MSDS. Material Safety Data Sheet

Transcription

1 PRODUCT NAME: PERMA SEAL ITEM NUMBER: DESCRIPTION: EPOXY CONCRETE SEALING COMPOUND HMIS CODES: H: 2* F: 3 R: 0 P: G PART A SECTION 1 IDENTIFICATION MANUFACTURER'S NAME: GARON PRODUCTS, INC. P.O. Box 1924, Wall, NJ ; Fax: EMERGENCY PHONE NO: CHEMTREC SECTION 2 HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS / CAS # OSHA PEL ACGIH TLV OSHA STEL WT % Solid Epoxy Resin CAS # ne ne ne Fluroaliphatic Polymeric Esters (Less than 3%) CAS# Unknown ne ne ne *Xylene CAS # ppm 100 ppm 150 ppm 32 Propriertary n Hazardous Additive CAS# Unknown ne ne ne SECTION 2 NOTES: *Indicates toxic chemical(s) subject to reporting requirements of section 313 of Title III and of 40 CFR 372. ACGIH STEL=150PPM for XYLENE. SECTION 3 PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point 279 F Vapor Density Specific Gravity (H 2 O=1) 1.0 Evaporation Rate Solubility in water Appearance and odor Negligible Pale yellow liquid with solvent odor. SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point 77 F Method Used Flammable limits in air by volume Extinguishing media Special Firefighting Procedures Unusual Fire and Explosion Hazards Seta Flash Lower: Upper: Foam, Alcohol Foam, CO 2, Dry Chemical. Do not enter confined fire area with out full bunker gear including a positive pressure NIOSH approved self contained breathing apparatus. Cool all fire exposed containers with water. Presence of solvents in product may require grounding. If fire occurs, solvents may produce excessive pressure. Sealed drums may rupture and ignite. Vapors are heavier than air and may travel along the ground and ignite by any source of ignition. Never use a cutting or welding torch near containers (even empty). All 5 gallon and larger containers should be grounded before transferring material. Page 1 of 7

2 SECTION 5 REACTIVITY DATA Stability Stable Conditions to avoid Incompatibility (Materials to avoid) Hazardous Decomposition or Byproducts Hazardous Polymerization Avoid excessive heat or open flames as well as all sources of ignition such as sparks, heaters, static discharges etc. Avoid Amine curing agents in uncontrolled amounts and strong oxidizing agents. May form toxic chemicals, carbon dioxide, carbon monoxide and various hydrocarbons etc. Will not occur. SECTION 6 HEALTH HAZARD DATA A. Health risks and symptoms of exposure Can cause nausea and respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. May cause an allergic reaction Skin Contact Eye Contact Skin Absorption May cause irritation, defatting and dermatitis. May cause an allergic reaction. Can cause severe irritation, redness, tearing or blurred vision. t likely to be absorbed in toxic amounts but measures should be taken to avoid all contact with this material. Can cause gastrointestinal irritation, nausea, vomiting, diarrhea and aspiration of material into the lungs can cause chemical pneumontitis, which can be fatal. B. Health hazards (acute & chronic): Epoxy resins can cause sensitization by exposure through contact or high concentrations of vapor. Over exposure to this material can cause cardiac abnormalities, anemia, liver abnormalities or kidney damage. CARCINOGENICITY Medical conditions generally aggravated by exposure NTP? IARC MONOGRAPHS? ingredients of this product are regulated as carcinogens. Respiratory conditions or other allergic responses. C. Emergency & First Aid Procedures Eyes Flush eyes with water for at least 15 minutes and consult a physician. Skin OSHA REGULATED? Skin contact will normally cause no more than irritation but wash affected area with soap and water and remove contaminated clothing promptly. Remove victim to fresh air area and administer oxygen if necessary. Do not induce vomiting, keep person warm and consult a physician immediately. Page 2 of 7

