SAFETY DATA SHEET CLEENOL TANNIN REMOVER

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Manufacturer Cleenol Group Ltd Neville House Beaumont Road Banbury Oxon OX16 1RB UK Tel : +44 (0) Fax : +44 (0) sales@cleenol.co.uk Cleenol Group Ltd Neville House Beaumont Road Banbury Oxon OX16 1RB UK Tel : +44 (0) Fax : +44 (0) sales@cleenol.co.uk 1.4. Emergency telephone number Emergency telephone SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Environmental hazards Acute Tox. 4 - H302 Eye Dam. 1 - H318 Not Classified Classification (67/548/EEC or 1999/45/EC) Xn;R22. Xi;R Label elements Pictogram 1/6

2 Signal word Hazard statements Precautionary statements Contains Supplementary precautionary statements Danger H302 Harmful if swallowed. H318 Causes serious eye damage. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P330 Rinse mouth. P501 Dispose of contents/container in accordance with national regulations. SODIUM PERCARBONATE P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P330 Rinse mouth. P501 Dispose of contents/container to 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures SODIUM CARBONATE 30-60% CAS number: EC number: Classification Eye Irrit. 2 - H319 Classification (67/548/EEC or 1999/45/EC) Xi;R36 SODIUM PERCARBONATE 30-60% CAS number: EC number: Classification Ox. Sol. 2 - H272 Eye Dam. 1 - H318 Acute Tox. 4 - H302 Classification (67/548/EEC or 1999/45/EC) Xn;R22. Xi;R41. O;R8. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Move affected person to fresh air at once. Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Get medical attention if any discomfort continues. Remove affected person from source of contamination. Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention promptly if symptoms occur after washing. 2/6

3 Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions 6.3. Methods and material for containment and cleaning up Methods for cleaning up Avoid generation and spreading of dust. Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid spilling. Avoid contact with skin and eyes Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in the original container Specific end use(s) SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Ingredient comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure limits for the product or ingredients. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Dust-resistant, chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. 3/6

4 Hygiene measures Respiratory protection Do not smoke in work area. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. No specific recommendations. Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Initial boiling point and range Solubility(ies) Dusty powder. White/off-white. Pleasant, agreeable. Not applicable. Soluble in water Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stability Stable at normal ambient temperatures Possibility of hazardous reactions Conditions to avoid Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Hazardous decomposition products Hazardous decomposition products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral ATE oral (mg/kg) 1, Inhalation Ingestion Skin contact Eye contact Dust in high concentrations may irritate the respiratory system. May cause discomfort if swallowed. Irritating to skin. Irritating to eyes. SECTION 12: Ecological Information Ecotoxicity Not regarded as dangerous for the environment Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil 4/6

5 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. SECTION 14: Transport information Road transport notes Rail transport notes Sea transport notes Air transport notes UN number UN proper shipping name Proper shipping name (ADR/RID) SODIUM CARBONATE PEROXYHYDRATE Proper shipping name (IMDG) SODIUM CARBONATE PEROXYHYDRATE Proper shipping name (ICAO) SODIUM CARBONATE PEROXYHYDRATE Proper shipping name (ADN) SODIUM CARBONATE PEROXYHYDRATE Transport hazard class(es) Transport labels Packing group Environmental hazards Special precautions for user Tunnel restriction code (-) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716). Guidance CHIP for everyone HSG228. Workplace Exposure Limits EH40. Safety Data Sheets for Substances and Preparations. Approved Classification and Labelling Guide (Sixth edition) L Chemical safety assessment SECTION 16: Other information Revision date 03/03/2015 Revision 1 Supersedes date 24/06/2013 5/6

6 SDS number Risk phrases in full Hazard statements in full K10 R22 Harmful if swallowed. R36 Irritating to eyes. R41 Risk of serious damage to eyes. R8 Contact with combustible material may cause fire. H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H318 Causes serious eye damage. H319 Causes serious eye irritation. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6/6