SECTION 1: Identification of the substance/mixture and of the company/undertaking
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1 Safety Data Sheet According to Regulation (EC) No 907/2006 Revision Date: 0/03/208 Version: 2.4 Date Printed: GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION : Identification of the substance/mixture and of the company/undertaking. Product identifiers Product Name Product Number Product type : PEGRx 2 Crystallization Kit : HR2-084 : Liquid.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses.3 Details of the supplier of the Safety Data Sheet Company : For research use only. Not for drug, household, or other use. : Hampton Research 34 Journey Aliso Viejo, CA United States Telephone : Telephone technical support is available 8:00 a.m. to 4:30 p.m. USA Pacific Standard Time. Fax : Fax Technical Support is available 24 hours a day. .4 Emergency telephone number Emergency phone : For CHEMTREC Assistance : For CHEMTREC Assistance : tech@hrmail.com Technical Support is available 24 hours a day. : (International) This is a summary MSDS for a kit, for the full MSDS for each of the components listed in section 6 please visit our website. SECTION 2: Hazards Identification 2. Classification of the substance or mixture Classification according to Regulation (EC) No 272/2008 [EU-GHS/CLP] see SECTION 6 Classification according to EU Directives 67/548/EEC or 999/45/EC see SECTION 6 Additional information: For full text of R- phrases: see SECTION Label elements Hazard pictogram Signal word : Not applicable : Not applicable HR Page of 0
2 SECTION 2: Hazards Identification Hazard statement(s) Precautionary statement(s) Supplemental Hazard s : Not applicable : Not applicable : Not applicable 2.3 Other hazards : none SECTION 3: Composition/information on ingredients Refer to component MSDS SECTION 4: First Aid Measures 4. Description of first aid measures General Advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 5 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. SECTION 5: Fire Fighting Measures 5. Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. HR Page 2 of 0
3 SECTION 5: Fire Fighting Measures Unsuitable extinguishing media None known 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further Information SECTION 6: Accidental Release Measures 6. Personal Precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see SECTION 8 and 3. SECTION 7: Handling and Storage 7. Personal Precautions Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. See Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end uses HR Page 3 of 0
4 SECTION 8: Exposure Controls/Personal Protection 8. Control parameters Components with workplace control parameters Consult a physician. Show this safety data sheet to the doctor in attendance. 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN66 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 66(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P (EU EN 43) particle respirator.for higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 43) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Environmental Exposure Controls See SECTION 6 SECTION 9: Physical and Chemical Properties SECTION 0: Stability and Reactivity 0. Reactivity 0.2 Chemical stability 0.3 Possibility of hazardous reactions HR Page 4 of 0
5 SECTION 0: Stability and Reactivity 0.4 Conditions to avoid 0.5 Incompatible materials 0.6 Hazardous decomposition products Other decomposition products - no data available SECTION : Toxicological Information Refer to component MSDS SECTION 2: Ecological Information Refer to component MSDS SECTION 3: Disposal Considerations 3. Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. SECTION 4: Transportation Information 4. UN number ADR/RID: 336 IMDG: 336 IATA: UN proper shipping name ADR/RID: CHEMICAL KIT IMDG: Chemical kit IATA: Chemical kit 4.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: Packaging group ADR/RID: - IMDG: - IATA: Environmental hazards ADR/RID: No IMDG: No IATA: No HR Page 5 of 0
6 SECTION 4: Transportation Information 4.6 Special precautions for user SECTION 5: Regulatory Information This safety data sheet complies with the requirements of Regulation (EC) No 907/ Safety, health and environmental regulations/legislation specific for the substance or mixture 5.2 Chemical Safety Assessment SECTION 6: Other Information Kit Components Substance Name [CAS] R-Phrase S-Phrase GHS Pictogram Hazard Precautionary (+/-)-2-Methyl-2,4-pentanediol / GHS07 H35-H39 P305 + P35 +,4-Dioxane / / Propanol /25-26 GHS02, GHS07, GHS08 GHS02, GHS07 H225-H39- -H35 H225-H39- H336 Ammonium acetate H35-H39- Ammonium citrate tribasic /37/ GHS07 H35-H39- P20-P26- P28-P305 + P35 + P20-P26- P305 + P35 + P26-P305 + P35 + P26-P305 + P35 + Ammonium sulfate BICINE BIS-TRIS /37/ GHS07 H35-H39- P26-P305 + P35 + BIS-TRIS propane Cadmium chloride hydrate /23/25-50/ GHS06, GHS08, GHS09 H30-H330- H340-H350- H360FD- H372-H40 P20-P260- P273-P284- P30 + P30- P30 Calcium chloride dihydrate GHS07 H39 P305 + P35 + Citric acid GHS07 H39 P305 + P35 + Dextran sulfate sodium salt WKG HR Page 6 of 0