3 SECTION 7 SAFE HANDLING & USE INFORMATION Steps to be taken in case material is released or spilled Waste disposal method Precautions to be taken in handling and storing Other precautions Wear respirator and protective clothing. Remove all sources of ignitions. Take up the remainder with an absorbent such as clay and place in disposal containers. Flush area with water to remove residue. Dispose of material in a waste disposal site in accordance with local, state and federal laws. Store in cool dry place. Seal all partially used containers. Wash with soap and water before eating, drinking, smoking or using toilet facilities. Mixed materials contain the hazards of all the components, therefore, read the 's of all the components prior to using material. Properly label all containers. Keep material away from all sources of ignition. Avoid al skin contact. Avoid breathing vapors generated from the material. Observe conditions of good general hygiene and safe working practices. Contaminated leather articles cannot be cleaned and must be discarded if contaminated with this product. Wash all contaminated clothing prior to the reuse thereof. Wear appropriate safety equipment and respirator at all times when ventilation is no sufficient to control vapors. SECTION 8 CONTROL MEASURES/PROTECTION INFORMATION Respiratory protection Use a NIOSH approved respirator as required to prevent over exposure to vapor in accordance with 29 CFR Engineering or administrative measures should be taken to reduce the risk and exposure. Ventilation Protective gloves Eye protection Other protective clothing or equipment Work/hygienic practices Provide sufficient mechanical (general and local exhaust) ventilation to maintain exposure below TLV. Impervious gloves Neoprene or Rubber. Splash goggles or glasses with side shields. Wear body covering clothing and other coverings as necessary such as apron and appropriate footwear to avoid contact with material. Observe good general hygienic practices. Page 3 of 7

4 PRODUCT NAME: PERMA SEAL ITEM NUMBER: DESCRIPTION: EPOXY CONCRETE SEALING COMPOUND PART B SECTION 1 HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS / CAS # OSHA PEL ACGIH TLV OSHA STEL WT % *Xylene CAS # Triethylene Tetramine CAS # Diner/TOFA, Reaction product with TETA CAS # ppm 100 ppm 150 ppm 38 ne ne ne ne ne ne nyl Phenol CAS # ne ne ne Benzene 1,3 Dimethanemine/Phenol/ Formaldahyde CAS # ne ne ne M Xylene Diamine CAS# ne.1mg/m 3 ne *Phenol CAS# ppm 5ppm 10ppm 1 Fatty Acid, Dimers, reaction products with TOFA CAS# Benzyl Alcohol CAS# ne ne ne ne ne ne Tetraethylene Pentamine CAS# ne ne ne SECTION 2 NOTES: *Indicates toxic chemical(s) subject to reporting requirements of section 313 of Title III and of 40 CFR 372. ACGIH STEL=150PPM for XYLENE. Butanol OSHA TWA (Skin) =50ppm. ACGIH TWA (Skin) =50ppm. Follow CWA 311 (B) (2) (A) 40 CFR 116, 117: CWA 304 (A) (1) 45FR 79318; TSCA 8 (d) 40 CFR FR 387 Guidelines. SECTION 2 PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Range 279 F 560 F Vapor Density Specific Gravity (H 2 O 1) 0.9 Evaporation Rate Solubility in water Appearance and odor Negligible Low Viscosity liquid with solvent odor. Page 4 of 7

5 SECTION 3 FIRE AND EXPLOSION HAZARD DATA Flash Point 74 F Method Used Flammable limits in air by volume Extinguishing media Special Firefighting procedures Unusual Fire and Explosion Hazards Seta Flash Lower: Upper: Foam, Alcohol Foam, CO 2, Dry Chemical. Do not enter confined fire area with out full bunker gear including a positive pressure NIOSH approved self contained breathing apparatus. Cool all fire exposed containers with water. Presence of solvents in product may require grounding. If fire occurs, solvents may produce excessive pressure. Sealed drums may rupture and ignite. Vapors are heavier than air and may travel along the ground and ignite by any source of ignition. Never use a cutting or welding torch near containers (even empty). All 5 gallon and larger containers should be grounded before transferring material. SECTION 4 REACTIVITY DATA Stability Stable Conditions to avoid Incompatibility (Materials to avoid) Hazardous Decomposition or Byproducts Hazardous Polymerization Avoid excessive heat or open flames as well as all sources of ignition such as sparks, heaters, static discharges etc. Avoid epoxy resin agents in uncontrolled amounts and strong oxidizing agents, as well as strong acids. May form toxic chemicals, carbon dioxide, carbon monoxide and various hydrocarbons etc. Will not occur. SECTION 5 HEALTH HAZARD DATA A. Health risks and symptoms of exposure Can cause nausea and respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. May cause an allergic reaction. Skin Contact Eye Contact Skin Absorption May cause irritation, defatting and dermatitis. May cause an allergic reaction. Can cause severe irritation, redness, tearing or blurred vision. t likely to be absorbed in toxic amounts but measures should be taken to avoid all contact with this material. Can cause gastrointestinal irritation, nausea, vomiting, diarrhea and aspiration of material into the lungs can cause chemical pneumontitis, which can be fatal. Page 5 of 7

