In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S28
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1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier name MONT MARTE INTERNATIONAL PTY LTD Address 27 Pentex Street, Salisbury, QLD, 4107, AUSTRALIA Telephone (07) Fax (07) Emergency Web site Synonym(s) ACRYLIC MEDIUM - GLOSS Use(s) ARTIST PAINT SDS date 15 August HAZARDS IDENTIFICATION CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA RISK PHRASES R43 May cause sensitisation by skin contact. SAFETY PHRASES S1/2 Keep locked up and out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S28 After contact with skin, wash immediately with plenty of water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN number Packing group Hazchem code DG class Subsidiary risk(s) 3. COMPOSITION/ INFORMATION ON INGREDIENTS Ingredient Identification Classification Content ISOTHIAZOLINONE CHLORIDE WATER POLYACRYLIC ACID PROPYLENE GLYCOL (PROPANE-1,2-DIOL) 2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE CAS: EC: CAS: EC: T;R23/24/25 C;R34 Xn;R43 N;R50/53 Not Available % 50 to 55% CAS: Not Available 30 to 40% CAS: EC: CAS: EC: Not Available Not Available 5 to 10% 1 to 5% Page 1 of 6
2 METHACRYLIC ACID - METHYL METHACRYLATE COPOLYMER CAS: Not Available <1% 4. FIRST AID MEASURES Eye Inhalation Skin Ingestion Advice to doctor If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. For advice, contact a Poison Information Centre on (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Treat symptomatically. 5. FIRE FIGHTING MEASURES Flammability Fire and explosion Extinguishing Hazchem code Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods of cleaning up References Wear Personal Protective Equipment (PPE) as detailed in Section 8 of this SDS. Prevent product from entering drains and waterways. Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. See Sections 8 and 13 for exposure controls and disposal. 7. STORAGE AND HANDLING Storage Handling Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should have appropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940). Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure standards Ingredient Reference TWA STEL ppm mg/m³ ppm mg/m³ Propane-1,2-diol (particulates only) SWA (AUS) Propane-1,2-diol (total vapour & particulates) SWA (AUS) Biological limits Engineering controls No biological limit allocated. Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Page 2 of 6
3 PPE Eye / Face Hands Body Respiratory When using large quantities or where heavy contamination is likely, wear splash-proof goggles. When using large quantities or where heavy contamination is likely, wear neoprene or nitrile or butyl gloves. When using large quantities or where heavy contamination is likely, wear coveralls. Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance COLOURED LIQUID Odour SLIGHT ODOUR Flammability CLASS C2 COMBUSTIBLE Flash point > 490 C Boiling point 100 C (Approximately) Melting point Evaporation rate ph 9 to 9.4 Vapour density Specific gravity 1.05 Solubility (water) INSOLUBLE Vapour pressure Upper explosion limit Lower explosion limit Partition coefficient Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties Odour threshold % Volatiles 10. STABILITY AND REACTIVITY Chemical stability Conditions to avoid Material to avoid Hazardous Decomposition Products Hazardous Reactions Stable under recommended conditions of storage. Avoid heat, sparks, open flames and other ignition sources. Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), heat and ignition sources. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Health Hazard Summary Eye Inhalation Skin Low to moderate toxicity - irritant. This product has the potential to cause adverse health effects with over exposure. Due to the small product size and upon dilution, the potential for adverse health effects may be reduced. May cause sensitisation by skin contact. Irritant. Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. May cause sensitisation by skin contact. Page 3 of 6
4 Ingestion Low to moderate toxicity. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea. Toxicity data ISOTHIAZOLINONE CHLORIDE ( ) 53 mg/kg (rat) POLYACRYLIC ACID ( ) 2000 mg/kg (guinea pig) LD50 (intraperitoneal) 39 mg/kg (mouse) LD50 (intravenous) 70 mg/kg (mouse) PROPYLENE GLYCOL (PROPANE-1,2-DIOL) ( ) > 2080 mg/kg (quail) LD50 (intraperitoneal) 6660 mg/kg LD50 (intravenous) 2600 mg/kg (dog) LD50 (skin) mg/kg (rabbit) LD50 (subcutaneous) mg/kg (mouse) LDLo (intramuscular) 6300 mg/kg (rabbit) LDLo (subcutaneous) mg/kg (guinea pig) TDLo (ingestion) 79 g/kg/56 weeks intermittently (child) 2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE ( ) LCLo (inhalation) > 3500 mg/m³/6 hours (rat) 3200 mg/kg (mouse & rat) LDLo (skin) > 20 ml/kg (guinea pig) 12. ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste disposal Legislation For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For larger amounts, contact the manufacturer for additional information. Prevent contamination of drains or waterways as aquatic life may be threatened and environmental damage may result. Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO) UN number Proper shipping name DG class/ Division Subsidiary risk(s) Packing group Hazchem code 15. REGULATORY INFORMATION Page 4 of 6
5 Poison schedule Inventory Listing(s) A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt. 16. OTHER INFORMATION Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary. PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate. Abbreviations ACGIH CAS # CNS EC No. GHS IARC LD50 mg/m³ OEL PEL ph ppm REACH STEL STOT-RE STOT-SE SUSMP SWA TLV TWA American Conference of Governmental Industrial Hygienists Chemical Abstract Service number - used to uniquely identify chemical compounds Central Nervous System EC No - European Community Number Globally Harmonized System International Agency for Research on Cancer Lethal Dose, 50% / Median Lethal Dose Milligrams per Cubic Metre Occupational Exposure Limit Permissible Exposure Limit relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). Parts Per Million Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals Short-Term Exposure Limit Specific target organ toxicity (repeated exposure) Specific target organ toxicity (single exposure) Standard for the Uniform Scheduling of Medicines and Poisons Safe Work Australia Threshold Limit Value Time Weighted Average Revision history Revision Description Initial SDS creation Page 5 of 6
6 Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: Fax: info@rmt.com.au Web: Revision: SDS Date: August 2013 End of SDS Page 6 of 6
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