Material Safety Data Sheet
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1 G-Biosciences/Genotech: St. Louis, MO, USA; Product: TBS, Tris buffered saline [20X] Dry Buffer Pack Catalog #: RC-148 [LU /JK-IA] Components Catalog # Quantity TBS RC-148 for 20L Section 1: Chemical Identification Name: TBS Material Safety Data Sheet Catalog #: a component of product Cat # RC-148 indicated above Section 2: Composition/Information on Ingredients TBS contains the following: Chemical name: CAS#: Tris Potassium chloride Sodium chloride Tris hcl Section 3: Hazards Identification Label precautionary statements. Irritant. Irritating to eyes, respiratory system and skin. Wear suitable protective clothing. Section 4: First-Aid Measures After eye contact: Immediately flush eyes with copious amounts of water for at least 15 minutes. Call a physician. After skin contact: Immediately wash skin with soap and copious amounts of water. After Inhalation: Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, call a physician. After swallowing: Wash out mouth with water provided person is conscious. Call a physician. Section 5: Fire Fighting Measures Extinguishing Agents: Water spray, carbon dioxide, dry chemical powder or appropriate foam. Special fire fighting procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire and explosions hazards: Emits toxic fumes under fire conditions. Section 6: Accidental Release Measures Human Safety Precautions: Exercise appropriate precautions to minimize direct contact with skin or eyes and prevent inhalation of dust. Cleaning/Collecting Measures: Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
2 Section 7: Handling and Storage Refer to section 8. Section 8: Exposure Controls/Personal Protection Personal protective equipment: Chemical safety goggles, compatible chemical-respirator, NIOSH/MSHA-approved respirator, and safety shower and eye bath. General Protective and Hygiene Measures: Mechanical exhaust required. Do not breathe dust. Avoid inhalation. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Keep tightly closed. Store in cool dry place. Section 9: Physical and Chemical Properties Form: Solid Color: none. Odor: None Section 10: Stability and Reactivity Thermal Decomposition/Conditions to be avoided: Avoid strong oxidizing agents. Dangerous Reactions: None known. Dangerous Products of Decomposition: Carbon monoxide, carbon dioxide, nitrogen oxides. Section 11: Toxicological Information On the skin: May be harmful if absorbed through the skin. May cause skin irritation. On the eye: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. Section 12: Ecological Information: Data not yet available Section 13: Disposal Considerations Recommendation: Contact a licensed professional waste disposal service to dispose of this material. Observe all federal, state and local environmental regulations. Section 14: Transport Information: Not dangerous goods. Safe for all transport.
3 Section 15: Regulatory information Irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Section 16: Other Information The above information is believed to be correct but does not purport to be all-inclusive and shall be used only as a guide. Geno Technology shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. G-Biosciences/Genotech St. Louis, MO, USA Web: technical@gbiosciences.com
4 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 5.0 Revision Date 03/13/2011 Print Date 11/27/ PRODUCT AND COMPANY IDENTIFICATION Product name : 1-O-Octyl-β-D-glucopyranoside Product Number : O3757 Brand : Sigma Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO USA Telephone : Fax : Emergency Phone # (For : (314) both supplier and manufacturer) Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards No known OSHA hazards Not a dangerous substance or mixture according to the Globaly Harmonised System (GHS). HMIS Classification Health hazard: 0 Flammability: 0 Physical hazards: 0 NFPA Rating Health hazard: 0 Fire: 0 Reactivity Hazard: 0 Potential Health Effects Inhalation Skin Eyes Ingestion 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : n-octyl glucoside OGP Formula : C 14 H 28 O 6 Molecular Weight : g/mol May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. May be harmful if swallowed. CAS-No. EC-No. Index-No. Concentration 1-O-Octyl-β-D-glucopyranoside Sigma - O3757 Page 1 of 6
5 4. FIRST AID MEASURES If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 5. FIRE-FIGHTING MEASURES Conditions of flammability Not flammable or combustible. Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Carbon oxides 6. ACCIDENTAL RELEASE MEASURES Personal precautions Avoid dust formation. Avoid breathing vapors, mist or gas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: -20 C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Sigma - O3757 Page 2 of 6
6 Eye protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures General industrial hygiene practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Safety data ph Melting point/freezing point Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water Relative vapour density Odour Odour Threshold Evaporation rate powder white 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Conditions to avoid Materials to avoid Strong oxidizing agents Sigma - O3757 Page 3 of 6
