: MOTOMASTER CHAINSAW BAR OIL - Fall/Winter
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1 Revision date: 28/08/2012 : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name. : Mixture : MOTOMASTER CHAINSAW BAR OIL - Fall/Winter Product code : , , Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/preparation : Speciality oil Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier: Canadian Tire Corporation 2180 Yonge Street M4P 2V8 Toronto, Ontario T (Business hours only) Manufacturer: CITGO Petroleum Corporation 1293 Eldridge Parkway Houston TX77077 lubeshelp@citgo.com 1.4. Emergency telephone number Emergency number : Supplier: (Business hours only- EST) Chemtrec (Outside USA) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects Avoid contact with eyes. Avoid repeated or prolonged skin contact. Do not store material in open or unmarked containers. Spilled material may present a slipping hazard Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II This mixture does not contain any ingredient that is included in the Ingredient Disclosure List and/or at above cut of concentration. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : In case of excessive inhalation of fumes move the person to fresh air. Keep victim warm and rested. In case of breathing difficulties administer oxygen. Seek medical attention immediately. 28/08/2012 EN (English) 1/6
2 First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : After contact with the molten product, cool rapidly with cold water. Wipe off as much as possible (using a clean, soft, absorbent material). Wash skin with plenty of water and soap. Remove contaminated clothing and shoes. Wash clothing before re-using. Clean or discard contaminated leather goods. : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if present and easy to do. Continue rinsing. In all cases of doubt, or when symptoms persist, seek medical advice. : Do NOT induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person. Allow small quantities to pass through the digestive system. Seek medical attention immediately Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Prolonged/repetitive skin contact may cause skin defattening or dermatitis. Exposure to this product will likely cause irritation to the respiratory system, digestive tract, eyes and skin. This material or its emissions may affect the central nervous system and/or aggravate pre-existing disorders. : May cause irritation to the respiratory tract and to other mucous membranes Indication of any immediate medical attention and special treatment needed Drain stomach by gastric lavage under qualified medical supervision. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: 5.2. Special hazards arising from the substance or mixture Explosion hazard Reactivity : This material can cause mild skin irritation from prolonged or repeated skin contact. Injection under the skin can cause inflammation and swelling. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical attention. : This product can cause transient mild eye irritation with short-term contact with liquid sprays or mists. Symptoms include stinging, watering, redness, and swelling. : This material can cause a laxative effect. Depression of the central nervous system, headaches, dizziness, drowsiness, loss of co-ordination. If swallowed, may be aspirated and cause lung damage. : Use dry chemical, foam, carbon dioxide or water fog. : Material will burn but does not easily ignite. When heated above the flash point, releases vapours. Heavier than air, vapours may travel long distances along ground, ignite and flash back to source. Exposed to ignition source, vapours can burn in open / explode if confined. : Stable under normal conditions of use Advice for firefighters Precautionary measures fire Protective equipment for firefighters : Water or foam may cause frothing. Carbon dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or inert gas in confined spaces. : Wear proper protective equipment. Extra personal protection: complete protective clothing including self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Spilled material may present a slipping hazard For non-emergency personnel Protective equipment For emergency responders Protective equipment : Wear suitable protective clothing gloves, and eye/face protection. : Wear suitable protective clothing, gloves and eye/face protection Environmental precautions Prevent entry to sewers and public waters. Avoid discharge to the environment. Specialist clean-up methods may be required. Ensure all national/local regulations are observed Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections Refer to sections 8 and 13. : Stop leak if safe to do so. Small spills: Clean up any spills as soon as possible, using an absorbent material to collect it. Collect in closed containers for disposal. Contain large spills to maximize product recovery or disposal. 28/08/2012 EN (English) 2/6
