Section 1 - Chemical Product and Company Identification. Catalog Numbers: , Synonyms: Acros Organics BVBA Company Identification:

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1 Material Safety Data Sheet Fehling B solution Section 1 - Chemical Product and Company Identification MSDS Name: Fehling B solution Catalog Numbers: , Synonyms: Acros Organics BVBA Company Identification: Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Acros Organics Company Identification: (USA) One Reagent Lane Fair Lawn, NJ For information in the US, call: 800-ACROS-01 For information in Europe, call: Emergency Number, Europe: Emergency Number US: CHEMTREC Phone Number, US: CHEMTREC Phone Number, Europe: Section 2 - Composition, Information on Ingredients CAS# Chemical Name: % EINECS# Sodium hydroxide 10% Potassium sodium tartrate tetrahydrate Text for R-phrases: see Section 16 Hazard Symbols: C ,6% unlisted Water 55,4% Hazard Symbols: Risk Phrases: C 35 Risk Phrases: 35

2 Potential Health Effects Eye: Skin: Ingestion: Inhalation: Chronic: Eyes: Skin: Ingestion: Inhalation: Notes to Physician: General Information: Extinguishing Media: General Information: Spills/Leaks: Section 3 - Hazards Identification EMERGENCY OVERVIEW Causes severe burns. Causes severe eye burns. Causes severe burns. Causes severe digestive tract burns. Causes chemical burns to the respiratory tract. Section 4 - First Aid Measures Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Section 5 - Fire Fighting Measures As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use foam, dry chemical, or carbon dioxide. Section 6 - Accidental Release Measures Use proper personal protective equipment as indicated in Section 8. Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - Handling and Storage Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on Handling: clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne

3 concentrations low. Exposure Limits CAS# : United Kingdom, WEL - STEL: 2 mg/m3 STEL United States OSHA: 2 mg/m3 TWA Belgium - TWA: 2 mg/m3 VLE France - VME: 2 mg/m3 VME Germany: 2 mg/m3 TWA (inhalable fraction) Japan: 2 mg/m3 Ceiling Malaysia: 2 mg/m3 Ceiling Spain: 2 mg/m3 VLA-EC CAS# : CAS# : Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure.

4 Clothing: Wear appropriate protective clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 Respirators: approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials Hazardous Decomposition Products Hazardous Polymerization RTECS#: Physical State: Clear liquid Color: colorless Odor: Not available ph: >12 Vapor Pressure: Not available Viscosity: Not available Boiling Point: 100 deg ( F) Freezing/Melting Point: Not available Autoignition Temperature: Not available Flash Point: Not available Explosion Limits: Lower: Not available Explosion Limits: Upper: Not available Decomposition Temperature: Not available Solubility in water: Not available Specific Gravity/Density: Molecular Formula: Molecular Weight: 0 Section 10 - Stability and Reactivity Not available Incompatible materials. Strong oxidizing agents. Carbon monoxide, carbon dioxide, sodium oxide, oxides of potassium. Has not been reported. Section 11 - Toxicological Information CAS# : WB CAS# : None listed CAS# : ZC LD50/LC50: RTECS:

5 Carcinogenicity: Other: Not available CAS# : Draize test, rabbit, eye: 400 ug Mild; Draize test, rabbit, eye: 1% Severe; Draize test, rabbit, eye: 50 ug/24h Severe; Draize test, rabbit, eye: 1 mg/24h Severe; Draize test, rabbit, skin: 500 mg/24h Severe;. RTECS: CAS# :. RTECS: CAS# : Oral, rat: LD50 = >90 ml/kg;. Sodium hydroxide - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Potassium sodium tartrate tetrahydrate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Water - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Section 12 - Ecological Information Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Shipping Name: Hazard Class: UN Number: Packing Group: Section 14 - Transport Information IATA IMO RID/ADR SODIUM SODIUM SODIUM HYDROXIDE HYDROXIDE HYDROXIDE SOLUTION SOLUTION SOLUTION II II II USA RQ: CAS# : 1000 lb final RQ; 454 kg final RQ European/International Regulations Section 15 - Regulatory Information European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases:

6 R 35 Causes severe burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# : 1 CAS# : 0 CAS# : Not available Canada CAS# is listed on Canada's DSL List CAS# is listed on Canada's DSL List </ TD> US Federal TSCA CAS# is listed on the TSCA Inventory. CAS# is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form in on the Inventory (40CFR720.3(u)(2)). CAS# is listed on the TSCA Inventory. Text for R-phrases from Section 2 R 35 Causes severe burns. Section 16 - Other Information MSDS Creation Date: 7/16/1996 Revision #1 Date 8/29/2003 Revisions were made in Sections: General revision. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages

7 howsoever arising, even if the company has been advised of the possibility of such damages

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