Cen-Pe-Co Quick Kleen Page 1 of 5 01/16/14 MATERIAL SAFETY DATA SHEET

Transcription

1 Cen-Pe-Co Quick Kleen Page 1 of 5 Section 1: PRODUCT AND COMPANY IDENTIFICATION Central Petroleum Company Phone Number: East Lincoln Street Monday-Friday, 8:00 a.m. 3:45 p.m. CST Walcott, IA Fax Number: Emergency: CHEMTREC Product Name: Cen-Pe-Co Quick Kleen Common Name: Diesel fuel additive Issued Date: 01/16/13 Supersedes Date: 05/03/13 Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Appearance/Odor: Amber liquid with strong pungent odor. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Potential Health Effects: See Section 11 for more information Likely Routes of Exposure: Eye and skin contact. Eye Contact: May cause irritation including discomfort, tearing, or blurred vision. Exposure to high concentrations of vapors may be irritating. Skin Contact: May cause irritation. Prolonged or repeated contact may lead to skin defatting, which can result in dryness, dermatitis, and cracking. Ingestion: Material poses an aspiration hazard. Ingestion may cause nausea or stomach discomfort. Inhalation: Inhalation may cause respiratory irritation, nausea, or discomfort. Exposure to decomposition products may cause a health hazard. Medical Conditions Aggravated By Exposure: Preexisting skin or respiratory conditions may be aggravated by overexposure. Target Organ Effects: Components of this material may cause damage to the blood, kidneys, liver, and central nervous system. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Component CAS# % by Wt. Distillate (Petroleum) Hydrotreated Light Naphthenic 2-Ethylhexyl Nitrate Petroleum Naphtha Ethylhexanol Naphthalene <1 1, 3, 5-Trimethylbenzene <1

2 Cen-Pe-Co Quick Kleen Page 2 of 5 Section 4: FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 20 minutes. Seek immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with plenty of water for at least 20 minutes. Seek immediate medical attention. Wash clothing before reuse. Ingestion: Do not induce vomiting. Wash out mouth with water. If vomiting occurs naturally, have victim lean forward to reduce the risk of aspiration. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Inhalation: Move to fresh air. Seek immediate medical attention. If not breathing, if breathing is irregular, or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Section 5: FIRE FIGHTING MEASURES Suitable Extinguishing Media: Water fog, foam, dry chemical, and carbon dioxide. Do not use water jet. Cool containers with water spray. Do not touch or walk through spilled material. Protection of Firefighters: Firefighters should wear self-contained breathing apparatus and full fire-fighting turnout gear. Fire/Explosion Hazards: Some components make produce toxic fumes, gases, and vapors on burning. Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Containers may rupture upon heating. Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with spilled material. Remove all potential sources of ignition. Take precautionary measures against static discharge. Ventilate spill area. Use personal protection recommended in Section 8. Environmental Precautions: Prevent material from entering sewers and waterways. Advise the Environmental Protection Agency (EPA) and appropriate state agencies, if required. Methods for Containment and Clean-Up: Use nonsparking tools and explosion-proof means to transfer to labeled, sealable containers for product recovery or safe disposal. For large spills, pump liquid into salvage tank. Soak up residues with an inert absorbent material such as sand, clay, earth, or floor absorbent and dispose of safely. Remove contaminated soil and dispose of safely. Do not wash away residues with water. Section 7: HANDLING AND STORAGE Handling:

