Issue Date 04-Feb-2015 Revision Date 04-Feb-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION OXYGEN STAIN REMOVER. Use only as stated on label.
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1 SAFETY DATA SHEET Issue Date 04-Feb-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name OXYGEN STAIN REMOVER Other means of identification Product Code SS 0502 Recommended use of the chemical and restrictions on use Recommended Use Destainer. Uses advised against Use only as stated on label. Details of the supplier of the safety data sheet Supplier Suburban Supply 29 Kearney Road Needham, MA Phone: (781) Emergency telephone number Emergency Telephone Chemtrec Classification 2. HAZARDS IDENTIFICATION OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute toxicity - Oral Category 5 Acute toxicity - Dermal t classified Acute toxicity - Inhalation (Dusts/Mists) Category 4 Serious eye damage/eye irritation Category 2 Label elements Emergency Overview Warning Hazard statements May be harmful if swallowed Harmful if inhaled Causes serious eye irritation Harmful to aquatic life with long lasting effects Appearance White Physical state granules Odor Mild Page 1 / 7
2 Precautionary Statements - Prevention Avoid breathing dust Use only outdoors or in a well-ventilated area Wash hands and any exposed skin thoroughly after handling. Wear eye protection Avoid release to the environment Precautionary Statements - Response Call a POISON CENTER or doctor/physician if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS First aid measures Chemical Name CAS. Weight-% Trade Secret Sodium Carbonate * Sodium Percarbonate * Sodium Silicate * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES General advice Skin Contact Eye contact Inhalation Ingestion Self-protection of the first aider If symptoms persist, call a physician. Do not breathe dust. Do not get in eyes, on skin, or on clothing. Consult a physician if necessary. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is not required. If skin irritation persists, call a physician. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing If symptoms persist, call a physician Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician Remove to fresh air. Call a physician. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Immediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a physician. Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Page 2 / 7
3 Symptoms Indication of any immediate medical attention and special treatment needed te to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Explosion data Sensitivity to Mechanical Impact ne. Sensitivity to Static Discharge ne. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Dam up. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Use with local exhaust ventilation. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. ne known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 3 / 7
4 Control parameters Exposure Guidelines Appropriate engineering controls Engineering Controls This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Respiratory protection General Hygiene Tight sealing safety goggles. Face protection shield. special technical protective measures are necessary. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state granules Appearance White Odor Mild Odor threshold Property Values Remarks Method ph % solution Melting point/freezing point Boiling point / boiling range Flash point ne Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Specific Gravity Water solubility completely soluble Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Viscosity Explosive properties Oxidizing properties Reactivity data available 10. STABILITY AND REACTIVITY Page 4 / 7
5 Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials ne known based on information supplied. Hazardous Decomposition Products ne known based on information supplied. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye contact Skin Contact Ingestion data available Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium Carbonate = 4090 mg/kg ( Rat ) Yes = 2300 mg/m 3 ( Rat ) 2 h Information on toxicological effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Chronic toxicity Aspiration hazard Avoid repeated exposure. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. Ecotoxicity 12. ECOLOGICAL INFORMATION 0% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Sodium Carbonate 242: 120 h Nitzschia mg/l EC : 96 h Pimephales promelas mg/l LC50 static 300: 96 h Lepomis macrochirus mg/l LC50 static Crustacea 265: 48 h Daphnia magna mg/l EC50 Page 5 / 7
6 Sodium Percarbonate Sodium Silicate Persistence and degradability Bioaccumulation 70: 240 h Chlorella emersonii mg/l EC50 Yes 70.7: 96 h Pimephales promelas mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC : 96 h Brachydanio rerio mg/l LC50 semi-static 4.9: 48 h Daphnia pulex mg/l EC50 216: 96 h Daphnia magna mg/l EC50 Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. 14. TRANSPORT INFORMATION DOT t regulated International Inventories TSCA DSL/NDSL EINECS/ELINCS AICS 15. REGULATORY INFORMATION Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of tified Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) Page 6 / 7
7 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide Registration Number t Applicable 16. OTHER INFORMATION NFPA Health hazards 2 Flammability 0 Instability 1 HMIS Health hazards 2 Flammability 0 Physical hazards 1 Physical and Chemical Properties Yes Personal protection N/A Issue Date 04-Feb-2015 Revision Date 04-Feb-2015 Revision te Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7
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