SAFETY DATA SHEET. Creation Date 08-Sep-2009 Revision Date 13-Mar-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 08-Sep-2009 Revision Number 1 Product Name Cat No. : 1. Identification L13312 CAS-No Synonyms Triethoxyborane Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. 30 Bond Street Ward Hill, MA Tel: Fax: tech@alfa.com Emergency Telephone Number During normal business hours (Monday-Friday, 8am-7pm EST), call (800) After normal business hours, call Carechem 24 at (866) Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Flammable liquids Category 2 Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor May cause drowsiness or dizziness Page 1 / 7

2 Precautionary Statements Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store in a well-ventilated place. Keep cool Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % Boric acid (H3BO3), triethyl ester >95 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Move to fresh air. Get medical attention immediately if symptoms occur. If not breathing, give artificial respiration. Do not induce vomiting. Obtain medical attention. Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed containers exposed to fire with water spray. Flash Point 11 C / 51.8 F Method - Autoignition Temperature Explosion Limits Upper Lower Page 2 / 7

3 Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Oxides of boron Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 4 Instability 1 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Take precautionary measures against static discharges. Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Remove all sources of ignition. Should not be released into the environment. Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Up Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Dispose of waste product or used containers according to local regulations. Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof equipment. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges. Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area. Keep away from heat and sources of ignition. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. No protective equipment is needed under normal use conditions. Page 3 / 7

4 Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor Odor Threshold ph Melting Point/Range C / F Boiling Point/Range C / mmhg Flash Point 11 C / 51.8 F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure C Vapor Density 5.03 Specific Gravity Solubility Insoluble in water Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula C6 H15 B O3 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Moisture sensitive. Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water. Strong oxidizing agents, Strong acids Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Oxides of boron Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information See actual entry in RTECS for complete information. Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity May cause eye, skin, and respiratory tract irritation The table below indicates whether each agency has listed any ingredient as a carcinogen. Page 4 / 7

5 Component CAS-No IARC NTP ACGIH OSHA Mexico Boric acid (H3BO3), triethyl ester Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard... None known None known Symptoms / effects,both acute and delayed Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods The toxicological properties have not been fully investigated. 12. Ecological information Soluble in water Persistence is unlikely based on information available.. Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Should not be released into the environment. DOT Proper Shipping Name ETHYL BORATE TDG Proper Shipping Name ETHYL BORATE IATA Proper Shipping Name Ethyl borate IMDG/IMO Proper Shipping Name Ethyl borate 14. Transport information Page 5 / 7

6 International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Boric acid (H3BO3), triethyl X X X X X X - ester Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Serious risk, Grade 3 Prepared By 16. Other information Health, Safety and Environmental Department tech@alfa.com Page 6 / 7

7 Creation Date 08-Sep-2009 Revision Date 13-Mar-2018 Print Date 13-Mar-2018 Revision Summary SDS authoring systems update, replaces ChemGes SDS No Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7