MATERIAL SAFETY. St. Paul, Minnesota or (651) (24 hours)

Transcription

1 MATERIAL SAFETY DATA SHEET 3M 3M Center St. Paul, Minnesota or (651) (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: HOME CARE DIVISION TRADE NAME: 3M ULTRATHON (tm) INSECT REPELLENT 8 ID NUMBER/U.P.C.: ISSUED: November 05, 2001 SUPERSEDES: November 01, 2001 DOCUMENT: INGREDIENT C.A.S. NO. PERCENT ISOPROPYL ALCOHOL LIQUEFIED PETROLEUM GAS N,N-DIETHYL M-TOLUAMIDE ,1-DIFLUOROETHANE < 5 OTHER INGREDIENTS < 20 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. 2. PHYSICAL DATA BOILING POINT:... ca. 180 F VAPOR PRESSURE:... N/D VAPOR DENSITY:... N/D EVAPORATION RATE:... N/D SOLUBILITY IN WATER:... neglig. SPECIFIC GRAVITY:... ca Water=1 PERCENT VOLATILE:... < 65 % ph:... N/D VISCOSITY:... ca centipoise MELTING POINT:... N/D

2 November 05, 2001 PAGE 2 2. PHYSICAL DATA (continued) APPEARANCE AND ODOR: Aerosol, alcohol DEET odor, light yellow color. 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT:... < 34 F FLAMMABLE LIMITS - LEL:... N/D FLAMMABLE LIMITS - UEL:... N/D AUTOIGNITION TEMPERATURE:... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Alcohol-type foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Water may not effectively extinguish fire; however, it should be used to keep fireexposed containers and surfaces cool and prevent explosive rupture. For leaks or spills which have not ignited, water spray can be used to disperse the flammable vapor and protect personnel attempting to stop the leak. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 0 AEROSOL STORAGE: 3 UNUSUAL REACTION HAZARD: none OSHA FIRE HAZARD CLASS: Class IB Flammable Liquid 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Heat. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.

3 November 05, 2001 PAGE 3 4. REACTIVITY DATA (continued) HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with inorganic absorbent material. Cover spill area with Light Water Brand or other ATC foam. (For further information on ATC foam usage, contact 3M Fire Protection Systems.) Collect using non-sparking tools. Clean up residue with water. Place in an approved metal container. Seal the container. RECOMMENDED DISPOSAL: Do not reuse empty container. Wrap container and put in trash. Do not puncture or incinerate. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes 6. SUGGESTED FIRST AID EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Discontinue use if irritation occurs. Use of this product may cause skin reactions in rare cases. If you

4 November 05, 2001 PAGE 4 6. SUGGESTED FIRST AID (continued) suspect that you or your child are reacting to this product, wash treated skin and call a poison control center. If you go to a doctor, take this repellent with you. INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. Call a physician or poison control center. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. SKIN PROTECTION: Not applicable. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use with adequate dilution ventilation. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or spray. PREVENTION OF ACCIDENTAL INGESTION: Wash hands after handling and before eating. RECOMMENDED STORAGE: Store away from acids. Store away from heat. Store at temperatures below 120 degrees F (49 degrees C). Store out of direct sunlight. Keep away from aluminum and zinc. Keep container dry. Keep container closed when not in use. Keep container in well-ventilated area. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Flammable liquid and vapor. Keep away from heat, sparks, open flame, and other sources of ignition. Prevent all sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Vapors may ignite explosively. Avoid static discharge.

5 November 05, 2001 PAGE 5 7. PRECAUTIONARY INFORMATION (continued) OTHER PRECAUTIONARY INFORMATION: Do not use on synthetic fabrics, plastics, watch crystals, leather, painted, or varnished surfaces. After returning indoors, wash treated skin with soap and water. Wash treated clothing. HMIS HAZARD RATINGS: HEALTH: 1 FLAMMABILITY: 4 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ISOPROPYL ALCOHOL PPM TWA ACGIH ISOPROPYL ALCOHOL PPM STEL ACGIH ISOPROPYL ALCOHOL PPM TWA OSHA ISOPROPYL ALCOHOL PPM STEL OSHA LIQUEFIED PETROLEUM GAS PPM TWA ACGIH LIQUEFIED PETROLEUM GAS PPM TWA OSHA N,N-DIETHYL M-TOLUAMIDE... NONE NONE NONE NONE 1,1-DIFLUOROETHANE PPM TWA CMRG 1,1-DIFLUOROETHANE PPM TWA AIHA OTHER INGREDIENTS... NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - AIHA: American Industrial Hygiene Assoc. Workplace Environmental Exposure Level Guideline - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established 8. HEALTH HAZARD DATA EYE CONTACT: Lacrimation: signs/symptoms can include severe stinging of the eyes and profuse tear discharge. Severe Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision and possible permanently impaired vision.

6 November 05, 2001 PAGE 6 8. HEALTH HAZARD DATA (continued) SKIN CONTACT: Moderate Skin Irritation: signs/symptoms can include redness, swelling, itching, and dryness. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Low Blood Pressure: signs/symptoms can include dizziness and fainting. Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. Nervous System Effects: signs/symptoms can include emotional changes, lack of coordination, tremors and sensory loss. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. Irritation of the Oral Mucosa: signs/symptoms can include bleeding, redness, swelling, and pain of the gums. REPRODUCTIVE/DEVELOPMENTAL TOXINS: N,N-DIETHYL-M-TOLUAMIDE ( ) is a potential reproductive hazard causing male and female reproductive effects by the dermal route of exposure in laboratory animals.

7 November 05, 2001 PAGE 7 SECTION CHANGE DATES HEADING SECTION CHANGED SINCE November 01, 2001 ISSUE The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.