinking or smoking Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions : Proper ground procedures to avoid static electricity should be followed. Keep locked up and out of reach of chlidren. Keep container tightly closed and in a well-ventilated place. Keep cool. Incompatible Products : Oxidizers Specific End Use(s) Hospital/Medical/Surgical Sanitizer & Disinfectant Cleaner, Bactericidal, Fungicidal, Virucidal, Tuberculocidal For professional use only. SECTION 8: Exposure Controls/Personal Protection 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL). Isopropyl alcohol ( ) USA ACGIH ACGIH TLV 200 ppm USA OSHA OSHA PEL 980 mg/m³ 2-Butoxyethanol ( ) USA ACGIH ACGIH TLV 20 ppm USA OSHA OSHA PEL 240 mg/m³ 8.2. Exposure Controls Appropriate Engineering Controls Personal Protective Equipment : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc. below recommended exposure limits. : Avoid all unnecessary exposure. Face shield. Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection. Hand Protection Eye Protection Skin and Body Protection Respiratory Protection Consumer Exposure Controls SECTION 9: Physical And Chemical Properties 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Colorless Odor : Alcohol-like Odor Threshold ph : 7.6 Evaporation rate Melting Point Freezing Point Boiling Point Flash Point : 30 C (80 F) TCC Auto-ignition Temperature Decomposition Temperature Flammability (solid, gas) : Flammable : Impermeable protective gloves. : A full face shield is recommended. Chemical safety goggles. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. 05/17/2016 EN (English US) SDS Ref.: 1629US 3/6

4 Vapor Pressure Relative Vapor Density at 20 C Specific Gravity : 0.97g/ml Solubility : Not determined. Partition coefficient: n-octanol/water Viscosity 9.2. Other Information No additional information available SECTION 10: Stability And Reactivity 10.1 Reactivity: Not reactive under normal conditions 10.2 Chemical Stability: Stable under recommended storage conditions. May form flammable/explosive vapor-air mixture Possibility of Hazardous Reactions: None under normal use Conditions to Avoid: Heat. Incompatible materials. Sources of ignition Incompatible Materials: Oxidizers Hazardous Decomposition Products: May include and are not limited to: oxides of carbon. SECTION 11: Toxicological Information Information On Toxicological Effects Likely Routes of Exposure: Inhalation, skin contact, eye contact, ingestion. ATE (oral) >2000 mg/kg, rat ATE (dermal) >2000 mg/kg, rabbit ATE (inhalation) >20 mg/l/4 h Isopropyl alcohol ( ) LD50 Oral LD50 Dermal LC50 Inhalation 2-Butoxyethanol ( ) LD50 Oral LC50 Inhalation 4396 mg/kg (rat) mg/kg (rat) 72.6 mg/l/4h (rat) 470 mg/kg (rat) 450 ppm/4h (rat) Skin Corrosion/Irritation : Not classified Serious Eye Damage/Irritation : Causes serious eye irritation. Respiratory or Skin Sensitization : Not classified Germ Cell Mutagenicity : Not classified Teratogenicity : Not classified Carcinogenicity : Not classified Symptoms/Injuries After Inhalation : Vapors may cause drowsiness and dizziness. May cause respiratory tract irritation. Symptoms/Injuries After Eye Contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swell of the conjunctiva. Symptoms/Injuries After Ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Symptoms/Injuries After Skin Contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. SECTION 12: Ecological Information Toxicity Ecotoxicity Persistence and Degradability Not established Bioaccumulative Potential Not established Mobility in Soil No additional information available : Not established 05/17/2016 EN (English US) SDS Ref.: 1629US 4/6

5 12.5. Other Adverse Effects No additional information available SECTION 13: Disposal Considerations Waste treatment methods Pesticide Disposal : Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility. Container Disposal : Refillable container. Refill this container with only the product originally supplied in this container. Do not reuse this container for any other purpose. When empty, fill the container about 20 percent full of water. Agitate vigorously and dispose of contents on site or at an approved waste disposal facility. Offer container for recycling, if available; otherwise dispose of container in trash. SECTION 14: Transport Information 14.1 In Accordance with DOT UN 1987, Alcohols, n.o.s. (Isopropanol), 3, PG III, LTD QTY 14.2 In Accordance with IMDG UN 1987, Alcohols, n.o.s. (Isopropanol), 3, PG III, LTD QTY 14.3 In Accordance with IATA Restricted Not packaged or labelled for air shipment. SECTION 15: Regulatory Information 15.1 US Federal Regulations EPA FIFRA Pesticide Product Notice EPA FIFRA Signal Word EPA FIFRA Hazard Statements EPA FIFRA Precautionary Statements SARA Section 311/312 Hazard Classes This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. Caution Keep out of reach of children. May be harmful if inhaled or absorbed through skin. May cause moderate eye irritation. Avoid breathing vapors and contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse. HAZARDS TO HUMANS AND DOMESTIC ANIMALS. Immediate (acute) health hazard All ingredients in this product are listed or are excluded from listing on the US Toxic Substances Act (TSCA) Chemical Substance Inventory US State Regulations No information available Canadian Regulations Not Applicable SECTION 16: Other Information, Including Date Of Preparation Or Last Revision Revision date : 05/17/2016 Other Information GHS Full Text Phrases: Flam. Liq. 2 Flammable liquids Category 2 Flam. Liq. 3 Flammable liquids Category 3 : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Eye Irrit. 2 Serious eye damage/eye irritation Category 2 Acute Tox 4 (Oral) Acute toxicity (oral) Category 4 Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4 Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H226 Flammable liquid and vapor H302 Harmful if swallowed 05/17/2016 EN (English US) SDS Ref.: 1629US 5/6

6 H312 H315 H319 H332 H336 NFPA Health Hazard NFPA Fire Hazard NFPA Reactivity Harmful if in contact with skin Causes skin irritation Causes serious eye irritation Harmful if inhaled. May cause drowsiness or dizziness : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given : 2 - Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water Party Responsible for the Preparation of This Document STERIS Corporation This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. STERIS NA GHS SDS 05/17/2016 EN (English US) SDS Ref.: 1629US 6/6