Date Printed: 16/FEB/2005 Date Updated: 14/MAR/2004 Version 1.3 According to 91/155/EEC
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1 SIGMA-ALDRICH 1 - Product and Company Information Material Safety Data Sheet Product Name ETHANOL, REAGENT, DENATURED, SPECTROPHOTOMETRIC GRADE Product Number Date Printed: 16/FEB/2005 Date Updated: 14/MAR/2004 Version 1.3 According to 91/155/EEC Company Sigma-Aldrich Company Ltd. The Old Brickyard New Road, Gillingham SP8 4XT United Kingdom Technical Phone # 44-(0) Fax 44-(0) Emergency Phone # 44-(0) Composition/Information on Ingredients Product Name CAS # EC no Annex I Index Number ETHANOL, DENATURED 5%MEOH, 5% IPA None None None Ingredient Name Percent CAS # EC no Annex I Index Number ETHYL ALCOHOL, NON-DENATURED, 200 PROOF Symbols: F R-Phrases: 11 Highly flammable. METHANOL X Symbols: F T R-Phrases: 11 23/24/25 39/23/24/25 Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. 2-PROPANOL Symbols: F Xi R-Phrases: Highly flammable. Irritating to eyes. Vapors may cause drowsiness and dizziness. Formula C2H6O Molecular Weight AMU 3 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Harmful: possible risk of irreversible effects through inhalation, in contact with skin, and if swallowed.
2 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. 5 - Fire Fighting Measures EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Emits toxic fumes under fire conditions. Flammable liquid. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Do not use if skin is cut or scratched. Wash thoroughly after handling. ALDRICH Page 2
3 STORAGE Conditions of Storage: Keep container closed. Keep away from heat, sparks, and open flame. SPECIAL REQUIREMENTS: Handle and store under inert gas. Moisture sensitive. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Remove and wash contaminated clothing promptly. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties Appearance Physical State: Liquid Property Value At Temperature or Pressure ph BP/BP Range 78 C 760 mmhg MP/MP Range -130 C Flash Point 9 C Method: closed cup Flammability Autoignition Temp 362 C Oxidizing Properties Explosive Properties Explosion Limits Lower: 3.3 % Upper: 24.5 % Vapor Pressure 44.6 mmhg 20 C SG/Density g/cm3 Partition Coefficient Viscosity Vapor Density 1.59 g/l Saturated Vapor Conc. Evaporation Rate Bulk Density Decomposition Temp. Solvent Content Water Content Surface Tension Conductivity Miscellaneous Data Solubility 10 - Stability and Reactivity STABILITY Stable: Stable. Conditions to Avoid: Moisture. Materials to Avoid: Oxidizing agents, Peroxides, Acids, Acid chlorides, Acid anhydrides, Alkali metals, Ammonia. ALDRICH Page 3
4 HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur 11 - Toxicological Information SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Can cause CNS depression. Exposure can cause: Gastrointestinal disturbances. Nausea, dizziness, and headache. Narcotic effect. May cause convulsions. ROUTE OF EXPOSURE Skin Contact: Causes skin irritation. Skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN INFORMATION Nerves. Eyes. Liver. Kidneys. Heart. Cardiovascular system. G.I. System. CHRONIC EXPOSURE - CARCINOGEN Result: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification Ecological Information No data available Disposal Considerations SUBSTANCE DISPOSAL Contact a licensed professional waste disposal service to dispose of this material. Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Observe all federal, state, and local environmental regulations Transport Information RID/ADR Proper Shipping Name: Flammable liquid, toxic, n.o.s. IMDG Subrisk: 6.1 Proper Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. Marine Pollutant: No Severe Marine Pollutant: No ALDRICH Page 4
5 Technical Name: Required IATA Subrisk: 6.1 Proper Shipping Name: Flammable liquid, toxic, n.o.s. Inhalation Packing Group I: No Technical Name: Required 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: F Xn Highly Flammable. Harmful. R-PHRASES: 11 20/21/22 36/37/38 68/20/21/22 Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Harmful: possible risk of irreversible effects through inhalation, in contact with skin, and if swallowed. S-PHRASES: / /37/39 45 Keep container tightly closed. Keep away from sources of ignition - no smoking. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. ALDRICH Page 5
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