Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet STAIN BLASTER G Section 1. Chemical product and company identification Trade name Product use STAIN BLASTER G Spot and stain remover Supplier Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN Code Date of issue 05-March-2010 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) Section 2. Hazards identification Physical state Emergency overview Liquid. [Liquid.] DANGER! CAUSES DIGESTIVE TRACT, EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION. Do not ingest. Do not get in eyes, on skin or on clothing. Avoid breathing vapors, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential acute health effects Corrosive to eyes. Corrosive to the skin. Severely irritating to the respiratory system. Causes burns to mouth, throat and stomach. See toxicological information (section 11) Section 3. Composition/information on ingredients Name CAS number % by weight BUTOXYETHANOL POTASSIUM HYDROXIDE Section 4. First aid measures Eye contact contact In case of contact, immediately flush eyes with cool running water. Remove contact lenses and continue flushing with plenty of water for at least 15 minutes. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Clean shoes thoroughly before reuse. If inhaled, remove to fresh air. If exposed person is not breathing, give artificial respiration or oxygen applied by trained personnel. Get medical attention immediately. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

2 STAIN BLASTER G Page 2/4 Section 5. Fire-fighting measures Flash point C (Closed cup) Hazardous thermal Decomposition products may include the following materials decomposition products carbon dioxide carbon monoxide metal oxide/oxides Fire-fighting media and Use an extinguishing agent suitable for the surrounding fire. instructions Dike area of fire to prevent runoff. Special protective equipment for fire-fighters Personal precautions Environmental precautions In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Methods for cleaning up Immediately contact emergency personnel. Stop leak if without risk. Use suitable protective equipment. Keep unnecessary personnel away. Do not touch or walk through spilled material. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling Storage Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or spray. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container tightly closed. Do not store above the following temperature 50 C Section 8. Exposure controls/personal protection Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Personal protection Use chemical splash goggles. For continued or severe exposure wear a face shield over the goggles. Hands Use chemical-resistant, impervious gloves. Use synthetic apron, other protective equipment as necessary to prevent skin contact. Respiratory Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. Name Exposure limits BUTOXYETHANOL ACGIH TLV (United States, 1/2009). TWA 20 ppm 8 hour(s). OSHA PEL (United States, 11/2006). Absorbed through skin. TWA 240 mg/m³ 8 hour(s). TWA 50 ppm 8 hour(s). POTASSIUM HYDROXIDE ACGIH TLV (United States, 1/2009). C 2 mg/m³ NIOSH REL (United States, 6/2009).

3 STAIN BLASTER G Page 3/4 TWA 2 mg/m³ 10 hour(s). Section 9. Physical and chemical properties Physical state Color Odor ph Relative density Viscosity Solubility Section 10. Stability and reactivity Liquid. [Liquid.] Clear. Odorless [Conc. (% w/w) 100%] 1.02 Dynamic 10 cp Easily soluble in the following materials cold water and hot water. Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Reactivity Highly reactive or incompatible with the following materials metals and acids. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Potential acute health effects Corrosive to eyes. Corrosive to the skin. Severely irritating to the respiratory system. Causes burns to mouth, throat and stomach. Potential chronic health effects Other adverse effects Target organs Contains material which may cause damage to the following organs blood, kidneys, lungs, liver, lymphatic system, upper respiratory tract, central nervous system (CNS). Section 12. Ecological information Ecotoxicity data Not reported Section 13. Disposal considerations Waste disposal Waste classification The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Unused product is D002 (Corrosive) Consult your local or regional authorities. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. UN Classification Not applicable. UN number Proper shipping name Class Packing group UN1719 CAUSTIC ALKALI LIQUID, N.O.S. (potassium hydroxide) 8

4 STAIN BLASTER G Page 4/4 III See shipping documents for specific transportation information. Section 15. Regulatory information HCS Classification Corrosive material Target organ effects U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 313 Form R - Reporting requirements Product name BUTOXYETHANOL CAS number Concentration 5 California Prop. 65 No products were found. Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards * Date of issue 05-March Responsible name Regulatory Affairs Date of previous issue 12-September Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