3 Cen-Pe-Co Quick Kleen Page 3 of 5 Keep away from heat, sparks, and open flame. Extinguish all possible ignition sources prior to use and until vapors are gone. Use approved bonding and grounding procedures. Use explosion-proof electrical equipment. Keep containers tightly sealed when not in use. Transfer only to approved containers with complete and appropriate labeling. Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Do not take internally. Wash hands and face before eating, drinking and smoking. Empty containers may contain residue. Do not cut, weld, braze, solder, drill, grind, or expose containers to heat, flame, spark, or other ignition sources. Storage: Keep container in a cool, well-ventilated area. Avoid possible sources of ignition. Keep containers tightly closed. Keep away from alkalis and acids. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Distillate (Petroleum) Hydrotreated Light Naphthenic ACGIH TLV: 5 Mg/M 3 8 hour /hour (oil mist limit) Naphthalene: OSHA TWA: 10 ppm ACGIH TWA: 10 ppm ACGIH STEL: 15 ppm Engineering Controls: Sufficient ventilation, in volume and pattern, should be provided to keep the vapor concentration below applicable OSHA requirements. Eye/Face Protection: Wear chemical splash goggles or full-face shield. Skin Protection: When contact is likely, wear chemical resistant gloves. Additional body garments should be used based upon the task being performed. Respiratory Protection: Use NIOSH approved respiratory equipment if there is the potential to exceed the exposure limits. General Hygiene Considerations: Wash hands before eating, drinking, smoking, or using washroom. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Color: Amber Odor: Strong pungent. Physical State: Liquid Flash Point: 217ºF (102.8ºC) (Calculated) Specific Gravity: 0.91

4 Cen-Pe-Co Quick Kleen Page 4 of 5 Section 10: STABILITY AND REACTIVITY Stability: Stable at normal temperatures and pressures. Conditions to Avoid: Avoid heat, sparks, flame, and other sources of ignition. Incompatible Materials: Avoid oxidizing agents, reducing materials, acids and alkalis, and combustible materials. Hazardous Decomposition Products: Combustion can form carbon dioxide, carbon monoxide, sulfur oxides, and nitrogen oxides. Section 11: TOXICOLOGICAL INFORMATION Specific toxicity tests have not been conducted on this mixture. In accordance with OSHA s Hazard Communication Standard , this mixture is assumed to have the same health hazards as its significant components. Acute effects: Eye Contact: Skin Contact: Ingestion: Inhalation: May cause irritation including discomfort, tearing, or blurred vision. Exposure to high concentrations of vapors may be irritating. May cause irritation. Prolonged or repeated contact may lead to skin defatting, which can result in dryness, dermatitis, and cracking. Ingestion may cause nausea or stomach discomfort. Material poses an aspiration hazard. Aspiration can cause chemical pneumonitis, which can be fatal. Inhalation may cause respiratory irritation, nausea, or discomfort. Exposure to decomposition products may cause a health hazard. Chronic effects: Repeated overexposure to petroleum naphtha can cause nervous system damage. Repeated overexposure to naphthalene may cause destruction of red blood cells with anemia, fever, jaundice and kidney and liver damage. Repeated ingestion of 2- ethylhexanol may cause injury to the liver and kidneys. Carcinogens or Potential Carcinogens Naphthalene IARC Group2B: Possibly carcinogenic to humans. Target Organ Effects: Components of this material may cause damage to the blood, kidneys, liver, and central nervous system. Animal Data: 2-Ethylhexyl Nitrate Dermal LD50 >5,000 mg/kg Rabbit Oral LD50 >10,000 mg/kg Rat

5 Cen-Pe-Co Quick Kleen Page 5 of 5 Section 12: ECOLOGICAL INFORMATION A component of this product shows a high bioaccumulation potential. Water polluting material. May be harmful to the environment if released in large quantities. Section 13: DISPOSAL CONSIDERATIONS Dispose in accordance with local, state, and federal regulations. Section 14: REGULATORY INFORMATION SARA 313 Information Component CAS# % by Wt. Naphthalene <1 Section 15: OTHER INFORMATION NFPA 704: National Fire Protection Association Health = 2 Flammability = 1 Reactivity = 1 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Disclaimer: This information has been compiled from sources considered to be dependable and is accurate to the best of Central Petroleum Company s knowledge; however, the Central Petroleum Company makes no warranty whatsoever, expressed or implied, of merchantability or fitness for particular purpose regarding the accuracy of such data or the results to be obtained from the use thereof. The Central Petroleum Company assumes no responsibility for injury to recipient or third persons or for any damage to any property and recipient assumes all such risks.