Safety Data Sheet Clidox Deactivator. 1. Identification

Transcription

1 1. Identification 1.1. Product identifier Product Identity Alternate Names 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method 1.3. Details of the supplier of the safety data sheet Company Name See Technical Data Sheet. See Technical Data Sheet. Pharmacal Research Labs.,Inc. 562 Captain Neville Dr. Waterbury, CT 06705, USA 24 hour Emergency Telephone No.: CHEMTREC (USA) (800) IN CANADA CALL CANUTEC (613) Customer Service: Pharmacal Research Labs.,Inc , (800) Hazard(s) identification 2.1. Classification of the substance or mixture Not a hazardous substance or mixture Label elements Not a hazardous substance or mixture. [Prevention]: P264 Wash thoroughly after handling. P280 Wear protective gloves / eye protection / face protection. [Response]: P IF SWALLOWED: Rinse mouth with water. P IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower. P IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell. P IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. Page 1 of 9

2 P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. P363 Wash contaminated clothing before reuse. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Sodium Thiosulfate Solution CAS Number: Not a hazardous substance or mixture. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vpvb-substance. *The full texts of the phrases are shown in Section First aid measures 4.1. Description of first aid measures General Inhalation Eyes Skin Ingestion In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Move to fresh air. Consult a physician if irritation of respiratory passages occur. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Wash off with soap and plenty of water. Call a poison control center or doctor for treatment advice. Have person rinse mouth with water. Do not give anything by mouth to an unconscious person. DO NOT Induce vomiting Most important symptoms and effects, both acute and delayed Overview The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11. Page 2 of 9

3 5. Fire-fighting measures 5.1. Extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide Special hazards arising from the substance or mixture no data 5.3. Advice for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. ERG Guide No. NA 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8) Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up Steps to be taken in case material is released or spilled: Keep in suitable, closed containers for disposal. Empty container warnings: Do not reuse empty container. Triple rinse with water. Dispose of in conformance with federal, state, and local regulations. 7. Handling and storage 7.1. Precautions for safe handling Use goggles or face shield, rubber gloves, and boots where contact is expected. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. See section 2 for further details. - [Storage]: 7.3. Specific end use(s) Keep out of reach of children. For professional use only. Do not mix with any other chemicals unless compatibility has been established by the manufacturer. Page 3 of 9

4 8. Exposure controls and personal protection 8.1. Control parameters Exposure Sodium Thiosulfate OSHA No Established Limit ACGIH NIOSH Supplier No Established Limit No Established Limit No Established Limit Carcinogen Data CAS No. Ingredient Source Value Sodium Thiosulfate OSHA Select Carcinogen: No NTP IARC Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 8.2. Exposure controls Respiratory Eyes Skin Engineering Controls Other Work Practices Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Chemical Splash goggles or faceshield See section 2 for further details. - [Prevention]: Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. All parts of the body should be washed after contact. Use neoprene or rubber gloves or PVC.. General industrial hygiene practice. An eyewash fountain should be located in areas where the product is used. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Page 4 of 9

5 9. Physical and chemical properties Appearance Odor Odor threshold ph 7.5 Melting point / freezing point Initial boiling point and boiling range Flash Point Evaporation rate (Ether = 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Clear Liquid Vapor pressure (Pa) Vapor Density Specific Gravity 1.3 Partition coefficient n-octanol/water (Log Kow) Auto-ignition temperature Decomposition temperature Viscosity (cst) 9.2. Other information Not Applicable Lower Explosive Limit: Upper Explosive Limit: Physical properties are approximate or typical values and should not be used for precise design purposes. 10. Stability and reactivity Reactivity Chemical stability Stable under normal circumstances Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong oxidizing agents, Strong acids Hazardous decomposition products Page 5 of 9

6 11. Toxicological information Acute toxicity Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor LD50, mg/l/4hr Inhalation Dust/Mist LD50, mg/l/4hr Inhalation Gas LD50, ppm Sodium Thiosulfate ( ) Note: When no route specific LD50 data is for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Classification Category Hazard Description Acute toxicity (oral) --- Not Applicable Acute toxicity (dermal) --- Not Applicable Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation --- Not Applicable Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity --- Not Applicable STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable 12. Ecological information Toxicity No additional information provided for this product. See Section 3 for chemical specific data. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l Sodium Thiosulfate ( ) Not Available Not Available Not Available Page 6 of 9

7 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment PBT/vPvB assessment not as chemical safety assessment not required/not conducted Other adverse effects 13. Disposal considerations Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14. Transport information DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) UN number NA NA NA UN proper shipping name Transport hazard class(es) ICAO/IATA Liquid Cleaning Coumpound Liquid Cleaning Coumpound Liquid Cleaning Coumpound DOT Hazard Class: NA DOT Label: NA IMDG: NA Sub Class: Not Applicable Packing group NA NA NA Air Class: NA Environmental hazards IMDG Marine Pollutant: No Special precautions for user No further information 15. Regulatory information Regulatory Overview Toxic Substance The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All components of this material are either listed or exempt from listing on the TSCA Page 7 of 9

8 Control Act ( TSCA) WHMIS Classification US EPA Tier II Hazards Inventory. NA EPCRA 311/312 Chemicals and RQs (lbs): No SARA Hazards Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): No Delayed (Chronic): No EPCRA 302 Extremely Hazardous: EPCRA 313 Toxic Chemicals: Proposition 65 - Carcinogens (>0.0%): Proposition 65 - Developmental Toxins (>0.0%): Proposition 65 - Female Repro Toxins (>0.0%): Proposition 65 - Male Repro Toxins (>0.0%): N.J. RTK Substances (>1%): Sodium thiosulfate Penn RTK Substances (>1%): Sodium thiosulfate 16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: Not a hazardous substance or mixture. This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable. Page 8 of 9

9 The information and recommendations contained herein are, to the best of Pharmacal s knowledge and belief, accurate and reliable as of the date issued. Pharmacal does not warrant or guarantee their accuracy or reliability, and Pharmacal shall not be liable for any loss or damage arising out of there use thereof. The information and recommendations are offered for the user s consideration and examination, and it is the user s responsibility to satisfy itself that they are suitable and complete for its particular use. The hazardous materials identification system (HMIS) and national fire protection association ratings have been included by Pharmacal research laboratories INC. In order to provide additional health and hazard information. The ratings recommended are based upon criteria supplied by the developers of these rating systems, together with Pharmacal s interpretation of the data. End of Document Page 9 of 9