Material Safety Data Sheet

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1 Material Safety Data Sheet Enriching lives through innovation. Validation date Product and company identification Product name MSDS # Product use In case of emergency 2. Physical state Odor Intermediate. Huntsman Petrochemical Corporation P.O. Box 4980 The Woodlands, TX TELEPHONE NUMBERS Transportation Emergency Company (800) CHEMTREC (800) Medical Emergency (409) (24 Hour) General MSDS Assistance (28) Technical Information (28) MSDS@huntsman.com Spills Leaks Fire or Exposure Call Chemtrec (800) Medical Emergency Information (800) In Mexico Hazards identification OSHA/HCS status Emergency overview Liquid. [Liquid.] Ammoniacal. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). CAUTION! MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Slightly irritating to the eyes and skin. Avoid breathing vapor or mist. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Contains material that may cause target organ damage, based on animal data. Wash thoroughly after handling. GENERAL INFORMATION Read the entire MSDS for a more thorough evaluation of the hazards. 3. Composition/information on ingredients Name CAS number % Triethanolamine Ethanolamine distillation residues Diethanolamine Page /7

2 4. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician 5. Firefighting measures Flash point Products of combustion Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for firefighters Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 0 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Wash out mouth with water. Move exposed person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. Symptomatic and supportive therapy as needed. Following severe exposure medical followup should be monitored for at least 48 hours. Closed cup 204 C (399.2 F) Decomposition products may include the following materials carbon oxides (CO, CO2), nitrogen oxides (NO, NO2 etc.). Use an extinguishing agent suitable for the surrounding fire. None known. In a fire or if heated, a pressure increase will occur and the container may burst. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Firefighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 3). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see section for emergency contact information and section 3 for waste disposal. Page 2/7

3 7. Handling Storage 8. Product name Handling and storage Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 0) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection Exposure limits Triethanolamine ACGIH TLV (United States, /2007). TWA 5 mg/m³ 8 hour(s). Diethanolamine ACGIH TLV (United States, /2007). Skin TWA 2 mg/m³ 8 hour(s). TWA 0.46 ppm 8 hour(s). NIOSH REL (United States, 2/200). TWA 5 mg/m³ 0 hour(s). TWA 3 ppm 0 hour(s). OSHA PEL 989 (United States, 3/989). TWA 5 mg/m³ 8 hour(s). TWA 3 ppm 8 hour(s). Consult local authorities for acceptable exposure limits. Preventive Measures Engineering controls Personal protection Eyes Skin Respiratory Hands Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Use local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For guidance on engineering control measures refer to publications such as the ACGIH current edition of 'Industrial Ventilation, a manual of Recommended Practice.' Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Use a properly fitted, airpurifying or airfed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemicalresistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Page 3/7

4 9. Physical and chemical properties General information Appearance Physical state Color Odor Odor threshold Liquid. [Liquid.] Clear. Ammoniacal. Important health, safety and environmental information ph Boiling point Melting point Flash point Oxidizing properties Vapor pressure Relative density Octanol/water partition coefficient Viscosity Vapor density VOC content C (68 F) Closed cup 204 C (399.2 F) kpa (0.0 mm Hg).3 Kinematic 3.6 cm 2 /s (360 cst) [at 38 C] 5.3 [Air = ] Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous polymerization Hazardous decomposition products. Toxicity data The product is stable. Toxicological information Acute toxicity Reactive or incompatible with the following materials oxidizing materials, organic materials, metals, acids and alkalis. Under normal conditions of storage and use, hazardous polymerization will not occur. Decomposition products may include the following materials carbon oxides (CO, CO2), nitrogen oxides (NO, NO2 etc.). Product/ingredient name test Species Result Exposure Diethanolamine LD50 Dermal Rabbit >5000 mg/kg LD50 Oral Rat Male, 700 to 2800 Female mg/kg Triethanolamine LD50 Dermal Rabbit Male, >5000 mg/kg Female LD50 Oral Rat Male, Female >5000 mg/kg Classification Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA Triethanolamine 3 Diethanolamine 3 Potential acute health effects Ingestion Inhalation Page 4/7

5 . Eyes Skin Toxicological information Potential chronic health effects Slightly irritating to the eyes. Slightly irritating to the skin. Target organs Contains material which may cause damage to the following organs blood, kidneys, liver, testes. Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects 2. Ecological information Aquatic ecotoxicity Environmental effects Product/ingredient name test Result Species Exposure Triethanolamine Acute IC Algae 72 hours Acute LC50.8 Fish Diethanolamine Acute LC Fish Acute LC Fish Acute LC Fish Acute EC50 0 Daphnia 48 hours to 87 Acute IC50 6 Bacteria 6 hours Acute IC to 798 Algae 72 hours Biodegradability Product/ingredient name test Result Dose Inoculum Triethanolamine 60 % Readily 28 days Diethanolamine 60 % Readily 28 days Product/ingredient name Aquatic halflife Photolysis Biodegradability Triethanolamine Readily Diethanolamine < 28 day(s). Readily Bioaccumulative potential Product/ingredient name LogPow BCF Potential Triethanolamine low Diethanolamine 2.8 to low Page 5/7

6 3. Disposal considerations Waste disposal 4. Transport information The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Transportation Emergency Number (CHEMTREC). Regulatory information DOT Classification TDG Classification UN number UN3082 Not regulated. Proper shipping name Environmentally hazardous substance, liquid, n.o.s. (Diethanolamine) Class PG* Label Additional information 9 III Reportable quantity 00 lbs. (45.4 kg) 9 Only regulated in Bulk. IMDG Class Not regulated. IATADGR Class Not regulated. PG* Packing group 5. United States Regulatory information HCS Classification U.S. Federal regulations CERCLA Hazardous substances. SARA 33 Form R Reporting requirements California Prop 65 Target organ effects United States inventory (TSCA 8b) All components are listed or exempted. Components Concentration Section 304 CERCLA Hazardous Substance CERCLA Reportable Quantity Diethanolamine % Listed This product does not contain nor is it manufactured with ozone depleting substances. Product name CAS number Concentration Diethanolamine 422 % Product Reportable Quantity SARA 33 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. Page 6/7

7 5. Canada Regulatory information Ingredient name Cancer Reproductive No significant risk level HEXAVALENT CHROMIUM COMPOUNDS WHMIS (Canada) CEPA (DSL) Yes. Yes. No. No. Class D2B Material causing other toxic effects (Toxic). All components are listed or exempted. Maximum acceptable dosage level This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 6. Other information Label requirements Hazardous Material Information System (U.S.A.) MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Health Fire hazard Reactivity * 0 National Fire Protection Association (U.S.A.) Health 0 Flammability Instability Date of printing Date of issue Date of previous issue Notice to reader 6/20/ June /8/2008. While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers, processors and end users. NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE, OR MAKE AVAILABLE, DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY, AT THE ABOVE ADDRESS. Page 7/7

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET SECTION 1: COMPANY AND PRODUCT IDENTIFICATION PRODUCT NAME: Thermal Energy Fluid MANUFACTURER: Bridgepoint Systems 4282 S 590 W Salt Lake City, UT 84123 Telephone: 801-261-1282 Prepared 02/01/2011 EMERGENCIES: