Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Loctite ML SFDN Page 1 of 9 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: Loctite ML SFDN Relevant identified uses of the substance or mixture and uses advised against: Intended use: Lubricant Details of the supplier of the safety data sheet: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com Emergency Telephone Number: 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture: SECTION 2: Hazards identification Classification (DPD): F+ - Extremely flammable R12 Extremely flammable. Dangerous for the environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness.

2 Loctite ML SFDN Page 2 of 9 Label elements (DPD): F+ - Extremely flammable Risk phrases: R12 Extremely flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S23 Do not breathe spray. S24 Avoid contact with skin. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children Contains: Hydrocarbon aliphatic C4-11 < 0,1% benzene Other hazards: The aerosol container is under pressure. Do not expose to high temperatures. General chemical description: Lubricant SECTION 3: Composition/information on ingredients

3 Loctite ML SFDN Page 3 of 9 Declaration of the ingredients according to CLP (EC) No 1272/2008: Butane, n- Hydrocarbon aliphatic C4-11 < 0,1% benzene Kerosine (petroleum) Isobutane Propane EC Number REACH-Reg No. content Classification >= 25- < 50 % Flammable gases 1 H220 Gases under pressure >= 15- < 20 % Aspiration hazard 1 H304 Germ cell mutagenicity 1B H340 Skin irritation 2 H315 Carcinogenicity 1B H350 Specific target organ toxicity - single exposure 3 H336 Aspiration hazard 1 H304 Flammable liquids 2 H225 Chronic hazards to the aquatic environment H >= 10- < 20 % Aspiration hazard 1 H >= 10- < 20 % Flammable gases 1 H220 Gases under pressure >= 10- < 20 % Flammable gases 1 H220 Gases under pressure Only dangerous ingredients for which a CLP classification is already available are displayed in this table. For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Butane, n- Hydrocarbon aliphatic C4-11 < 0,1% benzene Kerosine (petroleum) Isobutane Propane EC Number content Classification REACH-Reg No >= 25 - < 50 % F+ - Extremely flammable; R >= 15 - < 20 % F - Highly flammable; R11 Xi - Irritant; R38 Xn - Harmful; R65 R67 N - Dangerous for the environment; R51/ >= 10 - < 20 % Xn - Harmful; R >= 10 - < 20 % F+ - Extremely flammable; R >= 10 - < 20 % F+ - Extremely flammable; R12 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Description of first aid measures: SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice.

4 Loctite ML SFDN Page 4 of 9 Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice. Most important symptoms and effects, both acute and delayed: Vapors may cause drowsiness and dizziness. Indication of any immediate medical attention and special treatment needed: See section: Description of first aid measures Extinguishing media: Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Special hazards arising from the substance or mixture: Oxides of carbon, oxides of nitrogen, irritating organic vapors. Advice for firefighters: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Avoid skin and eye contact. Ensure adequate ventilation. Environmental precautions: Do not let product enter drains. Methods and material for containment and cleaning up: For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Reference to other sections: See advice in chapter 8 Precautions for safe handling: Use only in well-ventilated areas. Vapours should be extracted to avoid inhalation. Keep away from sources of ignition - no smoking. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. SECTION 7: Handling and storage Conditions for safe storage, including any incompatibilities: Store in a cool, well-ventilated place. Keep away from heat and direct sunlight.

5 Loctite ML SFDN Page 5 of 9 Specific end use(s): Lubricant SECTION 8: Exposure controls/personal protection Control parameters: Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks BUTANE Short Term Exposure EH40 WEL Limit (STEL): BUTANE Time Weighted Average (TWA): EH40 WEL Exposure controls: Respiratory protection: Use only in well-ventilated areas. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance aerosol yellow Odor characteristic ph Initial boiling point Flash point Decomposition temperature Vapour pressure (25 C (77 F)) Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solubility (qualitative) (Solvent: Acetone) -60 C (-76 F) 4000 mbar 0,6 g/cm3 Insoluble Soluble

6 Loctite ML SFDN Page 6 of 9 Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Other information: SECTION 10: Stability and reactivity Reactivity: Reacts with strong oxidants. Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: See section reactivity Conditions to avoid: Stable Hazardous decomposition products: Irritating organic vapours. SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Prolonged or repeated contact may cause skin irritation. Eye irritation: May cause mild irritation to the eyes. Germ cell mutagenicity: Butane, n- Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method

7 Loctite ML SFDN Page 7 of 9 SECTION 12: Ecological information General ecological information: Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water. The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Mobility: The product evaporates readily. Toxicity: Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 3 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: Kerosine (petroleum) Result Route of application Degradability Method aerobic 58,6 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil: Butane, n- Isobutane LogKow Bioconcentration factor (BCF) 2,89 Exposure time Species Temperature Method 2,88 20 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) SECTION 13: Disposal considerations Waste treatment methods: Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Disposal must be made according to official regulations. Waste code Other solvents and solvent mixtures

8 Loctite ML SFDN Page 8 of 9 SECTION 14: Transport information Road transport ADR: Class: 2 Classification code: 5F Hazard ident. number: Technical name: AEROSOLS Tunnelcode: (D) Railroad transport RID: Class: 2 Classification code: 5F Hazard ident. number: 23 Technical name: AEROSOLS Tunnelcode: Inland water transport ADN: Class: 2 Classification code: 5F Hazard ident. number: Technical name: AEROSOLS Marine transport IMDG: Class: 2.1 EmS: F-D,S-U Seawater pollutant: - Proper shipping name: AEROSOLS Air transport IATA: Class: 2.1 Packaging instructions (passenger) 203 Packaging instructions (cargo) 203 Proper shipping name: Aerosols, flammable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: VOC content 96 % (1999/13/EC)

9 Loctite ML SFDN Page 9 of 9 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R12 Extremely flammable. R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. H220 Extremely flammable gas. H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.