7 (CONTINUED) - SECTION 6: Other Information Kit Components Substance Name [CAS] R-Phrase S-Phrase GHS Pictogram DL-Malic acid / GHS05, GHS07 Hazard H302-H35- H38- Precautionary P26-P280- P305 + P35 + Ethylene glycol GHS07 H302 HEPES Imidazole /37/39-45 GHS05, GHS07, GHS08 H302-H34- H360D P20-P280- P305 + P35 + -P30 Lithium sulfate monohydrate H302 L-Proline Magnesium chloride hexahydrate Magnesium formate dihydrate /25 3 MES monohydrate /37/ GHS07 H35-H39- Malonic acid P26-P305 + P35 + n-octyl-b-d-glucoside Nickel(II) chloride hexahydrate / /53 Polyethylene glycol / GHS06, GHS08, GHS09 H30-H35- H37-H33- H334-H34- H350i- H360-H372- H40 P20-P26- P273-P280- P30 + P30- P3 Polyethylene glycol Polyethylene glycol, Polyethylene glycol, Polyethylene glycol 3, Polyethylene glycol 4, Polyethylene glycol 6, Polyethylene glycol 8, Polyethylene glycol 0, Polyethylene glycol 20, Polyethylene glycol monomethyl ether 550 Polyethylene glycol monomethyl ether 2,000 Polyethylene glycol monomethyl ether 5, Potassium formate Potassium sodium tartrate tetrahydrate /25 3 Succinic acid / /37/39 H35-H38- P26-P280- P305 + P35 + WKG 3 3 HR Page 7 of 0
8 (CONTINUED) - SECTION 6: Other Information Kit Components Substance Name [CAS] R-Phrase S-Phrase GHS Pictogram Hazard Precautionary Sodium acetate trihydrate Sodium chloride Sodium citrate tribasic dihydrate Sodium formate Tris /37/ H35-H39- P26-P305 + P35 + WKG 2 Relevant R-phrase(s), S-phrase(s), Hazard code(s), Hazard statement(s), and Precautionary statement(s) Risk Phrase(s) R : Highly Flammable R 9 : May form explosive peroxides R 20/22 : Harmful by inhalation and if swallowed R 2/22 : Harmful in contact with skin and if swallowed R 22 : Harmful if swallowed R 25 : Toxic if swallowed R 26 : Very Toxic by inhalation R 34 : Causes burns R 36 : Irritating to the eyes R 36/37 : Irritating to eyes and respiratory system R 36/38 : Irritating to eyes and skin R 36/37/38 : Irritating to eyes, respiratory system and skin R 37/38 : Irritating to respiratory system and skin R 40 : Limited evidence of a carcinogenic effect R 4 : Risk of serious damage to eyes R 43 : May cause sensitization by skin contact R 45 : May cause cancer R 46 : May cause heritable genetic damage R 48/23/25 : Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R 50/53 : Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R 60 : May impair fertility R 6 : May cause harm to the unborn child R 66 : Repeated exposure may cause skin dryness or cracking R 67 : Vapors may cause drowsiness and dizziness Safety Phrase(s) S 7 : Keep container tightly closed S 9 : Keep container in a well-ventilated place S 6 : Keep away from sources of ignition - No smoking S 22 : Do not breathe dust S 24/25 : Avoid contact with skin and eyes S 26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S 36 : Wear suitable protective clothing and seek medical advice S 36/37 : Wear suitable protective clothing and gloves HR Page 8 of 0
9 (CONTINUED) - SECTION 6: Other Information Relevant R-phrase(s), S-phrase(s), Hazard code(s), Hazard statement(s), and Precautionary statement(s) (CONTINUED) - Safety Phrase(s) S 36/37/39 : Wear suitable protective clothing, gloves and eye/face protection S 36/39 : Wear suitable protective clothing and eye/face protection S 39 : Wear eye/face protection S 45 : In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) S 46 : If swallowed, seek medical advice immediately and show this container or label S 53 : Avoid exposure - obtain special instruction before use S 60 : This material and/or its container must be disposed of as hazardous waste S 6 : Avoid release to the environment. Refer to special instructions safety data sheet GHS Pictogram(s) GHS02 : Flammable liquids GHS07 : Acute Toxicity Eye Irrit. 2 STOT SE 3 GHS05 : Eye Irrit. GHS08 : Carcinogenicity A, B GHS06 : Acute Toxicity GHS09 : Hazardous to aquatic environment Hazard statement(s) H225 : Highly Flammable liquid and vapour H30 : Toxic if swallowed H302 : Harmful if swallowed H32 : Harmful in contact with skin H34 : Causes severe skin burns and eye damage H35 : Causes skin irritation H37 : May cause an allergic skin reaction H38 : Causes serious eye damage H39 : Causes serious eye irritation H330 : Fatal if inhaled H33 : Toxic if inhaled H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled : May cause respiratory irritation H336 : May cause drowsiness or dizziness H340 : May cause genetic defects H34 : Suspected of causing genetic defects H350 : May cause cancer H35 : Suspected of causing cancer H360 : May damage fertility or the unborn child H372 : Causes damage to organs through prolonged or repeated exposure H40 : Very toxic to aquatic life with long lasting effects HR Page 9 of 0
10 (CONTINUED) - SECTION 6: Other Information Relevant R-phrase(s), S-phrase(s), Hazard code(s), Hazard statement(s), and Precautionary statement(s) Precautionary statement(s) P20 : Obtain special instructions before use. P20 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P260 : Do not breathe dust/fume/gas/mist/vapours/spray. P26 : Avoid breathing dust/fume/gas/mist/vapours/spray. P273 : Avoid release to the environment. P280 : Wear protective gloves/protective clothing/eye protection/face protection. P28 : Use personal protective equipment as required. P284 : Wear respiratory protection. P30 + P30: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P305 + P35 + : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P305 + P P30 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. P3 : Call a POISON CENTER or doctor/physician. DISCLAIMER For research use only. Not for drug, household, or other use. WARRANTY The above information is believed to be correct but does no purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of this product. Hampton Research Corp., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. License granted to make unlimited paper copies for internal use only Hampton Research Corp. HR Page 0 of 0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
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