SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 GLYCINE SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product Identification Product Name : GLYCINE 1.2 Relevant Identified Uses of the substance and uses advised against Identified Uses : Glycine has a wide variety of application from Raw Material for production, dietary supplements, food & feed additive, Platings, fertilizer plants, laboratory chemicals, etc 1.3 Details of Supplier & provider of Safety Data Sheet Company : Charkit Chemical Company LLC. Site Address : 32 Haviland Street South Norwalk, CT USA 1.4 Emergency telephone number Emergency Phone : Chemtrec: , Intl: SECTION 2: Hazards Identification 2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is not classified as dangerous according to Directive 67/548/EEC. 2.2 Label elements The product does not need to be labelled in accordance with EC directives or respective national laws. 2.3 Other Hazards As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing. SECTION 3: Components / Information on ingredients 3.1 Substances Synonyms : Glycocol, Aminoacetic acid, Aminoethanoic Acid Chemical Formula : CH 2NH 2COOH CAS No : : Molecular Weight : g/mol EC No. : The product contains > 98.5% Glycine. No components need to be disclosed according to the applicable regulations. 1

2 SECTION 4: First Aid Measures 4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. Get medical assistance in case of difficulty in breathing. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. Get Medical assistance if irritation develops In case of eye contact Flush eyes with water as a precaution. Get Medical assistance if irritation develops If swallowed Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section Indication of any immediate medical attention and special treatment needed SECTION 5: Fire Fighting Measures 5.1 Extinguishing Media Glycine by itself is not considered fire or explosion hazard. Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. In general extinguishing media suitable as per surrounding fire may be used. 5.2 Special hazards arising from the substance or mixture Carbon Oxides, Nitrogen Oxides (NO X) 5.3 Advice for Firefighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 5.3 Further Information SECTION 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section Enviromental Preacuations Do not let product enter drains. 2

3 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. SECTION 7: Handling and Storage 7.1 Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) Glycine is used in multiple application. The user must check the suitability and risks associated with his application. SECTION 8 : Exposure controls/personal protection 8.1 Control Parameters Components with workplace Control Parameters 8.2 Exposure Controls Appropriate industrial hygiene practices Personal Protective Equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin Protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. 3

4 Full Contact Material : Nitrile Rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: Dermatril (KCL 740 / Aldrich Z677272, Size M) Splash Contact Material : Nitrile Rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: Dermatril (KCL 740 / Aldrich Z677272, Size M) Data source: KCL GmbH, D Eichenzell, phone +49 (0) , sales@kcl.de, test method: EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of Environmental Exposure Do not let the product enter drains. SECTION 9: Physical & Chemical Properties 9.1 Information on basic Physical & Chemical Properties a) Apperance : Form Powder or Crystalline Colour White b) Odour : No typical or noticeable odour c) Odour Threshold : No typical or noticeable odour d) ph : 5.9 to 6.3 for 5% Solution in distilled water e) Melting Point / : Melting at about 233 to 240 O C with decomposition Freezing Point f) Initial boiling point : Not Applicable. and boiling range g) Flash Point : Not considered flammable h) Evaporation Rate : Not Applicable i) Flammability (Solid, Gas) : Not considered flammable 4

5 j) Upper / lower : Not considered flammable or explosive. flammability or explosive limits k) Vapour Pressure : No data available l) Vapour Density : No data available m) Relative Density : No data available n) Water Solubility : The product is freely soluble in water (about 25g / 100 ml at 25 o C). The solubility increases with temperature. o) Partition : No data available Coefficient: n- octanol / water p) Auto Ignition : Not Considered Flammable Temperature q) Decomposition : No data available Temperature r) Viscosity : No data available s) Explosive : Product is not considered an explosion risk. Properties t) Oxidising : No data available Properties 9.2 Other Safety Information Bulk Density : Typically between 0.7 to 0.9 gm / cc. Bulk density may vary depending upon particle size and crystalline nature. SECTION 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical Stability The product is stable under recommended storage conditions. Store in cool place. Keep container tightly closed in a dry place away from heat and light Possibility of Hazardous Reactions 10.4 Conditions to avoid 10.5 Incompatible Materials Strong Oxidising Agents 10.6 Hazardous Decomposition Products Other decomposition products No data Available. In the event of fire : See section 5 SECTION 11: Toxicological Information 11.1 Information on Toxicological Effects Acute Toxicity LD50 Oral Rat 7930 mg / kg (Investigated as Mutagen) Skin Corrosion / Irritation 5

6 Serious Eye Damage / Eye Irritation Respiratory or Skin Sensitisation Germ Cell Mutagenicity Carcinogenicity IARC : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive Toxicity Specific Target organ toxicity single exposure Specific Target organ toxicity Repeated exposure Aspiration Hazard Additional Information RTECS : MB To the best of our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated. SECTION 12 : Ecological Information 12.1 Toxicity 12.2 Persistence and Degradability 12.3 Bioaccumlative Potential 12.4 Mobility in soil 12.5 Results of PBT & vpvb Assessment PBT / vpvb assessment not available as chemical safety assessment is not required / not conducted 12.6 Other Adverse Effects 6

7 SECTION 13 : Disposal Considerations 13.1 Waste Treatment Methods Product Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Contaminated Packaging Dispose of container and unused contents in accordance with federal, state and local requirements. SECTION 14 : Transport Information 14.1 UN Number ADR / RID : - Not Regulated IMDG : - Not Regulated IATA : - Not Regulated 14.2 UN Proper Shipping Name ADR / RID : - Not Classified as dangerous Goods IMDG : - Not Classified as dangerous Goods IATA : - Not Classified as dangerous Goods 14.3 Transport Hazard Class(es) ADR / RID : - Not Classified as dangerous Goods IMDG : - Not Classified as dangerous Goods IATA : - Not Classified as dangerous Goods 14.4 Packaging Group ADR / RID : - Not Classified as dangerous Goods IMDG : - Not Classified as dangerous Goods IATA : - Not Classified as dangerous Goods 14.5 Enviromental Hazards ADR / RID : - No IMDG Marine Pollutant IATA : - No : - No 14.6 Special Precautions for user SECTION 15 : Regulatory Information This safety datasheet complies with the requirement of Regulation (EC) No : 1907 /

8 15.1 Safety, health and Environment regulations / legislation specific for the substance or mixture Chemical Safety Assessment 16. OTHER INFORMATION Disclaimer: ************************************************************************ We provide the information contained herein in good faith and on sources or data assumed to be reliable, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. W E MAKE NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, CHARKIT CHEMICAL CORPORATION WILL NOT BE RESPONSIBLE OR LIABLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Revision Date: May 29,