Material Safety Data Sheet

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1 Material Safety Data Sheet Date of issue 24 May 2012 Version 1 1. Identification of the material and supplier Names Product code Product name Supplier Emergency telephone number Uses Recommended use 2. Risk phrases Squirts Aerosol - Black (Gloss) PPG Industries Pty Limited (ABN ) Locked Bag 888 CLAYTON SOUTH Victoria 3169 Tel (03) Fax (03) (24hr) Hazards identification Statement of hazardous/dangerous nature Safety phrases 3. Coating. Paint. Painting-related materials. HAZARDOUS SUBSTANCE. DANGEROUS GOODS. R12- Extremely flammable. R36- Irritating to eyes. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately and show this container or label. Composition/information on ingredients Ingredient name CAS number Concentration acetone propane Solvent naphtha (petroleum), light aliph Solvent naphtha (petroleum), light arom ,2,4-trimethylbenzene cumene Other ingredients, determined not to be hazardous according to Safe Work criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. 4. First-aid measures Inhalation Ingestion Skin contact Eye contact Notes to physician Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Page 1/6

2 5. Fire-fighting measures Extinguishing media Suitable Not suitable Hazardous combustion products Special exposure hazards Special protective equipment for fire-fighters Hazchem code 6. Use an extinguishing agent suitable for the surrounding fire. None known. Decomposition products may include the following materials carbon oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. This material is harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. None Accidental release measures Personal precautions Environmental precautions Large spill Small spill No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurised contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note see section 1 for emergency contact information and section 13 for waste disposal. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. 7. Handling and storage All users should refer to the product Technical Data Sheet (TDS) before use. Handling Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Pressurised container protect from sunlight and do not expose to temperature exceeding 50 C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator Page 2/6

3 7. Storage 8. Handling and storage Exposure controls Engineering measures Hygiene measures Eyes Hands Respiratory Skin when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Empty containers retain product residue and can be hazardous. Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection Occupational exposure limits Ingredient name Exposure limits acetone Safe Work (, 8/2005). STEL 2375 mg/m³, 0 times per shift, 15 minute(s). STEL 1000 ppm, 0 times per shift, 15 minute(s). TWA 1185 mg/m³, 0 times per shift, 8 hour(s). TWA 500 ppm, 0 times per shift, 8 hour(s). propane ACGIH TLV (United States, 2/2010). TWA 1000 ppm 8 hour(s). 1,2,4-trimethylbenzene Safe Work (, 8/2005). TWA 123 mg/m³, 0 times per shift, 8 hour(s). TWA 25 ppm, 0 times per shift, 8 hour(s). cumene Safe Work (, 8/2005). Absorbed through skin. STEL 375 mg/m³, 0 times per shift, 15 minute(s). STEL 75 ppm, 0 times per shift, 15 minute(s). TWA 125 mg/m³, 0 times per shift, 8 hour(s). TWA 25 ppm, 0 times per shift, 8 hour(s). Recommended monitoring procedures Gloves If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Page 3/6

4 8. Exposure controls/personal protection Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. References Eye protectors should conform to AS/NZS 1336 and AS/NZS Chemical-resistant gloves should conform to AS/NZS Respiratory protection should conform to AS/NZS 1715 and AS/NZS Occupational footwear should conform to AS/NZS Physical state Colour Odour Boiling point Melting point Vapour pressure Liquid. Relative density 0.74 Flash point Flammable limits ph Auto-ignition temperature Solubility Physical and chemical properties Vapour density <35 C (<95 F) Closed cup -20 C (-4 F) 10. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Stable under recommended storage and handling conditions (see section 7). Avoid all possible sources of ignition (spark or flame). Reactive or incompatible with the following materials oxidizing materials strong acids strong alkalis Under normal conditions of storage and use, hazardous decomposition products should not be produced. 11. Toxicological information Potential acute health effects Inhalation Ingestion Skin contact Eye contact Over-exposure signs/symptoms Inhalation Ingestion Skin Vapours may cause drowsiness and dizziness. No known significant effects or critical hazards. Defatting to the skin. May cause skin dryness and irritation. Irritating to eyes. Adverse symptoms may include the following nausea or vomiting respiratory tract irritation coughing headache drowsiness/fatigue dizziness/vertigo No specific data. Adverse symptoms may include the following irritation dryness cracking Page 4/6

5 11. Eyes Toxicological information Target organs 12. Ecological information Environmental effects Other ecological information Biodegradability Other ecological information Persistence/degradability Conclusion/Summary Adverse symptoms may include the following irritation watering redness Contains material which causes damage to the following organs brain, central nervous system (CNS). Contains material which may cause damage to the following organs blood, lungs, heart, upper respiratory tract, skin, eye, lens or cornea, testes. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Product/ingredient name LogPow BCF Potential acetone low propane low 1,2,4-trimethylbenzene high cumene low Mobility Other adverse effects 13. Waste disposal Disposal considerations No known significant effects or critical hazards. Do not allow to enter drains or watercourses. The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Do not puncture or incinerate container. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information Regulation UN number Proper shipping name Classes PG* ADG 1950 AEROSOLS ADR 1950 AEROSOLS IMDG 1950 AEROSOLS IATA 1950 AEROSOLS PG* Packing group Additional information Hazchem code None Tunnel code (D) - - Page 5/6

6 15. Regulatory information Standard for the Uniform Scheduling of Drugs and Poisons SUSDP Schedule Control of Scheduled Carcinogenic Substances Ingredient name No listed substance inventory (AICS) Schedule 5 All components are listed or exempted. Schedule 16. Date of issue Disclaimer Other information Organisation that prepared the MSDS 24 May 2012 EHS Indicates information that has changed from previously issued version. The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Page 6/6

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