7 Hazardous decomposition products Other decomposition products - Hazardous decomposition products formed under fire conditions. - Carbon oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: ACGIH: NTP: OSHA: Reproductive toxicity No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation Ingestion Skin May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. Sigma - O3757 Page 4 of 6
8 Eyes May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: Not available 12. ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION OSHA Hazards No known OSHA hazards SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards No SARA Hazards Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Sigma - O3757 Page 5 of 6
9 Pennsylvania Right To Know Components 1-O-Octyl-β-D-glucopyranoside New Jersey Right To Know Components 1-O-Octyl-β-D-glucopyranoside CAS-No CAS-No Revision Date Revision Date California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. 16. OTHER INFORMATION Further information Copyright 2011 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Co., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Sigma - O3757 Page 6 of 6
10 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.2 Revision Date 05/08/2012 Print Date 11/20/ PRODUCT AND COMPANY IDENTIFICATION Product name : Pluronic F-127 Product Number : P2443 Brand : Sigma Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO USA Telephone : Fax : Emergency Phone # (For : (314) both supplier and manufacturer) Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards No known OSHA hazards GHS Classification Skin irritation (Category 3) GHS Label elements, including precautionary statements Pictogram Signal word Hazard statement(s) H316 Precautionary statement(s) HMIS Classification Health hazard: 1 Flammability: 0 Physical hazards: 0 NFPA Rating Health hazard: 1 Fire: 0 Reactivity Hazard: 0 Potential Health Effects Inhalation Skin Eyes Ingestion none Warning Causes mild skin irritation. none 3. COMPOSITION/INFORMATION ON INGREDIENTS May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. May be harmful if swallowed. Sigma - P2443 Page 1 of 6
11 No ingredients are hazardous according to OSHA criteria. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIREFIGHTING MEASURES Conditions of flammability Not flammable or combustible. Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Carbon oxides 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Sigma - P2443 Page 2 of 6
12 Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Eye protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Safety data powder colourless ph Melting point/freezing point Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water Relative vapour density Odour Odour Threshold Evaporation rate 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Sigma - P2443 Page 3 of 6
13 Conditions to avoid Materials to avoid Strong oxidizing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 LD50 Oral - rat - 9,380 mg/kg LD50 Oral - mouse - 15,000 mg/kg Inhalation LC50 Dermal LD50 LD50 Dermal - rabbit - 20,000 mg/kg Other information on acute toxicity Skin corrosion/irritation Skin - rabbit - Mild skin irritation - 24 h Serious eye damage/eye irritation Eyes - rabbit - Mild eye irritation - 24 h Eyes - rabbit - No eye irritation - OECD Test Guideline 405 Respiratory or skin sensitization rabbit - Did not cause sensitization on laboratory animals. Germ cell mutagenicity Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Carcinogenicity IARC: ACGIH: NTP: OSHA: Reproductive toxicity No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Sigma - P2443 Page 4 of 6
14 Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure Effects due to ingestion may include:, Diarrhoea, Weakness, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: MD ECOLOGICAL INFORMATION Toxicity Toxicity to fish Persistence and degradability Bioaccumulative potential Bioaccumulation is unlikely. Mobility in soil PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS static test LC50 - other fish - > 10,000 mg/l - 96 h Method: OECD Test Guideline 203 Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION OSHA Hazards No known OSHA hazards SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. Sigma - P2443 Page 5 of 6
15 SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards No SARA Hazards Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right To Know Components Polyethylene glycol, propoxylated New Jersey Right To Know Components Polyethylene glycol, propoxylated CAS-No CAS-No Revision Date Revision Date California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. 16. OTHER INFORMATION Further information Copyright 2012 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. Sigma - P2443 Page 6 of 6
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