2.2 : Non-flammable, nontoxic

Transcription

1 Page : 1 ón 2.2 : Non-flammable, nontoxic gases Warning M«SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name SDS Nr Use Company identification : 2.5% Vol CH4 // Air : 103DS2.5CH4A Emergency telephone number : Tel 24hr: +44 (0) SECTION 2. Hazards identification 2.1. Classification of the substance or mixture 2.2. Label elements 2.3. Other hazards : Industrial and professional. Perform risk assessment prior to use. : Units Speedwell Road Parkhouse Industrial Estate ST5 7RG Newcastle Under Lyme, Staffordshire UNITED SECTION 3. Composition/information on ingredients Mixture. Components : This product is hazardous. CAS No Substance name Contents EC No Classification(DSD) Classification(CLP) Index No Registration no Methane : 2.5 % F+; R12 Flam. Gas 1 (H220) * 1 Nitrogen : % Not classified (DSD) *1 Oxygen : % O; R8 Ox. Gas 1 (H270) * 1

2 Page : 2 SECTION 3. Composition/information on ingredients (continued) Full text of R-phrases see section 16. * 1: Listed in Annex IV / V REACH, exempted from registration. * 2: Registration deadline not expired. SECTION 4. First aid measures - Inhalation : Not hazardous. - Skin/eye contact : No effect on living tissue. Ingestion is not considered a potential route of exposure. - Ingestion : Ingestion is not considered a potential route of exposure. SECTION 5. Firefighting measures Extinguishing media - Suitable extinguishing media : All known extinguishants can be used. Specific hazards Hazardous combustion products Specific methods Special protective equipment for fire fighters : Exposure to fire may cause containers to rupture/explode. Supports combustion. : If possible, stop flow of product. Move away from the container and cool with water from a protected position. SECTION 6. Accidental release measures Personal precautions : None necessary. SECTION 7. Handling and storage Handling Storage : Open valve slowly to avoid pressure shock. Suck back of water into the container must be prevented. Do not allow backfeed into the container. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Refer to supplier's container handling instructions. : Keep container below 50 C in a well ventilated place. SECTION 8. Exposure controls/personal protection 8.2. Exposure controls Personal protection : None necessary. SECTION 9. Physical and chemical properties Physical state at 20 C / 101.3kPa Colour Odour Relative density, gas (air=1) : Compressed gas. : Colourless gas. : Odourless. : Lighter or similar to air.

3 Page : 3 SECTION 10. Stability and reactivity Stability and reactivity : Stable under normal conditions. SECTION 11. Toxicological information Toxicity information Rat inhalation LC50 [ppm/4h] : No toxicological effects from this product. : No data available. SECTION 12. Ecological information Ecological effects information Effect on ozone layer Global warming potential [CO2=1] : No ecological damage caused by this product. : Contains greenhouse gas(es) not covered by 842/2006/EC. SECTION 13. Disposal considerations General Disposal method : Consult supplier for specific recommendations. SECTION 14. Transport information UN number : 1956 Labelling ADR, IMDG, IATA Land transport (ADR/RID) ón : 2.2 : Non-flammable, non-toxic gases H.I. nr : 20 UN proper shipping name : COMPRESSED GAS, N.O.S. (Nitrogen, Oxygen) Transport hazard class(es) : 2 Classification code : 1 A Packing group Packing Instruction(s) Tunnel Restriction : E : Passage forbidden through tunnels of category E. Sea transport (IMDG) Proper shipping name : COMPRESSED GAS, N.O.S. (Nitrogen, Oxygen) Class : 2.2 Emergency Schedule (EmS) - Fire : F-C Emergency Schedule (EmS) - Spillage : S-V Packing instruction IMDG-Marine pollutant : - Air transport (ICAO-TI / IATA-DGR) Proper shipping name (IATA) : COMPRESSED GAS, N.O.S. (Nitrogen, Oxygen) Class : 2.2 Passenger and Cargo Aircraft : Packing instruction - Passenger and : 200 Cargo Aircraft

4 Page : 4 SECTION 14. Transport information (continued) Cargo Aircraft only : Packing instruction - Cargo Aircraft : 200 only ADR/RID - IMO-IMDG code - ICAO/IATA Other transport information : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. - Ensure there is adequate ventilation. - Compliance with applicable regulations. SECTION 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture SECTION 16. Other information GHS information (for internal use only) GHS information : GHS Category Determination according to "Profile" table ============================================== - Category : GSUP-C : GASES UNDER PRESSURE-Compressed (H280_W) All GHS Categories set by "Profile" table (if it exists) are removed (according to settings) GHS Conventional Method Calculation =============================== *** GHS Specific Concentration Limits --- SCL : No substance with SCL *** GHS Concentration Limits with cut-off : No cut-off values *** Normal concentration limits for "Very corrosive substances" : No "very corrosive" substances present in the mixture. GHS Category Determination according to experimental values - Acute Toxicity - human ======================================================================= == AT Oral LD50 : not applicable (category from "Profile" table remained, if it exists) AT Dermal LD50 : not applicable (category from "Profile" table remained, if it exists) AT Inhalation LC50 Gas LC50 : not applicable (category from "Profile" table remained, if it exists) GHS Category Determination according to experimental values - Acute and Chronic Toxicity - Aquatic environment ======================================================================= ======================= AT Aquatic Environment LC50 : not defined (category from "Profile" table remained, if it

5 Page : 5 SECTION 16. Other information (continued) exists) GHS Category Determination according to experimental values (other than AT) =============================================================== Flammability - gas : not defined (category from "Profile" table remained, if it exists). Oxydizing - gas : not defined (category from "Profile" table remained, if it exists). Corrosiveness : not defined (category from "Profile" table remained, if it exists). Eye damage : not defined (category from "Profile" table remained, if it exists). Training advice SPECIAL CASES - according to setting ============= : Receptacle under pressure. List of full text of R-phrases in section : R8 : Contact with combustible material may cause fire. 3. R12 : Extremely flammable. Note : This Safety Data Sheet has been established in accordance with the applicable European Union legislation. DISCLAIMER OF LIABILITY : Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out. Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. End of document