5 Material Safety Data Sheet STAIN BLASTER R Section 1. Chemical product and company identification Trade name Product use STAIN BLASTER R Laundry product Supplier Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN Code Date of issue 05-March-2010 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) Section 2. Hazards identification Physical state Emergency overview Liquid. [Liquid.] DANGER! CAUSES DIGESTIVE TRACT, EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION. HARMFUL IF SWALLOWED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. Do not ingest. Do not get in eyes, on skin or on clothing. Avoid breathing vapors, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential acute health effects See toxicological information (section 11) Corrosive to eyes. Corrosive to the skin. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. Severely irritating to the respiratory system. Harmful if swallowed. Causes burns to mouth, throat and stomach. Section 3. Composition/information on ingredients Name CAS number % by weight OXALIC ACID ethanol, 2-amino-, ethanedioate (21) (salt) Section 4. First aid measures Eye contact contact In case of contact, immediately flush eyes with cool running water. Remove contact lenses and continue flushing with plenty of water for at least 15 minutes. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Clean shoes thoroughly before reuse. If inhaled, remove to fresh air. If exposed person is not breathing, give artificial respiration or oxygen applied by trained personnel. Get medical attention immediately. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

6 STAIN BLASTER R Page 2/4 Section 5. Fire-fighting measures Flash point > 100 C Product does not support combustion. Hazardous thermal Decomposition products may include the following materials decomposition products carbon dioxide carbon monoxide nitrogen oxides Fire-fighting media and Use an extinguishing agent suitable for the surrounding fire. instructions Dike area of fire to prevent runoff. Special protective equipment for fire-fighters Personal precautions Environmental precautions In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Methods for cleaning up Immediately contact emergency personnel. Stop leak if without risk. Use suitable protective equipment. Keep unnecessary personnel away. Do not touch or walk through spilled material. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling Storage Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or spray. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Do not mix with bleach or other chlorinated products will cause chlorine gas. Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container tightly closed. Do not store above the following temperature 50 C Section 8. Exposure controls/personal protection Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Personal protection Hands Use chemical splash goggles. For continued or severe exposure wear a face shield over the goggles. Use chemical-resistant, impervious gloves. Respiratory Use synthetic apron, other protective equipment as necessary to prevent skin contact. Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. Name Exposure limits

7 STAIN BLASTER R Page 3/4 OXALIC ACID ACGIH TLV (United States, 1/2009). STEL 2 mg/m³ 15 minute(s). TWA 1 mg/m³ 8 hour(s). OSHA PEL (United States, 11/2006). TWA 1 mg/m³ 8 hour(s). NIOSH REL (United States, 6/2009). TWA 1 mg/m³ 10 hour(s). STEL 2 mg/m³ 15 minute(s). Section 9. Physical and chemical properties Physical state Color Odor ph Relative density Dispersibility properties Solubility Section 10. Stability and reactivity Liquid. [Liquid.] Colorless. Odorless. 1 [Conc. (% w/w) 100%] Easily dispersible in the following materials cold water and hot water. Easily soluble in the following materials cold water and hot water. Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Reactivity Extremely reactive or incompatible with the following materials alkalis. Do not mix with bleach or other chlorinated products will cause chlorine gas. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Potential acute health effects Corrosive to eyes. Corrosive to the skin. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. Severely irritating to the respiratory system. Harmful if swallowed. Causes burns to mouth, throat and stomach. Potential chronic health effects Other adverse effects Target organs Contains material which causes damage to the following organs the nervous system, heart. Contains material which may cause damage to the following organs kidneys, mucous membranes, gastrointestinal tract, upper respiratory tract, central nervous system (CNS), nose/sinuses, throat. Section 12. Ecological information Ecotoxicity data Not reported Section 13. Disposal considerations Waste disposal Waste classification The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Unused product is D002 (Corrosive) Consult your local or regional authorities.