3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : When using high-pressure equipment, injection of product can occur. Container remains hazardous when empty. Continue to observe all precautions. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources. Keep away from open flames, hot surfaces and sources of ignition. Prevent physical damage to package. : Handle in accordance with good industrial hygiene and safety practice. DO NOT use gasoline, kerosene, solvents, or harsh abrasives as skin cleansers. Avoid contact with skin and eyes. Wash hands thoroughly after handling. Remove all contaminated clothing and footwear. Wash contaminated clothing prior to re-use Conditions for safe storage, including any incompatibilities Storage condition(s) Incompatible materials 7.3. Specific end use(s) : Keep container tightly closed. Store tightly closed in a dry, cool and well-ventilated place. Store in original container. Avoid high temperatures. Keep out of direct sunlight. : Strong oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Oil mist USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ USA ACGIH ACGIH STEL (mg/m³) 10 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m3) 5 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Provide local exhaust or general room ventilation to minimize vapour concentrations. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. : Protective goggles. Gloves. Protective clothing. Hand protection Eye protection Skin and body protection Respiratory protection : Chemical resistant gloves (nitrile-rubber, PVC, neoprene). Use heat-protective gloves when handling product at elevated temperatures. : safety glasses with side-shields. Use splash goggles when eye contact due to splashing is possible. : When skin contact is possible, protective clothing including gloves, apron, sleeves, boots, head and face protection must be worn. Wear heat resistant boots and protective clothing when handling material at elevated temperatures. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. : An approved organic vapour respirator/supplied air or self-contained breathing apparatus must be used when vapour concentration exceeds applicable exposure limits. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Red. odour : Mild petroleum-like odour. Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : 202 C (Pensky-Martens.)(Open Cup) Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : < 0.1 kpa (20 C) 28/08/2012 EN (English) 3/6
4 Relative vapour density at 20 C Relative density : 0.9 (Water = 1) Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Stable under normal conditions of use Chemical stability Stable under normal conditions of use Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid : Water: Negligible solubility in cold water. : 140 cst (40 C) Keep away from heat/sparks/open flames/hot surfaces. - No smoking Incompatible materials Strong oxidizing agents Hazardous decomposition products On thermal combustion, forms: Carbon oxides (CO, CO2). smokes. Toxic fumes. hydrocarbons. Phosphorus oxides. Zinc oxide. Sulphur oxides. Nitrogen oxides (NOx). SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Ecology - general : Not classified (none of the components is classified for skin corrosion&irritation) : Not classified (none of the components is classified for eye damage/irritation) : Not classified (none of the components is classified for respiratory or skin sensitization) : Not classified (No classification for mutagenicity as none of the components is classified for mutagenicity) : Not classified (No classification for carcinogenicity as none of the components is classified for carcinogenicity) : Not classified (No classification for reproduction as none of the components is toxic for reproduction) : Not classified (None of the components shows specific effects in acute toxicity studies requiring classification for Specific Target Organ Systemic Toxicity single exposure) : Not classified (None of the components shows specific effects in acute toxicity studies requiring classification for Specific Target Organ Systemic Toxicity repeated exposure) : Not classified : Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. : This material has not been tested for environmental effects. This substance may be hazardous to the environment. May cause long lasting harmful effects to aquatic life. In case of large spills the product may be hazardous to aquatic organisms due to possible formation of a film on the surface water which can diminish dissolved oxygen levels Persistence and degradability Bioaccumulative potential 28/08/2012 EN (English) 4/6
5 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste disposal recommendations Additional information SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number No dangerous good in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group : Dispose of contents/container to comply with applicable local, national and international regulations. : Do not pressurize, cut, weld, braze solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources. Empty containers should be taken for recycle, recovery or waste in accordance with local regulation. : Do not attempt to clean container Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions National regulations Regional legislation : Listed on the AICS (the Australian Inventory of Chemical Substances). Listed on the Canadian DSL (Domestic Sustances List) inventory. Listed on Inventory of Existing Chemical Substances (IECSC). Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory. Listed on KECI (Chemical Inventory of Korea). Listed on New Zealand - Inventory of Chemicals (NZIoC). Listed on Inventory of Chemicals and Chemical Substances (PICCS). Listed on the United States TSCA (Toxic Substances Control Act) inventory Chemical safety assessment SECTION 16: Other information Sources of Key data : MSDS. 28/08/2012 EN (English) 5/6
6 Abbreviations and acronyms : CAS - Chemical Abstracts Service. CLP - Classification, Labelling and Packaging. CSR - Chemical Safety Report. GHS - Globally Harmonised System. MSDS - Material Safety Data Sheet. OSHA - Occupational Safety and Health Administration. Overland transport (ADR). PBT - Persistent, Bioaccumulative and Toxic substance. PEL- Permissible Exposure Level. REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals. Relat - Relative. SDS -. STEL- Short-Term Exposure Limit. TLV- Threshold Limit Value. TWA- Time Weighted Average. vpvb - Very Persistent and Very Bioaccumulative. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 28/08/2012 EN (English) 6/6
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