Revision Number: Issue date: 04/02/ PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 04/02/ PRODUCT AND COMPANY IDENTIFICATION Product type: Acrylics Item number: Restriction of Use: identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Contact information: Telephone: MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW HARMFUL IF SWALLOWED. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. HAZARD CLASS HAZARD CATEGORY ACUTE TOXICITY ORAL 4 SKIN IRRITATION 2 EYE IRRITATION 2A RESPIRATORY SENSITIZATION 1 SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. In case of inadequate ventilation wear respiratory protection. If SWALLOWED: Immediately call poison control or physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. If experiencing respiratory symptoms: Call a poison center or physician. Take off contaminated clothing. Not prescribed Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Page 1 of 6

2 4 % of the mixture consists of ingredient(s) of unknown acute toxicity. Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Polyfunctional aziridine Proprietary Silica, amorphous, treated ,5,8,11,14-Pentaoxapentadecane * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. Immediately wash skin thoroughly with soap and water. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Keep individual calm. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. This product may form explosive peroxides. Oxides of carbon. Oxides of nitrogen. Oxides of boron. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Remove all sources of ignition. Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Page 2 of 6

3 7. HANDLING AND STORAGE Handling: Storage: During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of ignition. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. Make sure containers are properly grounded before use or transfer of material. Refer to Section 8. For safe storage, store at or below 32 C (89.6 F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Polyfunctional aziridine Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust. 6 mg/m3 TWA 2,5,8,11,14-Pentaoxapentadecane Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Nitrile gloves. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Gel, Liquid Color: Colorless to yellow Odor: Mild Odor threshold: ph: Vapor pressure: Boiling point/range: Not determined Melting point/ range: Specific gravity: 1.17 Vapor density: Flash point: > 93 C (> F) Seta closed cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Soluble Partition coefficient (n-octanol/water): VOC content: 24.3 %; 274 g/l Viscosity: Decomposition temperature: Page 3 of 6

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under normal conditions of storage and use. May occur. Oxides of carbon. Oxides of nitrogen. Oxides of boron. Oxides of lithium. Irritating organic vapours. Oxidizing agents. Acids. Water. Alcohols. Anhydrides. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Do not mix in batches greater than 100 grams (0.22 pounds) unless you plan to use immediately. Protect from direct sunlight. Freezing conditions. UV light. Moisture. Humidity 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: May cause allergic respiratory reaction. These symptoms, which can include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed (up to several hours after exposure). Causes skin irritation. May cause allergic skin reaction. Causes serious eye irritation. Harmful if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Polyfunctional aziridine Allergen, Irritant, Respiratory Silica, amorphous, treated No Target Organs 2,5,8,11,14-Pentaoxapentadecane Irritant, Reproductive Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Polyfunctional aziridine No No No Silica, amorphous, treated No No No 2,5,8,11,14-Pentaoxapentadecane No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6

5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: 2,5,8,11,14-Pentaoxapentadecane (CAS# ). CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: above reporting de minimis Immediate Health above reporting de minimis This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 04/02/2014 Page 5 of 6

6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6