8 STAIN BLASTER R Page 4/4 Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. UN Classification Not applicable. UN number Proper shipping name Class Packing group UN3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (oxalic acid) 8 III Additional information Limited quantity See shipping documents for specific transportation information. Section 15. Regulatory information HCS Classification Corrosive material Target organ effects U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. California Prop. 65 No products were found. Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards * Date of issue 05-March Responsible name Regulatory Affairs Date of previous issue 24-August Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

9 Material Safety Data Sheet STAINBLASTER S Section 1. Chemical product and company identification Trade name Product use STAINBLASTER S Laundry product Supplier Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN Code Date of issue 05-March-2010 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) Section 2. Hazards identification Physical state Emergency overview Liquid. [Liquid.] WARNING! CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. Can cause central nervous system (CNS) depression. MAY CAUSE ALLERGIC SKIN REACTION. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential acute health effects Irritating to eyes. Moderately irritating to the skin. May cause sensitization by skin contact. Moderately irritating to the respiratory system. High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and may lead to unconsciousness. May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. may cause nausea, weakness and central nervous system effects. See toxicological information (section 11) Section 3. Composition/information on ingredients Name CAS number % by weight distillates (petroleum), hydrotreated light >50 alcohols, c12-16, ethoxylated Limonene Section 4. First aid measures Eye contact contact In case of contact, immediately flush eyes with cool running water. Remove contact lenses and continue flushing with plenty of water for at least 15 minutes. Get medical attention if irritation persists. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. If inhaled, remove to fresh air.

10 STAINBLASTER S Page 2/4 If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious person. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately. Section 5. Fire-fighting measures Flash point > 100 C Product does not support combustion. Hazardous thermal Decomposition products may include the following materials decomposition products carbon dioxide carbon monoxide Fire-fighting media and Use an extinguishing agent suitable for the surrounding fire. instructions Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst. Special protective equipment Fire-fighters should wear appropriate protective equipment and self-contained for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Use suitable protective equipment (section 8). Do not allow to enter drains or watercourses. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling Storage Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container tightly closed. Do not store above the following temperature 50 C Section 8. Exposure controls/personal protection Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Personal protection Wear eye protection. Hands Use chemical-resistant, impervious gloves. Use suitable protective equipment. Respiratory Avoid breathing vapors, spray or mists. Name Exposure limits distillates (petroleum), hydrotreated light ACGIH TLV (United States, 1/2009). Absorbed through skin. TWA 200 mg/m³ 8 hour(s). Limonene AIHA WEEL (United States, 1/2007). TWA 30 ppm 8 hour(s).

11 STAINBLASTER S Page 3/4 Section 9. Physical and chemical properties Physical state Color Odor ph Boiling/condensation point Relative density Dispersibility properties Solubility Liquid. [Liquid.] Colorless to light yellow. citrus 5 to 7 [Conc. (% w/w) 100%] >100 C (>212 F) Section 10. Stability and reactivity to Easily dispersible in the following materials cold water and hot water. Very slightly soluble in the following materials cold water and hot water. Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Potential acute health effects Irritating to eyes. Moderately irritating to the skin. May cause sensitization by skin contact. Moderately irritating to the respiratory system. High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and may lead to unconsciousness. May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. may cause nausea, weakness and central nervous system effects. Section 12. Ecological information Ecotoxicity data Not reported Section 13. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Consult your local or regional authorities. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. UN Classification UN number Proper shipping name Not applicable. Class Packing group Additional information UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ALCOHOL,C12-C16 POLY(1-6) ETHOXYLATE), Marine pollutant (Limonene) 9 III Limited quantity

12 STAINBLASTER S Page 4/4 See shipping documents for specific transportation information. Section 15. Regulatory information HCS Classification Irritating material Sensitizing material U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. California Prop. 65 No products were found. Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards Date of issue 05-March Responsible name Regulatory Affairs Date of previous issue 03-August Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