6 B. Health hazards (acute & chronic): Amines can cause sensitization by exposure through contact or high concentrations of vapor. Over exposure to this material can cause cardiac abnormalities, anemia, liver abnormalities or kidney damage. CARCINOGENICITY NTP? IARC MONOGRAPHS? ingredients of this product are regulated as carcinogens. OSHA REGULATED? Medical conditions generally aggravated by exposure Respiratory conditions or other allergic responses. C. Emergency & First Aid Procedures Eyes Flush eyes with water for at least 15 minutes and consult a physician. Skin Skin contact will normally cause no more than irritation but wash affected area with soap and water and remove contaminated clothing promptly. Remove victim to fresh air area and administer oxygen if necessary. Do not induce vomiting, keep person warm and consult a physician immediately. SECTION 6 SAFE HANDLING & USE INFORMATION Steps to be taken in case material is released or spilled Wear respirator and protective clothing. Remove all sources of ignitions. Take up the remainder with an absorbent such as clay and place in disposal containers. Flush area with water to remove residue. Waste disposal method Precautions to be taken in handling and storing Other precautions Dispose of material in a waste disposal site in accordance with local, state and federal laws. Store in cool dry place. Seal all partially used containers. Wash with soap and water before eating, drinking, smoking or using toilet facilities. Mixed materials contain the hazards of all the components, therefore, read the 's of all the components prior to using material. Properly label all containers. Keep material away from all sources of ignition. Avoid skin contact. Avoid breathing vapors generated from the material. Observe conditions of good general hygiene and safe working practices. Contaminated leather articles cannot be cleaned and must be discarded if contaminated with this product. Wash all contaminated clothing prior to the reuse thereof. Wear appropriate safety equipment and respirator at all times when ventilation is no sufficient to control vapors. Page 6 of 7

7 SECTION 7 CONTROL MEASURES/PROTECTION INFORMATION Respiratory protection Use a NIOSH approved respirator as required to prevent over exposure to vapor in accordance with 29 CFR Engineering or administrative measures should be taken to reduce the risk and exposure. Ventilation Protective gloves Eye protection Other protective clothing or equipment Work/hygienic practices Provide sufficient mechanical (general and local exhaust) ventilation to maintain exposure below toxic level values. Impervious gloves Neoprene or Rubber. Splash goggles or glasses with side shields. Wear body covering clothing and other coverings as necessary such as apron and appropriate footwear to avoid contact with material. Observe good general hygienic practices. Garon products are sold with the understanding that the buyer will test them in actual use and determine for himself their adaptability to his intended use. However, since such use is beyond our control, we do not guarantee the results to be obtained in the customer's processes. The information contained in this brief is advisory only, and the use of the materials and methods is solely at the risk of the user. These recommendations and suggestions for the use of our materials are in accordance with Garon standards. There are no other warranties by Garon of any nature whatsoever, expressed or implied, including any warranty of merchantability or fitness for a particular purpose in connection with this product, and under no circumstances, either expressed or implied, will GARON PRODUCTS, INC. be liable for damages in excess of the purchase price of this product. statement or recommendation not contained herein shall have any force or effect unless in an agreement signed by the officers of manufacturer and seller Garon Products, Inc 03/06 Page 7 of 7