SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.1 Revision Date: 10/27/2017

Transcription

1 1. Identification SAFETY DATA SHEET Material name: LOW RISE FOAM INSUL ADH BG PART B 5 GL Material: B405 Recommended use and restriction on use Recommended use: Curative Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco Incorporated 3735 Green Road BEACHWOOD OH US Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Acute toxicity (Inhalation- dust and mist) Serious Eye Damage/Eye Irritation Category 4 Category 2B Unknown toxicity - Health Acute toxicity, oral % Acute toxicity, dermal 0 % Acute toxicity, inhalation, vapor 100 % Acute toxicity, inhalation, dust 2.5 % or mist Label Elements Hazard Symbol: Signal Word: Hazard Statement: Warning Harmful if inhaled. Causes eye irritation. 1/12

2 Precautionary Statements Prevention: Response: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER/doctor/ if you feel unwell. Hazard(s) not otherwise classified (HNOC): None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Polypropylene glycol % * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Rinse mouth thoroughly. Move to fresh air. Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Get medical attention if symptoms occur. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. 2/12

3 Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. 7. Handling and storage Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities: Store away from incompatible materials. Store in original tightly closed container. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits None of the components have assigned exposure limits. None of the components have assigned exposure limits. 3/12

4 Appropriate Engineering Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory and eye protection may be needed in special circumstances, such as poorly ventilated spaces, heating, evaporation of liquids from large surfaces, spraying of mists, mechanical generation of dusts, drying of solids, etc. Wear goggles/face shield. Use suitable protective gloves if risk of skin contact. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing to remove contaminants. Discard contaminated footwear that cannot be cleaned. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: Colorless Odor: Slight odor Odor threshold: ph: 9-10 Melting point/freezing point: Initial boiling point and boiling range: Flash Point: > 177 C > 350 F(Pensky-Martens Closed Cup) Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: /12

5 Solubility(ies) Solubility in water: Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: Dispersible 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Material is stable under normal conditions. Avoid heat or contamination. Strong acids. Strong bases. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Eye contact: Ingestion: Moderately irritating to skin with prolonged exposure. Causes eye irritation. May be ingested by accident. Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: Skin Contact: Eye contact: Ingestion: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Not classified for acute toxicity based on available data. 5/12

6 Specified substance(s): Polypropylene glycol LD 50 (Rat): > 2,000 mg/kg Dermal Specified substance(s): Polypropylene glycol Not classified for acute toxicity based on available data. LD 50 (Rabbit): > 2,000 mg/kg Inhalation ATEmix: 2.43 mg/l Repeated dose toxicity Skin Corrosion/Irritation Specified substance(s): Polypropylene glycol in vivo (Rabbit): Not irritant Experimental result, Key study Serious Eye Damage/Eye Irritation Specified substance(s): Polypropylene glycol Rabbit, 1-48 hrs: Moderately irritating Respiratory or Skin Sensitization Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified 6/12

7 Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Specified substance(s): Polypropylene glycol LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss), 96 h): > 10,000 mg/l Mortality Aquatic Invertebrates Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates 7/12

8 Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Mobility in soil: Other adverse effects: 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 8/12

9 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. OSHA Specifically Regulated Substances (29 CFR ) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Toluene Acetaldehyde Propylene oxide Furan Reportable quantity 1000 lbs lbs. 100 lbs. 100 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate (Acute) Health Hazards SARA 302 Extremely Hazardous Substance Reportable Chemical Identity quantity Threshold Planning Quantity Propylene oxide 100 lbs lbs. Furan 100 lbs. 500 lbs. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Toluene 1000 lbs. Acetaldehyde 1000 lbs. Propylene oxide 100 lbs. Furan 100 lbs. SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Propylene oxide 500lbs Furan 500lbs Polypropylene glycol lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Chemical Identity Acetaldehyde Propylene oxide Furan Reportable quantity lbs lbs lbs Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. US State Regulations 9/12

10 US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Toluene Developmental toxin Acetaldehyde Carcinogenic Propylene oxide Carcinogenic Furan Carcinogenic US. New Jersey Worker and Community Right-to-Know Act No ingredient regulated by NJ Right-to-Know Law present. US. Massachusetts RTK - Substance List Chemical Identity Acetaldehyde Propylene oxide Furan US. Pennsylvania RTK - Hazardous Substances No ingredient regulated by PA Right-to-Know Law present. US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. International regulations Montreal protocol not applicable Stockholm convention not applicable Rotterdam convention not applicable Kyoto protocol not applicable VOC: When appropriately mixed with the other part, product has a VOC less water and exempt solvent of: 32 g/l Regulatory VOC (less water and exempt solvent) : 5 g/l VOC Method 310 : 0.50 % 10/12

11 Inventory Status: Australia AICS: Canada DSL Inventory List: EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: One or more components in this product are not listed on or One or more components in this product are not listed on or One or more components in this product are not listed on or One or more components in this product are not listed on or 16.Other information, including date of preparation or last revision Version #: 1.1 Further Information: 11/12

12 Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 12/12