13 Material Safety Data Sheet STAIN BLASTER A Section 1. Chemical product and company identification Trade name Product use STAIN BLASTER A Laundry product Supplier Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN Code Date of issue 05-March-2010 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) Section 2. Hazards identification Physical state Emergency overview Liquid. [Liquid.] CAUTION! MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. COMBUSTIBLE LIQUID AND VAPOR. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential acute health effects Moderately irritating to eyes. Moderately irritating to the skin. May cause sensitization by skin contact. Moderately irritating to the respiratory system. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. See toxicological information (section 11) Section 3. Composition/information on ingredients Name CAS number % by weight TEA-DODECYLBENZENESULFONATE GLYCERIN tripropylene glycol monomethyl ether alcohols, c12-16, ethoxylated ISOPROPYL ALCOHOL TRIETHANOLAMINE SODIUM METABISULFITE Section 4. First aid measures Eye contact contact In case of contact, immediately flush eyes with plenty of water. Remove contact lenses and flush again. Get medical attention if irritation persists. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. If inhaled, remove to fresh air. Do not induce vomiting. Never give anything by mouth to an unconscious person. If irritation persists, get medical attention.

14 STAIN BLASTER A Page 2/4 Section 5. Fire-fighting measures Flash point C (Closed cup) Hazardous thermal Decomposition products may include the following materials decomposition products carbon dioxide carbon monoxide nitrogen oxides sulfur oxides metal oxide/oxides Fire-fighting media and Use dry chemical, CO2, water spray (fog) or foam. instructions Use water spray to keep fire-exposed containers cool. Dike area of fire to prevent runoff. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment Fire-fighters should wear appropriate protective equipment and self-contained for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Use suitable protective equipment (section 8). Do not allow to enter drains or watercourses. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof means to transfer material to a sealable, appropriate container for disposal. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling Storage Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above the following temperature 50 C Section 8. Exposure controls/personal protection Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Personal protection Hands Eye protection recommended. For prolonged or repeated handling, use the following type of gloves Impervious gloves. Respiratory Use suitable protective equipment. Avoid breathing vapors, spray or mists. Name Exposure limits

15 STAIN BLASTER A Page 3/4 GLYCERIN ACGIH TLV (United States, 1/2009). TWA 10 mg/m³ 8 hour(s). Form Mist OSHA PEL (United States, 11/2006). TWA 5 mg/m³ 8 hour(s). Form Respirable fraction TWA 15 mg/m³ 8 hour(s). Form Total dust ISOPROPYL ALCOHOL ACGIH TLV (United States, 1/2009). STEL 400 ppm 15 minute(s). TWA 200 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA 980 mg/m³ 8 hour(s). TWA 400 ppm 8 hour(s). TRIETHANOLAMINE ACGIH TLV (United States, 1/2009). TWA 5 mg/m³ 8 hour(s). SODIUM METABISULFITE ACGIH TLV (United States, 1/2009). TWA 5 mg/m³ 8 hour(s). NIOSH REL (United States, 6/2009). TWA 5 mg/m³ 10 hour(s). Section 9. Physical and chemical properties Physical state Color Odor ph Boiling/condensation point Relative density Viscosity Solubility Liquid. [Liquid.] Yellow. Fragrance-like. 7 to 8.5 [Conc. (% w/w) 100%] >100 C (>212 F) Section 10. Stability and reactivity 0.99 to 1.19 Dynamic 75 cp Easily soluble in the following materials cold water and hot water. Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Potential acute health effects Moderately irritating to eyes. Moderately irritating to the skin. May cause sensitization by skin contact. Moderately irritating to the respiratory system. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. Potential chronic health effects Other adverse effects Target organs Contains material which may cause damage to the following organs kidneys, mucous membranes, upper respiratory tract, central nervous system (CNS).

16 STAIN BLASTER A Page 4/4 Section 12. Ecological information Ecotoxicity data Not reported Section 13. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Consult your local or regional authorities. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. UN Classification Not applicable. UN number Proper shipping name Class Packing group UN1987 ALCOHOLS, N.O.S. (Contains Isopropanol) 3 III Additional information Limited quantity See shipping documents for specific transportation information. Section 15. Regulatory information HCS Classification Combustible liquid Irritating material Sensitizing material Target organ effects U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. California Prop. 65 No products were found. Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards * Date of issue 05-March Responsible name Regulatory Affairs Date of previous issue 04-March Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.